The plausible reaction and mechanism should be draw and identified for the given set of molecules under acid-catalyst conditions. Concept introduction: Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water. Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule. Nucleophilic reaction : electron rich nucleophiles attack the positive or partially positive charge of an atom and replace a leaving group is called Nucleophilic Substitution reaction. Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

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Answer 1

Question

Chapter 20, Problem 65PP

(a)

Interpretation Introduction

Interpretation:

The plausible reaction and mechanism should be draw and identified for the given set of molecules under acid-catalyst conditions.

Concept introduction:

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Nucleophilic reaction: electron rich nucleophiles attack the positive or partially positive charge of an atom and replace a leaving group is called Nucleophilic Substitution reaction.

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

(b)

Interpretation Introduction

Interpretation:

The plausible reaction and mechanism should be draw and identified for the given set of molecules under acid-catalyst conditions.

Concept introduction:

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Nucleophilic reaction: electron rich nucleophiles attack the positive or partially positive charge of an atom and replace a leaving group is called Nucleophilic Substitution reaction.

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

(c)

Interpretation Introduction

Interpretation:

The plausible reaction and mechanism should be draw and identified for the given set of molecules under acid-catalyst conditions.

Concept introduction:

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Nucleophilic reaction: electron rich nucleophiles attack the positive or partially positive charge of an atom and replace a leaving group is called Nucleophilic Substitution reaction.

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

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Every chemist knows to ‘add acid to water with constant stirring’ when diluting a concentrated acid in order to keep the solution from spewing boiling acid all over the place. Explain how this one fact is enough to prove that strong acids and water do not form ideal solutions.

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Answer 2

Question

Chapter 20, Problem 65PP

(a)

Interpretation Introduction

Interpretation:

The plausible reaction and mechanism should be draw and identified for the given set of molecules under acid-catalyst conditions.

Concept introduction:

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Nucleophilic reaction: electron rich nucleophiles attack the positive or partially positive charge of an atom and replace a leaving group is called Nucleophilic Substitution reaction.

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

(b)

Interpretation Introduction

Interpretation:

The plausible reaction and mechanism should be draw and identified for the given set of molecules under acid-catalyst conditions.

Concept introduction:

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Nucleophilic reaction: electron rich nucleophiles attack the positive or partially positive charge of an atom and replace a leaving group is called Nucleophilic Substitution reaction.

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

(c)

Interpretation Introduction

Interpretation:

The plausible reaction and mechanism should be draw and identified for the given set of molecules under acid-catalyst conditions.

Concept introduction:

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Nucleophilic reaction: electron rich nucleophiles attack the positive or partially positive charge of an atom and replace a leaving group is called Nucleophilic Substitution reaction.

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

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Answer 3

Question

Chapter 20, Problem 65PP

(a)

Interpretation Introduction

Interpretation:

The plausible reaction and mechanism should be draw and identified for the given set of molecules under acid-catalyst conditions.

Concept introduction:

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Nucleophilic reaction: electron rich nucleophiles attack the positive or partially positive charge of an atom and replace a leaving group is called Nucleophilic Substitution reaction.

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

(b)

Interpretation Introduction

Interpretation:

The plausible reaction and mechanism should be draw and identified for the given set of molecules under acid-catalyst conditions.

Concept introduction:

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Nucleophilic reaction: electron rich nucleophiles attack the positive or partially positive charge of an atom and replace a leaving group is called Nucleophilic Substitution reaction.

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

(c)

Interpretation Introduction

Interpretation:

The plausible reaction and mechanism should be draw and identified for the given set of molecules under acid-catalyst conditions.

Concept introduction:

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Nucleophilic reaction: electron rich nucleophiles attack the positive or partially positive charge of an atom and replace a leaving group is called Nucleophilic Substitution reaction.

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

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Answer 4

Question

Chapter 20, Problem 65PP

(a)

Interpretation Introduction

Interpretation:

The plausible reaction and mechanism should be draw and identified for the given set of molecules under acid-catalyst conditions.

Concept introduction:

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Nucleophilic reaction: electron rich nucleophiles attack the positive or partially positive charge of an atom and replace a leaving group is called Nucleophilic Substitution reaction.

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

(b)

Interpretation Introduction

Interpretation:

The plausible reaction and mechanism should be draw and identified for the given set of molecules under acid-catalyst conditions.

Concept introduction:

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Nucleophilic reaction: electron rich nucleophiles attack the positive or partially positive charge of an atom and replace a leaving group is called Nucleophilic Substitution reaction.

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

(c)

Interpretation Introduction

Interpretation:

The plausible reaction and mechanism should be draw and identified for the given set of molecules under acid-catalyst conditions.

Concept introduction:

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Nucleophilic reaction: electron rich nucleophiles attack the positive or partially positive charge of an atom and replace a leaving group is called Nucleophilic Substitution reaction.

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

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Answer 5

Chapter 20, Problem 65PP

(a)

Interpretation Introduction

Interpretation:

The plausible reaction and mechanism should be draw and identified for the given set of molecules under acid-catalyst conditions.

Concept introduction:

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Nucleophilic reaction: electron rich nucleophiles attack the positive or partially positive charge of an atom and replace a leaving group is called Nucleophilic Substitution reaction.

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

(b)

Interpretation Introduction

Interpretation:

The plausible reaction and mechanism should be draw and identified for the given set of molecules under acid-catalyst conditions.

Concept introduction:

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Nucleophilic reaction: electron rich nucleophiles attack the positive or partially positive charge of an atom and replace a leaving group is called Nucleophilic Substitution reaction.

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

(c)

Interpretation Introduction

Interpretation:

The plausible reaction and mechanism should be draw and identified for the given set of molecules under acid-catalyst conditions.

Concept introduction:

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Nucleophilic reaction: electron rich nucleophiles attack the positive or partially positive charge of an atom and replace a leaving group is called Nucleophilic Substitution reaction.

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Answer 6

Chapter 20, Problem 65PP

(a)

Interpretation Introduction

Interpretation:

The plausible reaction and mechanism should be draw and identified for the given set of molecules under acid-catalyst conditions.

Concept introduction:

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Nucleophilic reaction: electron rich nucleophiles attack the positive or partially positive charge of an atom and replace a leaving group is called Nucleophilic Substitution reaction.

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Answer 7

Chapter 20, Problem 65PP

(a)

Interpretation Introduction

Interpretation:

The plausible reaction and mechanism should be draw and identified for the given set of molecules under acid-catalyst conditions.

Concept introduction:

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Nucleophilic reaction: electron rich nucleophiles attack the positive or partially positive charge of an atom and replace a leaving group is called Nucleophilic Substitution reaction.

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The plausible reaction and mechanism should be draw and identified for the given set of molecules under acid-catalyst conditions.

Concept introduction:

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Nucleophilic reaction: electron rich nucleophiles attack the positive or partially positive charge of an atom and replace a leaving group is called Nucleophilic Substitution reaction.

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The plausible reaction and mechanism should be draw and identified for the given set of molecules under acid-catalyst conditions.

Concept introduction:

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Nucleophilic reaction: electron rich nucleophiles attack the positive or partially positive charge of an atom and replace a leaving group is called Nucleophilic Substitution reaction.

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The plausible reaction and mechanism should be draw and identified for the given set of molecules under acid-catalyst conditions.

Concept introduction:

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Nucleophilic reaction: electron rich nucleophiles attack the positive or partially positive charge of an atom and replace a leaving group is called Nucleophilic Substitution reaction.

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The plausible reaction and mechanism should be draw and identified for the given set of molecules under acid-catalyst conditions.

Concept introduction:

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Nucleophilic reaction: electron rich nucleophiles attack the positive or partially positive charge of an atom and replace a leaving group is called Nucleophilic Substitution reaction.

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 20.2 - Prob. 2ATS Ch. 20.2 - Prob. 4ATS Ch. 20.3 - Prob. 5CC Ch. 20.4 - Prob. 6CC Ch. 20.5 - Prob. 7CC Ch. 20.5 - Prob. 2LTS Ch. 20.5 - Prob. 8PTS Ch. 20.5 - Prob. 9ATS Ch. 20.5 - Prob. 10ATS Ch. 20.5 - Prob. 11CC

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Chapter 20 Solutions