(a) Interpretation: Synthesis of the given compound beginning with acetoacetic ester is to be shown. Concept introduction: An acetoacetic ester synthesis results in an α- alkylated acetone compound because it has one ester group. The ester is hydrolyzed to the carboxylic acid and undergoes decarboxylation. Retro synthesis is undergone.

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Answer 1

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Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 21, Problem 21.71P

Interpretation Introduction

(a)

Interpretation:

Synthesis of the given compound beginning with acetoacetic ester is to be shown.

Concept introduction:

An acetoacetic ester synthesis results in an α- alkylated acetone compound because it has one ester group. The ester is hydrolyzed to the carboxylic acid and undergoes decarboxylation. Retro synthesis is undergone.

Interpretation Introduction

(b)

Interpretation:

Synthesis of the given compound beginning with acetoacetic ester is to be shown.

Concept introduction:

An acetoacetic ester synthesis results in an α- alkylated acetone compound because it has one ester group. The ester is hydrolyzed to the carboxylic acid and undergoes decarboxylation. Retro synthesis is undergone.

Interpretation Introduction

(c)

Interpretation:

Synthesis of the given compound beginning with acetoacetic ester is to be shown.

Concept introduction:

An acetoacetic ester synthesis results in an α- alkylated acetone compound because it has one ester group. The ester is hydrolyzed to the carboxylic acid and undergoes decarboxylation. Retro synthesis is undergone.

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The initial rates method can be used to determine the rate law for a reaction. using the data for the reaction below, what is the rate law for reaction? A+B-C - ALA] At (mot Trial [A] (mol) (MD 2 1 0.075 [B]( 0.075 mo LS 01350 2 0.075 0.090 0.1944 3 0.090 0.075 0.1350 Report value of k with two significant Figure

Compare trials 1 and 2 where [B] is constant. The rate law can be written as: rate = k[A][B]". rate2 0.090 = 9. rate1 0.010 [A]m 6.0m = 3m [A] m 2.0m

Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 21, Problem 21.71P

Interpretation Introduction

(a)

Interpretation:

Synthesis of the given compound beginning with acetoacetic ester is to be shown.

Concept introduction:

An acetoacetic ester synthesis results in an α- alkylated acetone compound because it has one ester group. The ester is hydrolyzed to the carboxylic acid and undergoes decarboxylation. Retro synthesis is undergone.

Interpretation Introduction

(b)

Interpretation:

Synthesis of the given compound beginning with acetoacetic ester is to be shown.

Concept introduction:

An acetoacetic ester synthesis results in an α- alkylated acetone compound because it has one ester group. The ester is hydrolyzed to the carboxylic acid and undergoes decarboxylation. Retro synthesis is undergone.

Interpretation Introduction

(c)

Interpretation:

Synthesis of the given compound beginning with acetoacetic ester is to be shown.

Concept introduction:

An acetoacetic ester synthesis results in an α- alkylated acetone compound because it has one ester group. The ester is hydrolyzed to the carboxylic acid and undergoes decarboxylation. Retro synthesis is undergone.

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Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 21, Problem 21.71P

Interpretation Introduction

(a)

Interpretation:

Synthesis of the given compound beginning with acetoacetic ester is to be shown.

Concept introduction:

An acetoacetic ester synthesis results in an α- alkylated acetone compound because it has one ester group. The ester is hydrolyzed to the carboxylic acid and undergoes decarboxylation. Retro synthesis is undergone.

Interpretation Introduction

(b)

Interpretation:

Synthesis of the given compound beginning with acetoacetic ester is to be shown.

Concept introduction:

An acetoacetic ester synthesis results in an α- alkylated acetone compound because it has one ester group. The ester is hydrolyzed to the carboxylic acid and undergoes decarboxylation. Retro synthesis is undergone.

Interpretation Introduction

(c)

Interpretation:

Synthesis of the given compound beginning with acetoacetic ester is to be shown.

Concept introduction:

An acetoacetic ester synthesis results in an α- alkylated acetone compound because it has one ester group. The ester is hydrolyzed to the carboxylic acid and undergoes decarboxylation. Retro synthesis is undergone.

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Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 21, Problem 21.71P

Interpretation Introduction

(a)

Interpretation:

Synthesis of the given compound beginning with acetoacetic ester is to be shown.

Concept introduction:

An acetoacetic ester synthesis results in an α- alkylated acetone compound because it has one ester group. The ester is hydrolyzed to the carboxylic acid and undergoes decarboxylation. Retro synthesis is undergone.

Interpretation Introduction

(b)

Interpretation:

Synthesis of the given compound beginning with acetoacetic ester is to be shown.

Concept introduction:

An acetoacetic ester synthesis results in an α- alkylated acetone compound because it has one ester group. The ester is hydrolyzed to the carboxylic acid and undergoes decarboxylation. Retro synthesis is undergone.

Interpretation Introduction

(c)

Interpretation:

Synthesis of the given compound beginning with acetoacetic ester is to be shown.

Concept introduction:

An acetoacetic ester synthesis results in an α- alkylated acetone compound because it has one ester group. The ester is hydrolyzed to the carboxylic acid and undergoes decarboxylation. Retro synthesis is undergone.

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Answer 5

Chapter 21, Problem 21.71P

Interpretation Introduction

(a)

Interpretation:

Synthesis of the given compound beginning with acetoacetic ester is to be shown.

Concept introduction:

An acetoacetic ester synthesis results in an α- alkylated acetone compound because it has one ester group. The ester is hydrolyzed to the carboxylic acid and undergoes decarboxylation. Retro synthesis is undergone.

Interpretation Introduction

(b)

Interpretation:

Synthesis of the given compound beginning with acetoacetic ester is to be shown.

Concept introduction:

An acetoacetic ester synthesis results in an α- alkylated acetone compound because it has one ester group. The ester is hydrolyzed to the carboxylic acid and undergoes decarboxylation. Retro synthesis is undergone.

Interpretation Introduction

(c)

Interpretation:

Synthesis of the given compound beginning with acetoacetic ester is to be shown.

Concept introduction:

An acetoacetic ester synthesis results in an α- alkylated acetone compound because it has one ester group. The ester is hydrolyzed to the carboxylic acid and undergoes decarboxylation. Retro synthesis is undergone.

Answer 6

Chapter 21, Problem 21.71P

Interpretation Introduction

(a)

Interpretation:

Synthesis of the given compound beginning with acetoacetic ester is to be shown.

Concept introduction:

An acetoacetic ester synthesis results in an α- alkylated acetone compound because it has one ester group. The ester is hydrolyzed to the carboxylic acid and undergoes decarboxylation. Retro synthesis is undergone.

Answer 7

Chapter 21, Problem 21.71P

Interpretation Introduction

(a)

Interpretation:

Synthesis of the given compound beginning with acetoacetic ester is to be shown.

Concept introduction:

An acetoacetic ester synthesis results in an α- alkylated acetone compound because it has one ester group. The ester is hydrolyzed to the carboxylic acid and undergoes decarboxylation. Retro synthesis is undergone.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Synthesis of the given compound beginning with acetoacetic ester is to be shown.

Concept introduction:

An acetoacetic ester synthesis results in an α- alkylated acetone compound because it has one ester group. The ester is hydrolyzed to the carboxylic acid and undergoes decarboxylation. Retro synthesis is undergone.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Synthesis of the given compound beginning with acetoacetic ester is to be shown.

Concept introduction:

An acetoacetic ester synthesis results in an α- alkylated acetone compound because it has one ester group. The ester is hydrolyzed to the carboxylic acid and undergoes decarboxylation. Retro synthesis is undergone.

Answer 10

Interpretation Introduction

(c)

Interpretation:

Synthesis of the given compound beginning with acetoacetic ester is to be shown.

Concept introduction:

An acetoacetic ester synthesis results in an α- alkylated acetone compound because it has one ester group. The ester is hydrolyzed to the carboxylic acid and undergoes decarboxylation. Retro synthesis is undergone.

Answer 11

Interpretation Introduction

(c)

Interpretation:

Synthesis of the given compound beginning with acetoacetic ester is to be shown.

Concept introduction:

An acetoacetic ester synthesis results in an α- alkylated acetone compound because it has one ester group. The ester is hydrolyzed to the carboxylic acid and undergoes decarboxylation. Retro synthesis is undergone.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 21 - Prob. 21.1P Ch. 21 - Prob. 21.2P Ch. 21 - Prob. 21.3P Ch. 21 - Prob. 21.4P Ch. 21 - Prob. 21.5P Ch. 21 - Prob. 21.6P Ch. 21 - Prob. 21.7P Ch. 21 - Prob. 21.8P Ch. 21 - Prob. 21.9P Ch. 21 - Prob. 21.10P

Solution Summary: The author explains that an acetoacetic ester synthesis results in an - alkylated

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