OWLv2 6-Months Printed Access Card for Kotz/Treichel/Townsend's Chemistry & Chemical Reactivity, 9th, 9th Edition
OWLv2 6-Months Printed Access Card for Kotz/Treichel/Townsend's Chemistry & Chemical Reactivity, 9th, 9th Edition
9th Edition
ISBN: 9781285460680
Author: Kotz, Treichel, Townsend
Publisher: Cengage Learning
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Chapter 21, Problem 124SCQ

(a)

Interpretation Introduction

Interpretation:

To predict the number of tin and oxide ions present in per unit cell of tin oxide.

Concept introduction:

The formula for tin oxide is SnO2. Tin has an oxidation number of +4 in this compound. SnO2 also known as, cassiterite is the main ore of tin.

Tin oxides crystallizes in a rutile like unit cell in which Sn4+ and O2 ions are present. The compound should be electrically neutral.

(b)

Interpretation Introduction

Interpretation:

Check whether it is thermodynamically feasible to transform solid SnO2 into liquid SnCl4 by reactionof the oxide with gaseous HCl or not. The equailibrium constant for this raction at 250C is to be determined.

Concept introduction:

The free energy change is expressed as,

ΔrG°=nΔfG°(products)nΔfG°(reactants)

The positive value of ΔrG° indicates the thermodynamic unfeasibility of a reaction.

If the free energy change value is known then the equilibrium constant can be determined using the following equation.

Kp=eΔrGRT

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Chapter 21 Solutions

OWLv2 6-Months Printed Access Card for Kotz/Treichel/Townsend's Chemistry & Chemical Reactivity, 9th, 9th Edition

Ch. 21.11 - The best catalysts used to accelerate the...Ch. 21.11 - Prob. 2.5ACPCh. 21 - Which of the following formulas is incorrect? (a)...Ch. 21 - The reaction of elemental phosphorus and excess...Ch. 21 - Like sulfur, selenium forms compounds in several...Ch. 21 - Prob. 4PSCh. 21 - Give examples of two basic oxides. Write equations...Ch. 21 - Prob. 6PSCh. 21 - Prob. 7PSCh. 21 - Prob. 8PSCh. 21 - Prob. 9PSCh. 21 - Prob. 10PSCh. 21 - For the product of the reaction you selected in...Ch. 21 - For the product of the reaction you selected in...Ch. 21 - Prob. 13PSCh. 21 - Prob. 14PSCh. 21 - Place the following oxides in order of increasing...Ch. 21 - Place the following oxides in order of increasing...Ch. 21 - Prob. 17PSCh. 21 - Prob. 18PSCh. 21 - Prob. 19PSCh. 21 - Prob. 20PSCh. 21 - Prob. 21PSCh. 21 - Prob. 22PSCh. 21 - Prob. 23PSCh. 21 - Prob. 24PSCh. 21 - Prob. 25PSCh. 21 - Prob. 26PSCh. 21 - Prob. 27PSCh. 21 - The compound Na2O2 consists of (a) two Na+ ions...Ch. 21 - Prob. 29PSCh. 21 - Write balanced equations for the reaction of...Ch. 21 - Prob. 31PSCh. 21 - (a) Write equations for the half-reactions that...Ch. 21 - Prob. 33PSCh. 21 - Prob. 34PSCh. 21 - When magnesium bums in air, it forms both an oxide...Ch. 21 - Prob. 36PSCh. 21 - Prob. 37PSCh. 21 - Prob. 38PSCh. 21 - Calcium oxide, CaO, is used to remove SO2 from...Ch. 21 - Prob. 40PSCh. 21 - Prob. 41PSCh. 21 - The element below aluminum in Group 3A is gallium,...Ch. 21 - Prob. 43PSCh. 21 - The boron trihalides (except BF3) hydrolyze...Ch. 21 - When boron hydrides burn in air, the reactions are...Ch. 21 - Prob. 46PSCh. 21 - Write balanced equations for the reactions of...Ch. 21 - Prob. 48PSCh. 21 - Prob. 49PSCh. 21 - Alumina, Al2O3, is amphoteric. Among examples of...Ch. 21 - Prob. 51PSCh. 21 - Prob. 52PSCh. 21 - Prob. 53PSCh. 21 - Silicon and oxygen form a six-membered ring in the...Ch. 21 - Describe the structure of pyroxenes (see page...Ch. 21 - Describe how ultrapure silicon can be produced...Ch. 21 - Prob. 57PSCh. 21 - Prob. 58PSCh. 21 - Prob. 59PSCh. 21 - Prob. 60PSCh. 21 - Prob. 61PSCh. 21 - Prob. 62PSCh. 21 - Prob. 63PSCh. 21 - The overall reaction involved in the industrial...Ch. 21 - Prob. 65PSCh. 21 - Prob. 66PSCh. 21 - Prob. 67PSCh. 21 - Prob. 68PSCh. 21 - Prob. 69PSCh. 21 - Which statement about oxygen is not true? (a)...Ch. 21 - Prob. 71PSCh. 21 - Prob. 72PSCh. 21 - Prob. 73PSCh. 21 - Sulfur forms a range of compounds with fluorine....Ch. 21 - Prob. 75PSCh. 21 - Which of the following statements is not correct?...Ch. 21 - The halogen oxides and oxoanions are good...Ch. 21 - Prob. 78PSCh. 21 - Bromine is obtained from brine wells. The process...Ch. 21 - Prob. 80PSCh. 21 - Prob. 81PSCh. 21 - Halogens combine with one another to produce...Ch. 21 - Prob. 83PSCh. 21 - Prob. 84PSCh. 21 - The standard enthalpy of formation of XeF4 is 218...Ch. 21 - Draw the Lewis electron dot structure for XeO3F2....Ch. 21 - Prob. 87PSCh. 21 - Prob. 88PSCh. 21 - Prob. 89GQCh. 21 - Prob. 90GQCh. 21 - Consider the chemistries of the elements...Ch. 21 - When BCl3 gas is passed through an electric...Ch. 21 - Prob. 93GQCh. 21 - Prob. 94GQCh. 21 - Prob. 95GQCh. 21 - Prob. 96GQCh. 21 - Prob. 97GQCh. 21 - Prob. 98GQCh. 21 - Prob. 99GQCh. 21 - Prob. 100GQCh. 21 - Prob. 101GQCh. 21 - Prob. 102GQCh. 21 - Prob. 103GQCh. 21 - Prob. 105GQCh. 21 - Prob. 106GQCh. 21 - A Boron and hydrogen form an extensive family of...Ch. 21 - In 1774, C. Scheele obtained a gas by reacting...Ch. 21 - The chemistry of gallium: (a) Gallium hydroxide,...Ch. 21 - Prob. 111GQCh. 21 - Prob. 112GQCh. 21 - Prob. 113GQCh. 21 - Prob. 114GQCh. 21 - Prob. 115ILCh. 21 - Prob. 116ILCh. 21 - Prob. 117ILCh. 21 - Prob. 118ILCh. 21 - Prob. 119ILCh. 21 - Prob. 120ILCh. 21 - Prob. 121SCQCh. 21 - Prob. 122SCQCh. 21 - Prob. 123SCQCh. 21 - Prob. 124SCQCh. 21 - Prob. 125SCQCh. 21 - Prob. 126SCQCh. 21 - Prob. 127SCQCh. 21 - Prob. 128SCQCh. 21 - Comparing the chemistry of carbon and silicon. (a)...Ch. 21 - Prob. 130SCQCh. 21 - Xenon trioxide, XeO3, reacts with aqueous base to...
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