Bundle: Introduction to General, Organic and Biochemistry, 11th + OWLv2, 4 terms (24 months) Printed Access Card
11th Edition
ISBN: 9781305705159
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Chapter 21, Problem 21.10P
Interpretation Introduction
Interpretation:
The reason as to why the melting points of the saturated fatty acids increase on moving from lauric acid to stearic acid is to be stated.
Concept Introduction:
Fatty acids contain carboxylic group at the end of a long hydrocarbon chain. On the basis of the presence of double bonds, there are two types of fatty acids, saturated fatty acid and unsaturated fatty acid. The double bonds between carbon atoms are absent in saturated fatty acids, whereas unsaturated fatty acids possess at least one double bond between carbon atoms.
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Using the bond energy values, calculate the energy that must be supplied or is released upon the polymerization of 755 monomers. If energy must be supplied, provide a positive number; if energy is released, provide a negative number. Hint: Avogadro’s number is 6.02 × 1023.
-AG|F=2E|V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
Acidic solution
-0.93
+0.38
-0.51 -0.06
H3PO4 →H4P206 H3PO3 H3PO2 → P→ PH3
-0.28
-0.50
→
-0.50
Basic solution
3-1.12
-1.57
-2.05 -0.89
PO HPO →→H2PO2 P PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P2O6 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5 PH,
0.0
-0.5-
2 3 9 3
-1.5
-2.0
Pa
H,PO
H,PO
H,PO
-3
-1 0
2
4
Oxidation state, N
2
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
c) Elemental phosphorus tends to disproportionate under basic conditions. Use data in…
These two reactions appear to start with the same starting materials but result in different products. How do the chemicals know which product to form? Are both products formed, or is there some information missing that will direct them a particular way?
Chapter 21 Solutions
Bundle: Introduction to General, Organic and Biochemistry, 11th + OWLv2, 4 terms (24 months) Printed Access Card
Ch. 21.8 - Prob. 21.1PCh. 21 - 21-2 Why are fats a good source of energy for...Ch. 21 - 21-3 Proteins, nucleic acids, and carbohydrates...Ch. 21 - Prob. 21.4PCh. 21 - Prob. 21.5PCh. 21 - Prob. 21.6PCh. 21 - 21-7 For the diglycerides in Problem 21-6, predict...Ch. 21 - 21-8 Predict which acid in each pair has the...Ch. 21 - Prob. 21.9PCh. 21 - Prob. 21.10P
Ch. 21 - Prob. 21.11PCh. 21 - Prob. 21.12PCh. 21 - 21-13 Rank the following in order of increasing...Ch. 21 - Prob. 21.14PCh. 21 - 21-15 Name the products of the saponification of...Ch. 21 - Prob. 21.16PCh. 21 - Prob. 21.17PCh. 21 - Prob. 21.18PCh. 21 - Prob. 21.19PCh. 21 - Prob. 21.20PCh. 21 - Prob. 21.21PCh. 21 - Prob. 21.22PCh. 21 - Prob. 21.23PCh. 21 - 21-24 In what sense is the active transport of K+...Ch. 21 - Prob. 21.25PCh. 21 - Prob. 21.26PCh. 21 - Prob. 21.27PCh. 21 - Prob. 21.28PCh. 21 - 21-29 Name all the groups of complex lipids that...Ch. 21 - Prob. 21.30PCh. 21 - Prob. 21.31PCh. 21 - Prob. 21.32PCh. 21 - Prob. 21.33PCh. 21 - Prob. 21.34PCh. 21 - Prob. 21.35PCh. 21 - Prob. 21.36PCh. 21 - Prob. 21.37PCh. 21 - Prob. 21.38PCh. 21 - 21-39 How does VLDL become LDL?Ch. 21 - Prob. 21.40PCh. 21 - Prob. 21.41PCh. 21 - Prob. 21.42PCh. 21 - Prob. 21.43PCh. 21 - 21-44 Describe the difference in structure between...Ch. 21 - Prob. 21.45PCh. 21 - Prob. 21.46PCh. 21 - Prob. 21.47PCh. 21 - 21-48 List all of the functional groups that make...Ch. 21 - 21-49 Explain how the constant elimination of bile...Ch. 21 - Prob. 21.50PCh. 21 - Prob. 21.51PCh. 21 - 21-52 What are the chemical and physiological...Ch. 21 - 21-53 How does aspirin, an anti-inflammatory drug,...Ch. 21 - Prob. 21.54PCh. 21 - Prob. 21.55PCh. 21 - Prob. 21.56PCh. 21 - Prob. 21.57PCh. 21 - Prob. 21.58PCh. 21 - Prob. 21.59PCh. 21 - 21-60 (Chemical Connections 21C) Why were Mark...Ch. 21 - Prob. 21.61PCh. 21 - Prob. 21.62PCh. 21 - Prob. 21.63PCh. 21 - Prob. 21.64PCh. 21 - Prob. 21.65PCh. 21 - Prob. 21.66PCh. 21 - Prob. 21.67PCh. 21 - 21-68 What is the role of taurine in lipid...Ch. 21 - Prob. 21.69PCh. 21 - 21-70 How many different triglycerides can you...Ch. 21 - Prob. 21.71PCh. 21 - Prob. 21.72PCh. 21 - Prob. 21.73PCh. 21 - Prob. 21.74PCh. 21 - Prob. 21.75PCh. 21 - 21-76 Which part of LDL interacts with the LDL...Ch. 21 - Prob. 21.77PCh. 21 - Prob. 21.78PCh. 21 - Prob. 21.79PCh. 21 - Prob. 21.80PCh. 21 - Prob. 21.81PCh. 21 - 21-82 Suggest a reason why the same protein system...Ch. 21 - Prob. 21.83PCh. 21 - Prob. 21.84PCh. 21 - 21-85 Which of the following statements is (are)...Ch. 21 - Prob. 21.86PCh. 21 - 21-87 Which statements are consistent with the...Ch. 21 - Prob. 21.88PCh. 21 - Prob. 21.89PCh. 21 - 21-90 To what extent do lipids and carbohydrates...Ch. 21 - Prob. 21.91PCh. 21 - Prob. 21.92PCh. 21 - Prob. 21.93PCh. 21 - Prob. 21.94PCh. 21 - Prob. 21.95PCh. 21 - Prob. 21.96PCh. 21 - Prob. 21.97PCh. 21 - Prob. 21.98PCh. 21 - Prob. 21.99PCh. 21 - 21-100 What are the functions of a cell membrane?...Ch. 21 - 21-101 Glycerophospholipids tend to have both a...Ch. 21 - Prob. 21.102P
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