General, Organic, and Biochemistry
10th Edition
ISBN: 9781260506198
Author: Denniston, Katherine
Publisher: MCGRAW-HILL HIGHER EDUCATION
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Chapter 21, Problem 21.55QP
Interpretation Introduction
Interpretation:
The type of reaction that is catalyzed by an enzyme that has the term kinase in its name has to be determined.
Concept Introduction:
The enzymes are the name given to the biological catalysts. Most of the enzymes are proteins. Proteins are the most abundant macromolecules in the cell. The structure of a protein is made up of 20 amino acids, they also are known as
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Identify and provide an explanation of the operational principles behind a Atomic Absorption Spectrometer (AAS). List the steps involved.
Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
Chapter 21 Solutions
General, Organic, and Biochemistry
Ch. 21.1 - Prob. 21.1QCh. 21.1 - Prob. 21.2QCh. 21.2 - Prob. 21.3QCh. 21.2 - Prob. 21.4QCh. 21.3 - Prob. 21.5QCh. 21.3 - Prob. 21.6QCh. 21.3 - Prob. 21.7QCh. 21.3 - Prob. 21.8QCh. 21.4 - Prob. 21.9QCh. 21.4 - Prob. 21.10Q
Ch. 21.6 - Prob. 21.11QCh. 21.6 - Prob. 21.12QCh. 21.7 - Prob. 21.13QCh. 21.7 - Prob. 21.14QCh. 21.7 - Prob. 21.15QCh. 21.7 - Prob. 21.16QCh. 21.7 - Prob. 21.17QCh. 21.7 - Prob. 21.18QCh. 21 - Prob. 21.19QPCh. 21 - Prob. 21.20QPCh. 21 - Prob. 21.21QPCh. 21 - Prob. 21.22QPCh. 21 - Prob. 21.23QPCh. 21 - Prob. 21.24QPCh. 21 - Prob. 21.25QPCh. 21 - Prob. 21.26QPCh. 21 - Prob. 21.27QPCh. 21 - Prob. 21.28QPCh. 21 - Write a balanced equation showing the hydrolysis...Ch. 21 - Prob. 21.30QPCh. 21 - Prob. 21.31QPCh. 21 - Prob. 21.32QPCh. 21 - Prob. 21.33QPCh. 21 - Prob. 21.34QPCh. 21 - Prob. 21.35QPCh. 21 - Prob. 21.36QPCh. 21 - Prob. 21.37QPCh. 21 - Prob. 21.38QPCh. 21 - Prob. 21.39QPCh. 21 - Prob. 21.40QPCh. 21 - Prob. 21.41QPCh. 21 - Prob. 21.42QPCh. 21 - Prob. 21.43QPCh. 21 - Prob. 21.44QPCh. 21 - Prob. 21.47QPCh. 21 - Prob. 21.48QPCh. 21 - Prob. 21.49QPCh. 21 - Prob. 21.50QPCh. 21 - Prob. 21.51QPCh. 21 - Prob. 21.52QPCh. 21 - Prob. 21.53QPCh. 21 - Prob. 21.54QPCh. 21 - Prob. 21.55QPCh. 21 - Prob. 21.56QPCh. 21 - Prob. 21.57QPCh. 21 - Prob. 21.58QPCh. 21 - Prob. 21.59QPCh. 21 - Prob. 21.60QPCh. 21 - Prob. 21.61QPCh. 21 - Prob. 21.62QPCh. 21 - Prob. 21.63QPCh. 21 - Prob. 21.64QPCh. 21 - Prob. 21.65QPCh. 21 - Prob. 21.66QPCh. 21 - Prob. 21.67QPCh. 21 - Prob. 21.68QPCh. 21 - Prob. 21.69QPCh. 21 - Prob. 21.70QPCh. 21 - Prob. 21.71QPCh. 21 - Prob. 21.72QPCh. 21 - Prob. 21.73QPCh. 21 - Prob. 21.74QPCh. 21 - Prob. 21.75QPCh. 21 - Prob. 21.76QPCh. 21 - Prob. 21.77QPCh. 21 - Prob. 21.78QPCh. 21 - Prob. 21.79QPCh. 21 - Prob. 21.80QPCh. 21 - Prob. 21.81QPCh. 21 - Prob. 21.82QPCh. 21 - Prob. 21.83QPCh. 21 - Prob. 21.84QPCh. 21 - Prob. 21.85QPCh. 21 - Prob. 21.86QPCh. 21 - Prob. 21.87QPCh. 21 - Prob. 21.88QPCh. 21 - Prob. 21.89QPCh. 21 - Prob. 21.90QPCh. 21 - Prob. 21.91QPCh. 21 - What enzyme in glycogen metabolism is stimulated...Ch. 21 - Prob. 21.93QPCh. 21 - Prob. 21.94QPCh. 21 - Prob. 21.95QPCh. 21 - Describe the function of the debranching enzyme in...Ch. 21 - Write a balanced equation for the reaction...Ch. 21 - Prob. 21.98QPCh. 21 - Prob. 21.99QPCh. 21 - Prob. 21.100QPCh. 21 - Prob. 6MCPCh. 21 - Prob. 7MCPCh. 21 - Prob. 8MCPCh. 21 - Prob. 9MCPCh. 21 - Prob. 10MCP
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