ORGANIC CHEMISTRY-W/STUD.SOLN.MAN.
ORGANIC CHEMISTRY-W/STUD.SOLN.MAN.
10th Edition
ISBN: 9781260001099
Author: Carey
Publisher: MCG
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Chapter 21, Problem 42P
Interpretation Introduction

Interpretation:

The structure of product formed by the reaction of diethyl malonate with each of the reagents is to be drawn.

Concept introduction:

The reaction of diethyl malonate with sodium ethoxide and alkyl halide results in the formation of alkylated malonate ester.

Sodium ethoxide extract α-hydrogen atom present between the two carbonyl groups and generate negative charge on carbon atom. It acts as a nucleophile and attacks the alkyl part of alkyl halide and form alkylated malonate ester.

The basic hydrolysis of ester involves cleavage of OR

bond and formation of carboxylic acid and alcohol. The decarboxylation of compound involves removal of CO2.

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> Can the molecule on the right-hand side of this organic reaction be made in good yield from no more than two reactants, in one step, by moderately heating the reactants? ? Δ • If your answer is yes, then draw the reactant or reactants in the drawing area below. You can draw the reactants in any arrangement you like. If your answer is no, check the box under the drawing area instead. Explanation Check Click and drag to start drawing a structure. Х © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Acces
Predict the major products of the following organic reaction: O O + A ? Some important notes: • Draw the major product, or products, of the reaction in the drawing area below. • If there aren't any products, because no reaction will take place, check the box below the drawing area instead. • Be sure to use wedge and dash bonds when necessary, for example to distinguish between major products that are enantiomers. Explanation Check Click and drag to start drawing a structure. eserved. Terms of Use | Privacy Center >
(EXM 2, PRBLM 3) Here is this problem, can you explain it to me and show how its done. Thank you I need to see the work for like prbl solving.

Chapter 21 Solutions

ORGANIC CHEMISTRY-W/STUD.SOLN.MAN.

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