The change in the oxyacid strength of the halogens as the number of oxygen in the formula increases is to be explained. Concept introduction: Oxyacid strength of the halogens is directly proportional to the number of oxygen atoms. To determine: An explanation corresponding to the change in the oxyacid strength of the halogens as the number of oxygen in the formula increases.

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5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15% glycerin by weight. If the original charge is 500 kg, evaluate; e. The ratio of sucrose to water in the original charge (wt/wt). f. Moles of CO2 evolved. g. Maximum possible amount of ethanol that could be formed. h. Conversion efficiency. i. Per cent excess of excess reactant. Reactions: Inversion reaction: C12H22O11 + H2O →2C6H12O6 Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2 Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3

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Chapter 20, Problem 65E

Interpretation Introduction

Interpretation: The change in the oxyacid strength of the halogens as the number of oxygen in the formula increases is to be explained.

Concept introduction: Oxyacid strength of the halogens is directly proportional to the number of oxygen atoms.

To determine: An explanation corresponding to the change in the oxyacid strength of the halogens as the number of oxygen in the formula increases.

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5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15% glycerin by weight. If the original charge is 500 kg, evaluate; e. The ratio of sucrose to water in the original charge (wt/wt). f. Moles of CO2 evolved. g. Maximum possible amount of ethanol that could be formed. h. Conversion efficiency. i. Per cent excess of excess reactant. Reactions: Inversion reaction: C12H22O11 + H2O →2C6H12O6 Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2 Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3

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