Organic Chemistry
Organic Chemistry
7th Edition
ISBN: 9780321803221
Author: Paula Y. Bruice
Publisher: Prentice Hall
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Chapter 20, Problem 35P

(a)

Interpretation Introduction

Interpretation:

The product obtained in skraup synthesis by replacing aniline with para-ethylaniline has to be given.

Concept Introduction:

Skraup synthesis is the reaction of aniline with an alpha-beta unsaturated carbonyl compound and proceeds through the formation of carbocation and results in the formation of cyclic ring which on reduction gives quinoline.

(b)

Interpretation Introduction

Interpretation: The product obtained in skraup synthesis by replacing glycerol with 3-hexen-2-one has to be given.

Concept Introduction:

Skraup synthesis is the reaction of aniline with an alpha-beta unsaturated carbonyl compound and proceeds through the formation of carbocation and results in the formation of cyclic ring which on reduction gives quinoline.

(c)

Interpretation Introduction

Interpretation: The reactants required for the preparation of 2,7-diethyl-3-methylquinoline in skraup synthesis should be given.

Concept Introduction:

Skraup synthesis is the reaction of aniline with an alpha-beta unsaturated carbonyl compound and proceeds through the formation of carbocation and results in the formation of cyclic ring which on reduction gives quinoline.

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