Chemistry: Structure and Properties (2nd Edition)
2nd Edition
ISBN: 9780134293936
Author: Nivaldo J. Tro
Publisher: PEARSON
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Question
Chapter 21, Problem 26E
Interpretation Introduction
Interpretation:
Explain the types of reaction alcohols generally show. Illustrate with suitable examples.
Concept introduction:
Alcohols will give specific reactions due to presence of OH (hydroxyl group). This group can be oxidized, removed or substituted completely or the hydrogen can be substituted (acidic character).
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Identify and provide an explanation that distinguishes a qualitative and quantitative chemical analysis. Provide examples.
Identify and provide an explanation of the operational principles behind a Atomic Absorption Spectrometer (AAS). List the steps involved.
Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
Chapter 21 Solutions
Chemistry: Structure and Properties (2nd Edition)
Ch. 21 - Prob. 1ECh. 21 - Prob. 2ECh. 21 - Prob. 3ECh. 21 - Prob. 4ECh. 21 - Prob. 5ECh. 21 - Prob. 6ECh. 21 - Prob. 7ECh. 21 - What are the main classifications of hydrocarbons?...Ch. 21 - Prob. 9ECh. 21 - What are structural isomers? How do the properties...
Ch. 21 - Prob. 11ECh. 21 - Define each term related to optical isomerism:...Ch. 21 - Prob. 13ECh. 21 - Prob. 14ECh. 21 - Explain geometric isomerism in alkenes. How do the...Ch. 21 - Prob. 16ECh. 21 - Prob. 17ECh. 21 - Prob. 18ECh. 21 - Prob. 19ECh. 21 - Prob. 20ECh. 21 - Prob. 21ECh. 21 - Prob. 22ECh. 21 - Prob. 23ECh. 21 - Prob. 24ECh. 21 - Prob. 25ECh. 21 - Prob. 26ECh. 21 - Prob. 27ECh. 21 - Prob. 28ECh. 21 - Prob. 29ECh. 21 - Prob. 30ECh. 21 - Prob. 31ECh. 21 - Prob. 32ECh. 21 - Prob. 33ECh. 21 - Prob. 34ECh. 21 - Prob. 35ECh. 21 - Prob. 36ECh. 21 - Prob. 37ECh. 21 - Prob. 38ECh. 21 - Prob. 39ECh. 21 - Prob. 40ECh. 21 - Name each alkane.Ch. 21 - Prob. 42ECh. 21 - Prob. 43ECh. 21 - Draw a structure for each alkane. a....Ch. 21 - Prob. 45ECh. 21 - Complete and balance each hydrocarbon combustion...Ch. 21 - Prob. 47ECh. 21 - Prob. 48ECh. 21 - Prob. 49ECh. 21 - Prob. 50ECh. 21 - Name each alkene.Ch. 21 - Prob. 52ECh. 21 - Prob. 53ECh. 21 - Name each alkyne.Ch. 21 - Draw the correct structure for each compound. a....Ch. 21 - Prob. 56ECh. 21 - Prob. 57ECh. 21 - Prob. 58ECh. 21 - Prob. 59ECh. 21 - Prob. 60ECh. 21 - Prob. 61ECh. 21 - Prob. 62ECh. 21 - Prob. 63ECh. 21 - Prob. 64ECh. 21 - Prob. 65ECh. 21 - Prob. 66ECh. 21 - Prob. 67ECh. 21 - Prob. 68ECh. 21 - Prob. 69ECh. 21 - Prob. 70ECh. 21 - Prob. 71ECh. 21 - Prob. 72ECh. 21 - Prob. 73ECh. 21 - Prob. 74ECh. 21 - Prob. 75ECh. 21 - Prob. 76ECh. 21 - Prob. 77ECh. 21 - Prob. 78ECh. 21 - Prob. 79ECh. 21 - Prob. 80ECh. 21 - Prob. 81ECh. 21 - Prob. 82ECh. 21 - Prob. 83ECh. 21 - Prob. 84ECh. 21 - Prob. 85ECh. 21 - Prob. 86ECh. 21 - Prob. 87ECh. 21 - Prob. 88ECh. 21 - Identify each organic compound as an alkane,...Ch. 21 - Identify each organic compound as an alkane,...Ch. 21 - Prob. 91ECh. 21 - Prob. 92ECh. 21 - Prob. 93ECh. 21 - Determine whether each pair of structures are...Ch. 21 - Prob. 95ECh. 21 - Prob. 96ECh. 21 - Classify each organic reaction as combustion,...Ch. 21 - Prob. 98ECh. 21 - Prob. 99ECh. 21 - Prob. 100ECh. 21 - Prob. 101ECh. 21 - Prob. 102ECh. 21 - Prob. 103ECh. 21 - Prob. 104ECh. 21 - Prob. 105ECh. 21 - Prob. 106ECh. 21 - Prob. 107ECh. 21 - Prob. 108ECh. 21 - Prob. 109ECh. 21 - Prob. 110ECh. 21 - Prob. 111ECh. 21 - Prob. 112ECh. 21 - Prob. 113ECh. 21 - Prob. 114ECh. 21 - Draw the structure and name a compound with the...Ch. 21 - Prob. 116ECh. 21 - Prob. 117ECh. 21 - Prob. 118ECh. 21 - Prob. 119ECh. 21 - Prob. 120ECh. 21 - Prob. 121ECh. 21 - Prob. 1SAQCh. 21 - Prob. 2SAQCh. 21 - Prob. 3SAQCh. 21 - Prob. 4SAQCh. 21 - Prob. 5SAQCh. 21 - Prob. 6SAQCh. 21 - Prob. 7SAQCh. 21 - Prob. 8SAQCh. 21 - Prob. 9SAQCh. 21 - Prob. 10SAQ
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