ORGANIC CHEMISTRY-W/STUD.SOLN.MAN.
10th Edition
ISBN: 9781260001099
Author: Carey
Publisher: MCG
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Question
Chapter 21, Problem 45P
Interpretation Introduction
Interpretation:
The formation of the product if each of the given reactants undergoes Claisen condensation is to be explained.
Concept Introduction:
Claisen condensation occurs between two esters or one ester and a carbonyl compound that must have an alpha hydrogen atom with them
It favours the formation of a single bond between two carbon atoms in the presence of a strong base.
The product formed ion the Claisen condensation is either a
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option choice:
Isoleucine
Histidine
Threonine
Alanine
Lysine
Aspartate
Tryptophan
Tyrosine
Leucine
Arginine
Cysteine
Asparagine
Valine
Glutamine
Glycine
Methionine
Serine
Proline
Phenylalanine
Glutamate
sketch the nature of the metal-alkylidene bonding interactions.
Part C
The perspective formula of isoleucine, an amino acid, is provided below.
HOOC
H₂NIC
H
川
CH3
CH,CH3
Draw the Newman projection in staggered conformation for isoleucine by viewing the molecule along the
C-2-C-3 bond.
1. Edit the Newman projection on the canvas.
2. Replace the appropriate hydrogens with the appropriate -CH3 or other groups.
3. If you need to start over, Undo or choose a Newman projection from the Templates toolbar
(bottom).
Important: Never delete the hydrogen atoms or bonds directly attached to the template, and do not move
them by dragging or dropping them. That will break the projections structures. Only replace them!
▸ View Available Hint(s)
0 2
H± 3D
EXP.
L
ד
י
CONT. 2
H
0
N
о
Chapter 21 Solutions
ORGANIC CHEMISTRY-W/STUD.SOLN.MAN.
Ch. 21.1 - Prob. 1PCh. 21.1 - Prob. 2PCh. 21.1 - Prob. 3PCh. 21.1 - Prob. 4PCh. 21.1 - Prob. 5PCh. 21.2 - Prob. 6PCh. 21.2 - Prob. 7PCh. 21.2 - Prob. 8PCh. 21.3 - Prob. 9PCh. 21.3 - Prob. 10P
Ch. 21.3 - Prob. 11PCh. 21.4 - Prob. 12PCh. 21.4 - Prob. 13PCh. 21.5 - Prob. 14PCh. 21.5 - Problem 21.15 Write the structure of the Dieckmann...Ch. 21.5 - Prob. 16PCh. 21.5 - Prob. 17PCh. 21.6 - Prob. 18PCh. 21.6 - Prob. 19PCh. 21.6 - Prob. 20PCh. 21.6 - Prob. 21PCh. 21.6 - Prob. 22PCh. 21.7 - Prob. 23PCh. 21.8 - Problem 21.24 Mesityl oxide is an industrial...Ch. 21.8 - Prob. 25PCh. 21.8 - Prob. 26PCh. 21.8 - Prob. 27PCh. 21.8 - Prob. 28PCh. 21 - Prob. 29PCh. 21 - Terreic acid, a naturally occurring antibiotic...Ch. 21 - Prob. 31PCh. 21 - Prob. 32PCh. 21 - Prob. 33PCh. 21 - Prob. 34PCh. 21 - Give the structure of the expected organic product...Ch. 21 - Prob. 36PCh. 21 - Prob. 37PCh. 21 - Prob. 38PCh. 21 - Prob. 39PCh. 21 - Give the structure of the principal organic...Ch. 21 - Prob. 41PCh. 21 - Prob. 42PCh. 21 - Prob. 43PCh. 21 - Prob. 44PCh. 21 - Prob. 45PCh. 21 - Prob. 46PCh. 21 - Prob. 47PCh. 21 - The use of epoxides as alkylating agents for...Ch. 21 - Prob. 49PCh. 21 - Show how you could prepare each of the following...Ch. 21 - Prob. 51PCh. 21 - Prob. 52PCh. 21 - Prob. 53PCh. 21 - Prob. 54PCh. 21 - The - methylene ketone sarkomycin has an...Ch. 21 - - Lactone can be prepared in good yield from...Ch. 21 - Prob. 57PCh. 21 - Prob. 58DSPCh. 21 - The Enolate Chemistry of Dianionss The synthetic...Ch. 21 - Prob. 60DSPCh. 21 - Prob. 61DSPCh. 21 - Prob. 62DSPCh. 21 - Prob. 63DSP
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