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(a)
Interpretation:
The name and structural formula of the
Concept introduction:
The hydrogen atom from the carbon chain can be replaced by atoms/group of atoms called a functional group. The presence of functional group gives characteristics properties to the compound. The chemical properties of the compounds containing the similar functional group are same based on the carbon chain length.
The structural formula is a simplest model that represents the arrangement of atoms and bonds in a molecule.
(b)
Interpretation:
To write the structural diagrams show the difference between an aldehyde and a ketone
Concept introduction:
The structural diagram is a simplified model that represents the arrangement of atoms and bonds in a molecule. Both aldehyde and ketone are carbonyl compounds. In the carbonyl functional group, the carbon atom is double bonded to an oxygen atom. The remaining valency of the carbon atom can be satisfied by an alkyl group or a hydrogen atom.
(c)
Interpretation:
The structural diagrams for all possible aldehyde or ketone isomers of
Concept introduction:
Isomers are the compounds that have the same molecular formula but different in structural arrangement. The connectivity of atoms is different in isomers.
The structural diagram is a simplified model that represents the arrangement of atoms and bonds in a molecule.
Both aldehyde and ketone are carbonyl compounds. In the carbonyl functional group, the carbon atom is double bonded to an oxygen atom. In aldehyde, the remaining valencies of the carbon are filled by an alkyl group and a hydrogen atom while in ketone, the remaining valencies of the carbon are satisfied alkyl groups.
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Chapter 21 Solutions
Introduction to Chemistry, Special Edition
- 6. a) C2's. Phosphorus pentafluoride PF5 belongs to D3h symmetry group. Draw the structure of the molecule, identify principal axis of rotation and perpendicular (4 points) b) assume that the principal axis of rotation is aligned with z axis, assign symmetry labels (such as a1, b2, etc.) to the following atomic orbitals of the P atom. (character table for this group is included in the Supplemental material). 3s 3pz (6 points) 3dz²arrow_forward2. Construct Lewis-dot structures, and draw VESPR models for the ions listed below. a) SiF5 (4 points) b) IOF4 (4 points)arrow_forward5. Complex anion [AuCl2]¯ belongs to Doh symmetry point group. What is the shape of this ion? (4 points)arrow_forward
- 4. Assign the following molecules to proper point groups: Pyridine N 1,3,5-triazine N Narrow_forward7. a) Under normal conditions (room temperature & atmospheric pressure) potassium assumes bcc lattice. Atomic radius for 12-coordinate K atom is listed as 235 pm. What is the radius of potassium atom under normal conditions? (3 points) b) Titanium metal crystallyzes in hcp lattice. Under proper conditions nitrogen can be absorbed into the lattice of titanium resulting in an alloy of stoichiometry TiNo.2. Is this compound likely to be a substitutional or an interstitial alloy? (Radius of Ti (12-coordinate) is 147 pm; radius of N atom is 75 pm. (3 points)arrow_forwardcan someone answer the questions and draw out the complete mechanismarrow_forward
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