Chemistry & Chemical Reactivity
Chemistry & Chemical Reactivity
9th Edition
ISBN: 9781305176461
Author: Kotz
Publisher: Cengage
Question
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Chapter 21, Problem 110SCQ

(a)

Interpretation Introduction

Interpretation:

To estimate the mass of lime required to precipitate magneisum from sea water.

Concept introduction:

Magnesium is an alkaline earth metal and is prsent in sea water. The magnesium present in sea water can be extracted by precipitating it with either CaO or Ca(OH)2. The pure metal from the salt obtained can be obtained by the process of electrolysis.

Numberofmoles=MassMolecularmass

Mass=Numberofmoles×Molecularmass

(b)

Interpretation Introduction

Interpretation:

To estimate the mass of product produced at anode and cathode on electrolysis of MgCl2 and also total number of Faradays of electricity used.

Concept introduction:

Magnesium is an alkaline earth metal and is prsent in sea water. The magnesium present in sea water can be extracted by precipitating it with either CaO or Ca(OH)2. The pure metal from the salt obtained can be obtained by the process of electrolysis.

The reduction happens at cathode

The oxidation happens at anode.

Numberofmoles=MassMolecularmass

Mass=Numberofmoles×Molecularmass

The total number of Faradays of electricity used is calculated by the number of electrons involved in the reaction

(c)

Interpretation Introduction

Interpretation:

To estimate how many Joules are required per mole for the given industrial process

Concept introduction:

Magnesium is an alkaline earth metal and is prsent in sea water. The magnesium present in sea water can be extracted by precipitating it with either CaO or Ca(OH)2. The pure metal from the salt obtained can be obtained by the process of electrolysis.

Numberofmoles=MassMolecularmass

Mass=Numberofmoles×Molecularmass

1kWh=1kilowatthour=3.6×106J

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2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled** Peak Chemical Shift (d) 5.7 1 Multiplicity multiplate .......... 5.04 double of doublet 2 4.98 double of doublet 3 4.05 doublet of quartet 4 5 LO 3.80 quartet 1.3 doublet 6 Peak Chemical Shift (d) Multiplicity
Interpreting NMR spectra is a skill that often requires some amount of practice, which, in turn, necessitates access to a collection of NMR spectra. Beyond Labz Organic Synthesis and Organic Qualitative Analysis have spectral libraries containing over 700 1H NMR spectra. In this assignment, you will take advantage of this by first predicting the NMR spectra for two closely related compounds and then checking your predictions by looking up the actual spectra in the spectra library. After completing this assignment, you may wish to select other compounds for additional practice. 1. Write the IUPAC names for the following two structures: Question 2 Question 3 2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled**
11:14 ... worksheets.beyondlabz.com 3. To check your predictions, click this link for Interpreting NMR Spectra 1. You will see a list of all the - compounds in the spectra library in alphabetical order by IUPAC name. Hovering over a name in the list will show the structure on the chalkboard. The four buttons on the top of the Spectra tab in the tray are used to select the different spectroscopic techniques for the selected compound. Make sure the NMR button has been selected. 4. Scroll through the list of names to find the names for the two compounds you have been given and click on the name to display the NMR spectrum for each. In the NMR tables below, list the chemical shift, the splitting, and the number of hydrogens associated with each peak for each compound. Compare your answers to your predictions. **Not all slots must be filled** Peak Chemical Shift (d) Multiplicity 1 2 3 4 5

Chapter 21 Solutions

Chemistry & Chemical Reactivity

Ch. 21.8 - Prob. 4QCh. 21.8 - Prob. 3RCCh. 21.11 - Prob. 1QCh. 21.11 - Prob. 2QCh. 21 - Give examples of two basic oxides. Write equations...Ch. 21 - Prob. 2PSCh. 21 - Prob. 3PSCh. 21 - Prob. 4PSCh. 21 - Prob. 5PSCh. 21 - Prob. 6PSCh. 21 - For the product of the reaction you selected in...Ch. 21 - For the product of the reaction you selected in...Ch. 21 - Prob. 9PSCh. 21 - Prob. 10PSCh. 21 - Place the following oxides in order of increasing...Ch. 21 - Place the following oxides in order of increasing...Ch. 21 - Prob. 13PSCh. 21 - Prob. 14PSCh. 21 - Prob. 15PSCh. 21 - Prob. 16PSCh. 21 - Prob. 17PSCh. 21 - Prob. 18PSCh. 21 - Prob. 19PSCh. 21 - Prob. 20PSCh. 21 - Prob. 21PSCh. 21 - Write balanced equations for the reaction of...Ch. 21 - Prob. 23PSCh. 21 - (a) Write equations for the half-reactions that...Ch. 21 - When magnesium bums in air, it forms both an oxide...Ch. 21 - Prob. 26PSCh. 21 - Prob. 27PSCh. 21 - Prob. 28PSCh. 21 - Calcium oxide, CaO, is used to remove SO2 from...Ch. 21 - Prob. 30PSCh. 21 - Prob. 31PSCh. 21 - The boron trihalides (except BF3) hydrolyze...Ch. 21 - When boron hydrides burn in air, the reactions are...Ch. 21 - Prob. 34PSCh. 21 - Write balanced equations for the reactions of...Ch. 21 - Prob. 36PSCh. 21 - Prob. 37PSCh. 21 - Alumina, Al2O3, is amphoteric. Among examples of...Ch. 21 - Prob. 39PSCh. 21 - Prob. 40PSCh. 21 - Describe the structure of pyroxenes (see page...Ch. 21 - Describe how ultrapure silicon can be produced...Ch. 21 - Prob. 43PSCh. 21 - Prob. 44PSCh. 21 - Prob. 45PSCh. 21 - Prob. 46PSCh. 21 - Prob. 47PSCh. 21 - The overall reaction involved in the industrial...Ch. 21 - Prob. 49PSCh. 21 - Prob. 50PSCh. 21 - Prob. 51PSCh. 21 - Prob. 52PSCh. 21 - Prob. 53PSCh. 21 - Prob. 54PSCh. 21 - Prob. 55PSCh. 21 - Sulfur forms a range of compounds with fluorine....Ch. 21 - The halogen oxides and oxoanions are good...Ch. 21 - Prob. 58PSCh. 21 - Bromine is obtained from brine wells. The process...Ch. 21 - Prob. 60PSCh. 21 - Prob. 61PSCh. 21 - Halogens combine with one another to produce...Ch. 21 - The standard enthalpy of formation of XeF4 is 218...Ch. 21 - Draw the Lewis electron dot structure for XeO3F2....Ch. 21 - Prob. 65PSCh. 21 - Prob. 66PSCh. 21 - Prob. 67GQCh. 21 - Prob. 68GQCh. 21 - Consider the chemistries of the elements...Ch. 21 - When BCl3 gas is passed through an electric...Ch. 21 - Prob. 71GQCh. 21 - Prob. 72GQCh. 21 - Prob. 73GQCh. 21 - Prob. 74GQCh. 21 - Prob. 75GQCh. 21 - Prob. 76GQCh. 21 - Prob. 77GQCh. 21 - Prob. 78GQCh. 21 - Prob. 79GQCh. 21 - Prob. 80GQCh. 21 - Prob. 81GQCh. 21 - Prob. 83GQCh. 21 - Prob. 84GQCh. 21 - A Boron and hydrogen form an extensive family of...Ch. 21 - In 1774, C. Scheele obtained a gas by reacting...Ch. 21 - What current must be used in a Downs cell...Ch. 21 - The chemistry of gallium: (a) Gallium hydroxide,...Ch. 21 - Prob. 89GQCh. 21 - Prob. 90GQCh. 21 - Prob. 91GQCh. 21 - Prob. 92GQCh. 21 - Prob. 93ILCh. 21 - Prob. 94ILCh. 21 - Prob. 95ILCh. 21 - Prob. 96ILCh. 21 - Prob. 97ILCh. 21 - Prob. 98ILCh. 21 - Prob. 99SCQCh. 21 - Prob. 100SCQCh. 21 - Prob. 101SCQCh. 21 - Prob. 102SCQCh. 21 - Prob. 103SCQCh. 21 - Prob. 104SCQCh. 21 - Prob. 105SCQCh. 21 - Prob. 106SCQCh. 21 - Prob. 107SCQCh. 21 - Prob. 108SCQCh. 21 - Prob. 109SCQCh. 21 - Prob. 110SCQCh. 21 - Comparing the chemistry of carbon and silicon. (a)...Ch. 21 - Prob. 112SCQCh. 21 - Xenon trioxide, XeO3, reacts with aqueous base to...
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