Interpretation:
The
Concept Introduction:
Enthalpy of reaction:
The enthalpy of a reaction is calculated by subtracting the heat of formation of reactatns from heat of formation of products.
Exothermic and Endothermic Reaction:
Exothermic reaction is a reaction in which heat is given out to the surrounding from the system.
Endothermic reaction is a reaction in which heat is gained by the system from the surrounding.
Want to see the full answer?
Check out a sample textbook solutionChapter 21 Solutions
OWLv2 for Ebbing/Gammon's General Chemistry, 11th Edition, [Instant Access], 1 term (6 months)
- Data are given in Appendix 1 for white phosphorus, P4(s). P4(g) has the following thermodynamic values: Hf=58.9kJ/mol , S=280.0J/kmol . What is the temperature at which white phosphorus sublimes at 1 atm pressure?arrow_forwardComparing the chemistry of carbon and silicon. (a) Write balanced chemical equations for the reactions of H2O() with CH4 (forming CO2 and H2) and SiH4 (forming SiO2 and H2). (b) Using thermodynamic data, calculate the standard free energy change for the reactions in (a). Is either reaction product-favored at equilibrium? (c) Look up the electronegativities of carbon, silicon, and hydrogen. What conclusion can you draw concerning the polarity of CH and SiH bonds? (d) Carbon and silicon compounds with the formulas (CH3)2CO (acetone) and [(CH3)2SiO]n (a silicone polymer) also have quite different structures. Draw Lewis structures for these species. This difference, along with the difference between structures of CO2 and SiO2, suggests a general observation about silicon compounds. Based on that observation, do you expect that a silicon compound with a structure similar to ethene (C2H4) exists?arrow_forwardWhen boron hydrides burn in air, the reactions are very exothermic (a) Write a balanced equation for the combustion of B5H9(g) in air to give B2O3(s) and H2O(g). (b) Calculate the enthalpy of combustion for B5H9(g) (fH = 73.2 kJ/mol), and compare it with the enthalpy of combustion of B2H6 (2038 kJ/mol). (The enthalpy of formation of B2O3(s) is 1271.9 kJ/mol.) (c) Compare the enthalpy of combustion of C2H6(g) with that of B2H6(g). Which transfers more energy as heat per gram?arrow_forward
- Although nitrogen trifluoride (NF3) is a thermally stable compound, nitrogen triiodide (NI3) is known to be a highly explosive material. NI3 can be synthesized according to the equation BN(s) + 3IF(g) BF3(g) + NI3(g) a. What is the enthalpy of formation for NI3(s) given the enthalpy of reaction (307 kJ) and the enthalpies of formation for BN(s) (254 kJ/mol), IF(g) (96 kJ/mol), and BF3(g) (1136 kJ/mol)? b. It is reported that when the synthesis of NI3 is conducted using 4 moles of IF for every 1 mole of BN, one of the by-products isolated is [IF2]+[BF4]. What are the molecular geometries of the species in this by-product? What are the hybridizations of the central atoms in each species in the by-product?arrow_forward(a) Elemental boron reacts with fluorine to form BF3, a gas. Write a balanced chemical equation for the reaction of solid boron with fluorine gas. (b) ΔHf° for BF3(g) is -1135.6 kj/mol. Calculate the standard enthalpy change in the reaction of boron with fluorine.arrow_forwardHow much energy is required to produce 1.00 kg of aluminum by the reaction 2 Al2O3(s) + 3 C(s) + 1.97 × 103 kJ → 4 Al(s) + 3 CO2(g)?arrow_forward
- Determine the energy associated with each of these processes in order to recycle 1.26 mol Cu. The smelting of copper occurs by the balanced chemical equation: CuO(s)+CO(g)Cu(s)+CO2(g)where ΔH°f,CuO is = –155 kJ/mol. Assume the process of recycling copper is simplified to just the melting of the solid Cu starting at 25°C. The melting point of Cu is 1084.5°C with ΔH°fus = 13.0 kJ/mol and a molar heat capacity, cP,Cu = 24.5 J/mol·°C.arrow_forwardThe reaction that was on the screen when you started and its derivative demonstrate that the reaction enthalpy, ΔH, changes sign when a process is reversed. Consider the reaction H2O(l)→H2O(g), ΔH =44.0kJ What will ΔH be for the reaction if it is reversed?arrow_forward23. Given that the enthalpy of neutralization for the reaction of HCl (a strong acid) and NaOH (a strong base) is always -55.90 kJ per mole of H2O formed, what is the concentration of a 55 mL sample of HCl if the enthalpy of neutralization for the reaction was found to be -4.85 kJ, ΔTsoln = 4.5 ºC and the calorimeter constant value is 0.17 kJ/ºC 2.34 M 0.73 M 4.15 M 1.33 M 1.52 Marrow_forward
- Write a balanced equation for the formation of CO2(g) from C(s) and O2(g). Calculate the enthalpy change for this reaction using the following data (at 25 degrees Celsius): C(s) + 1/2 O2(g) --> CO(g) change in H = -111 kJ CO(g) + 1/2 O2(g) --> CO2(g) change in H = -394 kJ Is the reaction endothermic or exothermic?arrow_forwardFe2O3(s) + 3CO(s) → 2Fe(s) + 3CO2(g) ΔH = -28.0 kJ 3Fe(s) + 4CO2(s) → Fe3O4(s) + 4CO(g) ΔH = +12.5 kJ The enthalpy of reaction of Fe2O3 with CO 3Fe2O3(s) + CO(g) → CO2(g) + 2Fe3O4(s) is ____kJ.arrow_forwardUse heat of formation data from Appendix E to calculate ∆H ° for the following reaction:ClO2 (g) + O(g) → ClO(g) + O2(g)arrow_forward
- Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
- Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage LearningChemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning