The mechanism for the elimination step in the Wohl degradation is to be drawn. Concept Introduction: In Wohl degradation, the first step is aldose carbonyl group is converted to the oxime. Then oxime is dehydrated by an acetic anhydride to give the nitrile (a cyanohydrin). The formation of cyanohydrin is reversible in nature. It undergoes a basic hydrolysis to give aldose with one less carbon with a loss of HCN molecule.

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Answer 1

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Chapter 20, Problem 67P

Interpretation Introduction

Interpretation:

The mechanism for the elimination step in the Wohl degradation is to be drawn.

Concept Introduction:

In Wohl degradation, the first step is aldose carbonyl group is converted to the oxime. Then oxime is dehydrated by an acetic anhydride to give the nitrile (a cyanohydrin). The formation of cyanohydrin is reversible in nature. It undergoes a basic hydrolysis to give aldose with one less carbon with a loss of HCN molecule.

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Answer 2

Question

Chapter 20, Problem 67P

Interpretation Introduction

Interpretation:

The mechanism for the elimination step in the Wohl degradation is to be drawn.

Concept Introduction:

In Wohl degradation, the first step is aldose carbonyl group is converted to the oxime. Then oxime is dehydrated by an acetic anhydride to give the nitrile (a cyanohydrin). The formation of cyanohydrin is reversible in nature. It undergoes a basic hydrolysis to give aldose with one less carbon with a loss of HCN molecule.

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Answer 3

Question

Chapter 20, Problem 67P

Interpretation Introduction

Interpretation:

The mechanism for the elimination step in the Wohl degradation is to be drawn.

Concept Introduction:

In Wohl degradation, the first step is aldose carbonyl group is converted to the oxime. Then oxime is dehydrated by an acetic anhydride to give the nitrile (a cyanohydrin). The formation of cyanohydrin is reversible in nature. It undergoes a basic hydrolysis to give aldose with one less carbon with a loss of HCN molecule.

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Answer 4

Question

Chapter 20, Problem 67P

Interpretation Introduction

Interpretation:

The mechanism for the elimination step in the Wohl degradation is to be drawn.

Concept Introduction:

In Wohl degradation, the first step is aldose carbonyl group is converted to the oxime. Then oxime is dehydrated by an acetic anhydride to give the nitrile (a cyanohydrin). The formation of cyanohydrin is reversible in nature. It undergoes a basic hydrolysis to give aldose with one less carbon with a loss of HCN molecule.

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Answer 5

Chapter 20, Problem 67P

Interpretation Introduction

Interpretation:

The mechanism for the elimination step in the Wohl degradation is to be drawn.

Concept Introduction:

In Wohl degradation, the first step is aldose carbonyl group is converted to the oxime. Then oxime is dehydrated by an acetic anhydride to give the nitrile (a cyanohydrin). The formation of cyanohydrin is reversible in nature. It undergoes a basic hydrolysis to give aldose with one less carbon with a loss of HCN molecule.

Answer 6

Chapter 20, Problem 67P

Interpretation Introduction

Interpretation:

The mechanism for the elimination step in the Wohl degradation is to be drawn.

Concept Introduction:

In Wohl degradation, the first step is aldose carbonyl group is converted to the oxime. Then oxime is dehydrated by an acetic anhydride to give the nitrile (a cyanohydrin). The formation of cyanohydrin is reversible in nature. It undergoes a basic hydrolysis to give aldose with one less carbon with a loss of HCN molecule.

Answer 7

Chapter 20, Problem 67P

Interpretation Introduction

Interpretation:

The mechanism for the elimination step in the Wohl degradation is to be drawn.

Concept Introduction:

In Wohl degradation, the first step is aldose carbonyl group is converted to the oxime. Then oxime is dehydrated by an acetic anhydride to give the nitrile (a cyanohydrin). The formation of cyanohydrin is reversible in nature. It undergoes a basic hydrolysis to give aldose with one less carbon with a loss of HCN molecule.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 20.1 - Prob. 1P Ch. 20.2 - Prob. 2P Ch. 20.2 - Prob. 3P Ch. 20.3 - Prob. 4P Ch. 20.3 - Prob. 5P Ch. 20.3 - Prob. 6P Ch. 20.4 - Prob. 7P Ch. 20.4 - Prob. 8P Ch. 20.5 - Prob. 9P Ch. 20.5 - Prob. 10P

Solution Summary: The author explains the mechanism for the elimination step in the Wohl degradation.

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