The ΔG o for reaction between A l ( s ) a n d C d 2 + ( a q ) has to be calculated. Concept Introduction: An electrochemical cell is a device in which a redox reaction is used to convert chemical energy into electrical energy. Such device is also known as the galvanic or voltaic cell. Galvanic cell consists of two half-cells. The redox reaction occurs in these half-cells. The half-cell in which the reduction reaction occurs is known as the reduction half-cell, whereas the half-cell in which the oxidation reaction occurs is known as the oxidation half-cell. Anode: The electrode where the oxidation occurs is called as an anode. It is a negatively charged electrode. Cathode: The electrode where reduction occurs is called as a cathode. It is a positively charged electrode. Oxidation: The gain of oxygen or the loss of hydrogen or the loss of an electron in a species during a redox reaction is called as oxidation. Reduction: The loss of oxygen or the gain of hydrogen or the gain of an electron in a species during a redox reaction is called as reduction. The Standard Gibb’s free energy change and the standard cell potential are related as followed: Δ ° G = -nFE ° cell n - Number of electrons involved per equivalent of the net redox reaction in the cell F - Faraday’s Constant (96500 C) E ° cell - Standard cell potential.

Question

Want to see the full answer?

Answer 1

Question

Chapter 21, Problem 21.61P

(a)

Interpretation Introduction

Interpretation:

The ΔGo for reaction between Al(s) and Cd2+(aq) has to be calculated.

Concept Introduction:

An electrochemical cell is a device in which a redox reaction is used to convert chemical energy into electrical energy. Such device is also known as the galvanic or voltaic cell.

Galvanic cell consists of two half-cells. The redox reaction occurs in these half-cells. The half-cell in which the reduction reaction occurs is known as the reduction half-cell, whereas the half-cell in which the oxidation reaction occurs is known as the oxidation half-cell.

Anode: The electrode where the oxidation occurs is called as an anode. It is a negatively charged electrode.

Cathode: The electrode where reduction occurs is called as a cathode. It is a positively charged electrode.

Oxidation: The gain of oxygen or the loss of hydrogen or the loss of an electron in a species during a redox reaction is called as oxidation.

Reduction: The loss of oxygen or the gain of hydrogen or the gain of an electron in a species during a redox reaction is called as reduction.

The Standard Gibb’s free energy change and the standard cell potential are related as followed:

Δ°G = -nFE°cell

n - Number of electrons involved per equivalent of the net redox reaction in the cell

F - Faraday’s Constant (96500 C)

E°cell - Standard cell potential.

(b)

Interpretation Introduction

Interpretation:

The ΔGo for reaction between I2(s) and Br−(aq) has to be calculated.

Concept Introduction:

An electrochemical cell is a device in which a redox reaction is used to convert chemical energy into electrical energy. Such device is also known as the galvanic or voltaic cell.

Galvanic cell consists of two half-cells. The redox reaction occurs in these half-cells. The half-cell in which the reduction reaction occurs is known as the reduction half-cell, whereas the half-cell in which the oxidation reaction occurs is known as the oxidation half-cell.

Anode: The electrode where the oxidation occurs is called as an anode. It is a negatively charged electrode.

Cathode: The electrode where reduction occurs is called as a cathode. It is a positively charged electrode.

Oxidation: The gain of oxygen or the loss of hydrogen or the loss of an electron in a species during a redox reaction is called as oxidation.

Reduction: The loss of oxygen or the gain of hydrogen or the gain of an electron in a species during a redox reaction is called as reduction.

The Standard Gibb’s free energy change and the standard cell potential are related as followed:

Δ°G = -nFE°cell

n - Number of electrons involved per equivalent of the net redox reaction in the cell

F - Faraday’s Constant (96500 C)

E°cell - Standard cell potential.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Photochemical smog is formed in part by the action of light on nitrogen dioxide. The wavelength of radiation absorbed by NO2 in this reaction is 197 nm.(a) Draw the Lewis structure of NO2 and sketch its π molecular orbitals.(b) When 1.56 mJ of energy is absorbed by 3.0 L of air at 20 °C and 0.91 atm, all the NO2 molecules in this sample dissociate by the reaction shown. Assume that each absorbed photon leads to the dissociation (into NO and O) of one NO2 molecule. What is the proportion, in parts per million, of NO2 molecules in this sample? Assume that the sample behaves ideally.

Correct each molecule in the drawing area below so that it has the skeletal ("line") structure it would have if it were dissolved in a 0.1 M aqueous solution of HCI. If there are no changes to be made, check the No changes box under the drawing area. No changes. HO Explanation Check NH, 2 W O :□ G ©2025 M unter Accessibility

An expression for the root mean square velocity, vrms, of a gas was derived. Using Maxwell’s velocity distribution, one can also calculate the mean velocity and the most probable velocity (mp) of a collection of molecules. The equations used for these two quantities are vmean=(8RT/πM)1/2 and vmp=(2RT/M)1/2 These values have a fixed relationship to each other.(a) Arrange these three quantities in order of increasing magnitude.(b) Show that the relative magnitudes are independent of the molar mass of the gas.(c) Use the smallest velocity as a reference for establishing the order of magnitude and determine the relationship between the larger and smaller values.