EBK ORGANIC CHEMISTRY-PRINT COMPANION (
EBK ORGANIC CHEMISTRY-PRINT COMPANION (
4th Edition
ISBN: 9781119776741
Author: Klein
Publisher: WILEY CONS
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Chapter 20, Problem 42PP

(a)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Hydroboration-oxidation: Generally alkenes react with boron followed by hydrogen peroxide and in presence of base like sodium hydroxide it gives corresponding alcohol and it follows anti-Markovnikoff rule.

Anti-Markovnikoff Rule: Alkenes belong to the group of unsaturated hydrocarbons that is one molecule of alkene contains at least one double bond. Due to the presence of pi electrons, they show addition reactions attacks carbon-carbon double bond to form the additional products.

To find: The reagent for the given transformation.

(b)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Hydroboration-oxidation: Generally alkenes react with boron followed by hydrogen peroxide and in presence of base like sodium hydroxide it gives corresponding alcohol and it follows anti-Markovnikoff rule.

Anti-Markovnikoff Rule: Alkenes belong to the group of unsaturated hydrocarbons that is one molecule of alkene contains at least one double bond. Due to the presence of pi electrons, they show addition reactions attacks carbon-carbon double bond to form the additional products.

To find: The reagent for the given transformation.

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Part I. Problem solving. Include all necessary calculations 13 provide plots and graphs. Complexation wl diphenyl carbazide (OPC) in acidic media is another type of sensitive photometric method used for the analysis of aqueous. hexavalent chromium. At 540nm the cherry-red complex as a result of DPC reaction w/ chromium can be photometrically measured. at this wavelength. - a 25mL The UV-vis analysis for the determination of nexavalent chromium in ground water sample is given below. The experiment was based on external calibration method w/ each measurement sample prepared are as follows lab sample analysis contained the standard 100 ppb croy cor groundwater sample, volumes used as indicated below), 12.50 mL of 0.02 M H2Soy and 5.50 ml of 100 ppm DPC (wi water to adjust final volume to 25-ml). The main stripping method was square wave voltammetry, following the conditions set in the main ASV experiment. Standard 100 Volumetric Groundwater H2SO4 0.20 M, flask Sample, mL ppb CrO4*, 100…

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