(a) Interpretation: The oxidation state and the identity of M ion in the complex [ MCl 4 ] 2 − needs to be determined. Concept introduction: When considering transition metals , some has partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

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Answer 1

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Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 21, Problem 21.129SP

Interpretation Introduction

(a)

Interpretation:

The oxidation state and the identity of M ion in the complex [MCl4]2− needs to be determined.

Concept introduction:

When considering transition metals, some has partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

Interpretation Introduction

(b)

Interpretation:

The valence bond orbital diagram for two possible ions needs to be drawn.

Concept introduction:

According to the valence bond theory, there is an electrons pair of opposite spin which are shared by two atoms as a result of orbital overlap. Here, a coordination complex occurs as a result of the overlapping of filled ligand orbital with a pair of electrons and empty hybrid orbital of the metal.

Interpretation Introduction

(c)

Interpretation:

The ion which is more likely to exist according to their common oxidation states needs to be determined.

Concept introduction:

Transition metals show different oxidation states. When considering a transition metal ion, it is more likely to exit their most stable oxidation state.

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Answer 2

Question

Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 21, Problem 21.129SP

Interpretation Introduction

(a)

Interpretation:

The oxidation state and the identity of M ion in the complex [MCl4]2− needs to be determined.

Concept introduction:

When considering transition metals, some has partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

Interpretation Introduction

(b)

Interpretation:

The valence bond orbital diagram for two possible ions needs to be drawn.

Concept introduction:

According to the valence bond theory, there is an electrons pair of opposite spin which are shared by two atoms as a result of orbital overlap. Here, a coordination complex occurs as a result of the overlapping of filled ligand orbital with a pair of electrons and empty hybrid orbital of the metal.

Interpretation Introduction

(c)

Interpretation:

The ion which is more likely to exist according to their common oxidation states needs to be determined.

Concept introduction:

Transition metals show different oxidation states. When considering a transition metal ion, it is more likely to exit their most stable oxidation state.

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Answer 3

Question

Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 21, Problem 21.129SP

Interpretation Introduction

(a)

Interpretation:

The oxidation state and the identity of M ion in the complex [MCl4]2− needs to be determined.

Concept introduction:

When considering transition metals, some has partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

Interpretation Introduction

(b)

Interpretation:

The valence bond orbital diagram for two possible ions needs to be drawn.

Concept introduction:

According to the valence bond theory, there is an electrons pair of opposite spin which are shared by two atoms as a result of orbital overlap. Here, a coordination complex occurs as a result of the overlapping of filled ligand orbital with a pair of electrons and empty hybrid orbital of the metal.

Interpretation Introduction

(c)

Interpretation:

The ion which is more likely to exist according to their common oxidation states needs to be determined.

Concept introduction:

Transition metals show different oxidation states. When considering a transition metal ion, it is more likely to exit their most stable oxidation state.

Expert Solution & Answer

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Answer 4

Question

Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 21, Problem 21.129SP

Interpretation Introduction

(a)

Interpretation:

The oxidation state and the identity of M ion in the complex [MCl4]2− needs to be determined.

Concept introduction:

When considering transition metals, some has partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

Interpretation Introduction

(b)

Interpretation:

The valence bond orbital diagram for two possible ions needs to be drawn.

Concept introduction:

According to the valence bond theory, there is an electrons pair of opposite spin which are shared by two atoms as a result of orbital overlap. Here, a coordination complex occurs as a result of the overlapping of filled ligand orbital with a pair of electrons and empty hybrid orbital of the metal.

Interpretation Introduction

(c)

Interpretation:

The ion which is more likely to exist according to their common oxidation states needs to be determined.

Concept introduction:

Transition metals show different oxidation states. When considering a transition metal ion, it is more likely to exit their most stable oxidation state.

Expert Solution & Answer

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See solution

Answer 5

Chapter 21, Problem 21.129SP

Interpretation Introduction

(a)

Interpretation:

The oxidation state and the identity of M ion in the complex [MCl4]2− needs to be determined.

Concept introduction:

When considering transition metals, some has partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

Interpretation Introduction

(b)

Interpretation:

The valence bond orbital diagram for two possible ions needs to be drawn.

Concept introduction:

According to the valence bond theory, there is an electrons pair of opposite spin which are shared by two atoms as a result of orbital overlap. Here, a coordination complex occurs as a result of the overlapping of filled ligand orbital with a pair of electrons and empty hybrid orbital of the metal.

Interpretation Introduction

(c)

Interpretation:

The ion which is more likely to exist according to their common oxidation states needs to be determined.

Concept introduction:

Transition metals show different oxidation states. When considering a transition metal ion, it is more likely to exit their most stable oxidation state.

Answer 6

Chapter 21, Problem 21.129SP

Interpretation Introduction

(a)

Interpretation:

The oxidation state and the identity of M ion in the complex [MCl4]2− needs to be determined.

Concept introduction:

When considering transition metals, some has partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

Answer 7

Chapter 21, Problem 21.129SP

Interpretation Introduction

(a)

Interpretation:

The oxidation state and the identity of M ion in the complex [MCl4]2− needs to be determined.

Concept introduction:

When considering transition metals, some has partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The valence bond orbital diagram for two possible ions needs to be drawn.

Concept introduction:

According to the valence bond theory, there is an electrons pair of opposite spin which are shared by two atoms as a result of orbital overlap. Here, a coordination complex occurs as a result of the overlapping of filled ligand orbital with a pair of electrons and empty hybrid orbital of the metal.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The valence bond orbital diagram for two possible ions needs to be drawn.

Concept introduction:

According to the valence bond theory, there is an electrons pair of opposite spin which are shared by two atoms as a result of orbital overlap. Here, a coordination complex occurs as a result of the overlapping of filled ligand orbital with a pair of electrons and empty hybrid orbital of the metal.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The ion which is more likely to exist according to their common oxidation states needs to be determined.

Concept introduction:

Transition metals show different oxidation states. When considering a transition metal ion, it is more likely to exit their most stable oxidation state.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The ion which is more likely to exist according to their common oxidation states needs to be determined.

Concept introduction:

Transition metals show different oxidation states. When considering a transition metal ion, it is more likely to exit their most stable oxidation state.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 21 - Prob. 21.1P Ch. 21 - Prob. 21.2A Ch. 21 - Prob. 21.3P Ch. 21 - Prob. 21.4A Ch. 21 - Prob. 21.5P Ch. 21 - Prob. 21.6A Ch. 21 - Prob. 21.7P Ch. 21 - Prob. 21.8A Ch. 21 - Which of the following [Pt( H 2O)2Cl3Br]...Ch. 21 - Prob. 21.10A

Solution Summary: The author explains the oxidation state and the identity of M ion in the complex.

Concept explainers

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Chapter 21 Solutions

Solution Summary: The author explains the oxidation state and the identity of M ion in the complex.

Concept explainers

(c) Interpretation: The ion which is more likely to exist according to their common oxidation states needs to be determined. Concept introduction: Transition metals show different oxidation states. When considering a transition metal ion, it is more likely to exit their most stable oxidation state.

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Chapter 21 Solutions