The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated. Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds. To determine: The correct name of the complex [ Cu ( NH 3 ) 4 ] Cl 2 .

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Answer 1

Question

Chapter 21, Problem 4RQ

(a)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex [Cu(NH3)4]Cl2 .

(b)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex [Ni(en)2]SO4 .

(c)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex K[Cr(H2O)2]Cl4 .

(d)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex Na4[Co(CN)4C2O4] .

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5. Please draw in the blanks the missing transition states and the correlated products. Explicitly display relevant absolute stereochemical configuration. MeOH I OMe H Endo transition state, dienophile approaching from the bottom of diene + H ཎྞཾ ཌཱརཱ༔,_o OMe H H OMe Endo transition state, dienophile approaching from the top of diene or from the bottom but horizontally flipped (draw one) + Exo transition state, dienophile approaching from the top of diene or from the bottom but horizontally flipped (draw one) Exo transition state, dienophile approaching from the top of diene or from the bottom but horizontally flipped (draw one) MeO H H MeO H MeO H MeO H H

H H (1) H C. C C .H (2) (3) Cl H The ideal value for bond angle (1) is (Choose one) and the ideal value for bond angle (3) is (Choose one) degrees, the value for bond angle (2) is (Choose one) degrees, degrees.

Answer 2

Question

Chapter 21, Problem 4RQ

(a)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex [Cu(NH3)4]Cl2 .

(b)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex [Ni(en)2]SO4 .

(c)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex K[Cr(H2O)2]Cl4 .

(d)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex Na4[Co(CN)4C2O4] .

Expert Solution & Answer

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See solution

Answer 3

Question

Chapter 21, Problem 4RQ

(a)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex [Cu(NH3)4]Cl2 .

(b)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex [Ni(en)2]SO4 .

(c)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex K[Cr(H2O)2]Cl4 .

(d)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex Na4[Co(CN)4C2O4] .

Expert Solution & Answer

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Answer 4

Question

Chapter 21, Problem 4RQ

(a)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex [Cu(NH3)4]Cl2 .

(b)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex [Ni(en)2]SO4 .

(c)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex K[Cr(H2O)2]Cl4 .

(d)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex Na4[Co(CN)4C2O4] .

Expert Solution & Answer

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Answer 5

Chapter 21, Problem 4RQ

(a)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex [Cu(NH3)4]Cl2 .

(b)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex [Ni(en)2]SO4 .

(c)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex K[Cr(H2O)2]Cl4 .

(d)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex Na4[Co(CN)4C2O4] .

Answer 6

Chapter 21, Problem 4RQ

(a)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex [Cu(NH3)4]Cl2 .

Answer 7

Chapter 21, Problem 4RQ

(a)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex [Cu(NH3)4]Cl2 .

Answer 8

(b)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex [Ni(en)2]SO4 .

Answer 9

(b)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex [Ni(en)2]SO4 .

Answer 10

(c)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex K[Cr(H2O)2]Cl4 .

Answer 11

(c)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex K[Cr(H2O)2]Cl4 .

Answer 12

(d)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex Na4[Co(CN)4C2O4] .

Answer 13

(d)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex Na4[Co(CN)4C2O4] .

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 21 - What two first-row transition metals have...Ch. 21 - Prob. 2RQ Ch. 21 - Prob. 3RQ Ch. 21 - Prob. 4RQ Ch. 21 - Prob. 5RQ Ch. 21 - Prob. 6RQ Ch. 21 - Prob. 7RQ Ch. 21 - Prob. 8RQ Ch. 21 - Prob. 9RQ Ch. 21 - Prob. 10RQ

Solution Summary: The author explains that the nomenclature of coordination compounds is used to represent the formulas and their names in a systematic manner.

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Chapter 21 Solutions