(a) How much heat transfer occurs from 20.0 kg of 90.0C water placed in contact with 20.0 kg of 10.0C water, producing a final temperature of 50.0C ? (b) How much work could a Carnot engine do with this heat transfer, assuming it operates between two reservoirs at constant temperatures of 90.0C and 10.0C ? (c) What increase in entropy is produced by mixing 20.0 kg of 90.0C water with 20.0 kg of 10.0C water? (d) Calculate the amount of work made unavailable by this mixing using a low temperature of 10.0C, and compare it with the work done by the Garnet engine. Explicitly show how you follow the steps in the Problem-Solving Strategies for Entropy. (e) Discuss how everyday processes make increasingly more energy unavailable to do work, as implied by this problem.

A 2.00-mol sample of a diatomic ideal gas expands slowly and adiabatically from a pressure of 5.00 atm and a volume of 12.0 L to a final volume of 30.0 L. (a) What is the final pressure of the gas? (b) What are the initial and final temperatures? Find (c) Q, (d) Eint, and (e) W for the gas during this process.

The insulated cylinder shown below is closed at both ends and contains an insulating piston that is flee to move on frictionless bearings. The piston divides the chamber into two compartments containing gases A and B. Originally, each compartment has a volume of 5.0102 m3 and contains a monatomic ideal gas at a temperature of and a pressure of 1.0 atm. (a) How many moles of gas are in each compartment? (b) Heat Q is slowly added to A so that it expands and B is compressed until the pressure of both gases is 3.0 atm. Use the fact that the compression of B is adiabatic to determine the final volume of both gases. (c) What are their final temperatures? (d) What is the value of Q?

This problem compares the energy output and heat transfer to the environment by two different types of nuclear power stationsone with the normal efficiency of 34.0%, and another with an improved efficiency of 40.0%. Suppose both have the same heat transfer into the engine in one day. 2.501014J. (a) How much more electrical energy is produced by the more efficient power station? (b) How much less heat transfer occurs to the environment by the more efficient power station? (One type of more ef?cient nuclear power station, the gas—cooled reactor, has not been reliable enough to be economically feasible in spite of its greater eficiency.)

(a) On a winter day, a certain house loses 5.00108J of heat to the outside (about 500,000 Btu). What is the total change in entropy due to this heat transfer alone, assuming an average indoor temperature of 21.0C and an average outdoor temperature of 5.00C ? (b) This large change in entropy implies a large amount of energy has become unavailable to do work. Where do we find more energy when such energy is lost to us?

A multicylinder gasoline engine in an airplane, operating at 2.50 103 rev/min, takes in energy 7.89 103 J and exhausts 4.58 103 J for each revolution of the crankshaft. (a) How many liters of fuel does it consume in 1.00 h of operation if the heat of combustion of the fuel is equal to 4.03 107 J/L? (b) What is the mechanical power output of the engine? Ignore friction and express the answer in horsepower. (c) What is the torque exerted by the crankshaft on the load? (d) What power must the exhaust and cooling system transfer out of the engine?

A car salesperson claims that a 300-hp engine is a necessary option in a compact car, in place of the conventional 130-hp engine. Suppose you intend to drive the car within speed limits ( 65 mi/h) on flat terrain. How would you counter this sales pitch?

An ideal gas with specific heat ratio confined to a cylinder is put through a closed cycle. Initially, the gas is at Pi, Vi, and Ti. First, its pressure is tripled under constant volume. It then expands adiabatically to its original pressure and finally is compressed isobarically to its original volume. (a) Draw a PV diagram of this cycle. (b) Determine the volume at the end of the adiabatic expansion. Find (c) the temperature of the gas at the start of the adiabatic expansion and (d) the temperature at the end of the cycle. (e) What was the net work done on the gas for this cycle?

A 4.00-L sample of a diatomic ideal gas with specific heat ratio 1.40, confined to a cylinder, is carried through a closed cycle. The gas is initially at 1.00 atm and 300 K. First, its pressure is tripled under constant volume. Then, it expands adiabatically to its original pressure. Finally, the gas is compressed isobarically to its original volume. (a) Draw a PV diagram of this cycle. (b) Determine the volume of the gas at the end of the adiabatic expansion. (c) Find the temperature of the gas at the start of the adiabatic expansion. (d) Find the temperature at the end of the cycle. (e) What was the net work done on the gas for this cycle?