The mechanism has to be proposed for the conversion of A to B and B to C, function of the sodium amide it be explained.

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Answer 1

Question

Chapter 21, Problem 21.57P

(a)

Interpretation Introduction

Interpretation:

The mechanism has to be proposed for the conversion of A to B and B to C, function of the sodium amide it be explained.

(b)

Interpretation Introduction

Interpretation:

The importance of introducing benzyl group in chloramine has to be explained for the conversion of B to C.

(c)

Interpretation Introduction

Interpretation:

The reagent has to be proposed for the conversion of D to E for removing benzyl group.

Concept introduction:

Hydrogenolysis: Amine or alcohol reaction with H₂ in the presence of a transition

Metal catalyst gives the corresponding amine or alcohol.

(d)

Interpretation Introduction

Interpretation:

The reagent has to be proposed for the conversion of E to bidisomide.

(e)

Interpretation Introduction

Interpretation:

The possible stereoisomer’s has to be shown if the product is chiral.

Concept introduction:

Chiral:

A molecule is non superimposable on its mirror image is called chiral molecule. Four different atoms attached to a carbon atom is called chiral molecule.

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer.

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Answer 2

Question

Chapter 21, Problem 21.57P

(a)

Interpretation Introduction

Interpretation:

The mechanism has to be proposed for the conversion of A to B and B to C, function of the sodium amide it be explained.

(b)

Interpretation Introduction

Interpretation:

The importance of introducing benzyl group in chloramine has to be explained for the conversion of B to C.

(c)

Interpretation Introduction

Interpretation:

The reagent has to be proposed for the conversion of D to E for removing benzyl group.

Concept introduction:

Hydrogenolysis: Amine or alcohol reaction with H₂ in the presence of a transition

Metal catalyst gives the corresponding amine or alcohol.

(d)

Interpretation Introduction

Interpretation:

The reagent has to be proposed for the conversion of E to bidisomide.

(e)

Interpretation Introduction

Interpretation:

The possible stereoisomer’s has to be shown if the product is chiral.

Concept introduction:

Chiral:

A molecule is non superimposable on its mirror image is called chiral molecule. Four different atoms attached to a carbon atom is called chiral molecule.

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer.

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Answer 3

Question

Chapter 21, Problem 21.57P

(a)

Interpretation Introduction

Interpretation:

The mechanism has to be proposed for the conversion of A to B and B to C, function of the sodium amide it be explained.

(b)

Interpretation Introduction

Interpretation:

The importance of introducing benzyl group in chloramine has to be explained for the conversion of B to C.

(c)

Interpretation Introduction

Interpretation:

The reagent has to be proposed for the conversion of D to E for removing benzyl group.

Concept introduction:

Hydrogenolysis: Amine or alcohol reaction with H₂ in the presence of a transition

Metal catalyst gives the corresponding amine or alcohol.

(d)

Interpretation Introduction

Interpretation:

The reagent has to be proposed for the conversion of E to bidisomide.

(e)

Interpretation Introduction

Interpretation:

The possible stereoisomer’s has to be shown if the product is chiral.

Concept introduction:

Chiral:

A molecule is non superimposable on its mirror image is called chiral molecule. Four different atoms attached to a carbon atom is called chiral molecule.

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer.

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Answer 4

Question

Chapter 21, Problem 21.57P

(a)

Interpretation Introduction

Interpretation:

The mechanism has to be proposed for the conversion of A to B and B to C, function of the sodium amide it be explained.

(b)

Interpretation Introduction

Interpretation:

The importance of introducing benzyl group in chloramine has to be explained for the conversion of B to C.

(c)

Interpretation Introduction

Interpretation:

The reagent has to be proposed for the conversion of D to E for removing benzyl group.

Concept introduction:

Hydrogenolysis: Amine or alcohol reaction with H₂ in the presence of a transition

Metal catalyst gives the corresponding amine or alcohol.

(d)

Interpretation Introduction

Interpretation:

The reagent has to be proposed for the conversion of E to bidisomide.

(e)

Interpretation Introduction

Interpretation:

The possible stereoisomer’s has to be shown if the product is chiral.

Concept introduction:

Chiral:

A molecule is non superimposable on its mirror image is called chiral molecule. Four different atoms attached to a carbon atom is called chiral molecule.

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer.

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Answer 5

Chapter 21, Problem 21.57P

(a)

Interpretation Introduction

Interpretation:

The mechanism has to be proposed for the conversion of A to B and B to C, function of the sodium amide it be explained.

(b)

Interpretation Introduction

Interpretation:

The importance of introducing benzyl group in chloramine has to be explained for the conversion of B to C.

(c)

Interpretation Introduction

Interpretation:

The reagent has to be proposed for the conversion of D to E for removing benzyl group.

Concept introduction:

Hydrogenolysis: Amine or alcohol reaction with H₂ in the presence of a transition

Metal catalyst gives the corresponding amine or alcohol.

(d)

Interpretation Introduction

Interpretation:

The reagent has to be proposed for the conversion of E to bidisomide.

(e)

Interpretation Introduction

Interpretation:

The possible stereoisomer’s has to be shown if the product is chiral.

Concept introduction:

Chiral:

A molecule is non superimposable on its mirror image is called chiral molecule. Four different atoms attached to a carbon atom is called chiral molecule.

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer.

Answer 6

Chapter 21, Problem 21.57P

(a)

Interpretation Introduction

Interpretation:

The mechanism has to be proposed for the conversion of A to B and B to C, function of the sodium amide it be explained.

Answer 7

Chapter 21, Problem 21.57P

(a)

Interpretation Introduction

Interpretation:

The mechanism has to be proposed for the conversion of A to B and B to C, function of the sodium amide it be explained.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The importance of introducing benzyl group in chloramine has to be explained for the conversion of B to C.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The importance of introducing benzyl group in chloramine has to be explained for the conversion of B to C.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The reagent has to be proposed for the conversion of D to E for removing benzyl group.

Concept introduction:

Hydrogenolysis: Amine or alcohol reaction with H₂ in the presence of a transition

Metal catalyst gives the corresponding amine or alcohol.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The reagent has to be proposed for the conversion of D to E for removing benzyl group.

Concept introduction:

Hydrogenolysis: Amine or alcohol reaction with H₂ in the presence of a transition

Metal catalyst gives the corresponding amine or alcohol.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The reagent has to be proposed for the conversion of E to bidisomide.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The reagent has to be proposed for the conversion of E to bidisomide.

Answer 14

(e)

Interpretation Introduction

Interpretation:

The possible stereoisomer’s has to be shown if the product is chiral.

Concept introduction:

Chiral:

A molecule is non superimposable on its mirror image is called chiral molecule. Four different atoms attached to a carbon atom is called chiral molecule.

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer.

Answer 15

(e)

Interpretation Introduction

Interpretation:

The possible stereoisomer’s has to be shown if the product is chiral.

Concept introduction:

Chiral:

A molecule is non superimposable on its mirror image is called chiral molecule. Four different atoms attached to a carbon atom is called chiral molecule.

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called diastereomers.

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer.

Answer 16

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Answer 17

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Answer 18

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Answer 19

Ch. 21.2 - Construct a Frost circle for a planar...Ch. 21.2 - Which compound gives a signal in the 1H-NMR...Ch. 21.2 - Prob. 21.3P Ch. 21.2 - Prob. 21.4P Ch. 21.3 - Prob. 21.5P Ch. 21.4 - Arrange these compounds in order of increasing...Ch. 21.4 - Prob. AQ Ch. 21.4 - Prob. BQ Ch. 21.4 - Prob. CQ Ch. 21.5 - Prob. 21.7P

The mechanism has to be proposed for the conversion of A to B and B to C, function of the sodium amide it be explained.

Solution Summary: The author explains the mechanism for the conversion of A to B and B to C, and the importance of introducing benzyl group in chloramine.

Interpretation:

The mechanism has to be proposed for the conversion of A to B and B to C, function of the sodium amide it be explained.

Interpretation:

The importance of introducing benzyl group in chloramine has to be explained for the conversion of B to C.

Interpretation:

The reagent has to be proposed for the conversion of D to E for removing benzyl group.

Concept introduction:

Hydrogenolysis: Amine or alcohol reaction with H₂ in the presence of a transition

Metal catalyst gives the corresponding amine or alcohol.

Interpretation:

The reagent has to be proposed for the conversion of E to bidisomide.

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Chapter 21 Solutions

The mechanism has to be proposed for the conversion of A to B and B to C, function of the sodium amide it be explained.

Solution Summary: The author explains the mechanism for the conversion of A to B and B to C, and the importance of introducing benzyl group in chloramine.

Interpretation: The mechanism has to be proposed for the conversion of A to B and B to C, function of the sodium amide it be explained.

Interpretation: The importance of introducing benzyl group in chloramine has to be explained for the conversion of B to C.

Interpretation: The reagent has to be proposed for the conversion of D to E for removing benzyl group. Concept introduction: Hydrogenolysis: Amine or alcohol reaction with H2 in the presence of a transition Metal catalyst gives the corresponding amine or alcohol.

Interpretation: The reagent has to be proposed for the conversion of E to bidisomide.

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Chapter 21 Solutions

Interpretation:

The mechanism has to be proposed for the conversion of A to B and B to C, function of the sodium amide it be explained.

Interpretation:

The importance of introducing benzyl group in chloramine has to be explained for the conversion of B to C.

Interpretation:

The reagent has to be proposed for the conversion of D to E for removing benzyl group.

Concept introduction:

Hydrogenolysis: Amine or alcohol reaction with H₂ in the presence of a transition

Metal catalyst gives the corresponding amine or alcohol.

Interpretation:

The reagent has to be proposed for the conversion of E to bidisomide.