EBK ORGANIC CHEMISTRY-PRINT COMPANION (
EBK ORGANIC CHEMISTRY-PRINT COMPANION (
4th Edition
ISBN: 9781119776741
Author: Klein
Publisher: WILEY CONS
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Chapter 20.10, Problem 20CC
Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

  • Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.
  • Fischer esterification: By refluxing carboxylic acids with alcohols in presence of acid catalyst it gives ester as product. The reaction first described by “Emil Fischer” and this reaction is known as “Fischer esterification” reaction.
  •  Ester formation: carboxylic acids reacts with alkyl halides in presence of strong base it gives ester as product.

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Draw the major product of the Claisen condensation reaction between two molecules of this ester. Ignore inorganic byproducts. Incorrect, 5 attempts remaining 1. NaOCH3/CH3OH 2. Acidic workup Select to Draw O Incorrect, 5 attempts remaining The total number of carbons in the parent chain is incorrect. Review the reaction conditions including starting materials and/or intermediate structures and recount the number of carbon atoms in the parent chain of your structure. OK
Using a cell of known pathlength b = 1.25115 x 10-3 cm, a water absorption spectrum was measured. The band at 1645 cm-1, assigned to the O-H bending, showed an absorbance, A, of 1.40. a) Assuming that water density is 1.00 g/mL, calculate the water molar concentration c (hint: M= mole/L) b) Calculate the molar absorptivity, a, of the 1645 cm-1 band c) The transmitted light, I, can be written as I= Ioexp(-xb), where x is the absorption coefficient (sometimes designated as alpha), Io is the input light, and b is the cell pathlength. Prove that x= (ln10)*x*c d) Calculate x for the 1645 cm-1 band
Convert 1.38 eV into wavelength (nm) and wavenumber (cm-1) (c = 2.998 x 108 m/s; h = 6.626 x 10-34 J*s).

Chapter 20 Solutions

EBK ORGANIC CHEMISTRY-PRINT COMPANION (

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