EBK PHYSICAL CHEMISTRY
2nd Edition
ISBN: 8220100477560
Author: Ball
Publisher: Cengage Learning US
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Chapter 20, Problem 20.82E
Show that another form of the Michaelis-Menten equation is
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When an unknown amine reacts with an unknown acid chloride, an amide with a molecular mass of 163 g/mol (M* = 163 m/z)
is formed. In the infrared spectrum, important absorptions appear at 1661, 750 and 690 cm. The 13C NMR and DEPT spectra
are provided. Draw the structure of the product as the resonance contributor lacking any formal charges.
13C NMR
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DEPT 135
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Draw the unknown amide.
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Chapter 20 Solutions
EBK PHYSICAL CHEMISTRY
Ch. 20 - Prob. 20.1ECh. 20 - The oxidation-reduction reaction between iron...Ch. 20 - The oxidation-reduction reaction between iron...Ch. 20 - The rate of the reaction...Ch. 20 - For a certain reaction between NO and O2, the rate...Ch. 20 - For a reaction between SO2 and Cl2, the rate law...Ch. 20 - Consider the chemical reaction A+B+Cproducts...Ch. 20 - For the chemical reaction...Ch. 20 - Explain how a species might be part of a rate law...Ch. 20 - Refer to Example 20.2 and explain whether any...
Ch. 20 - Rate law experiments dont always give data in the...Ch. 20 - Prob. 20.12ECh. 20 - What must the units on k be for the following rate...Ch. 20 - What must the units on k be for the following rate...Ch. 20 - The reaction 2O33O2 has first-order kinetics and a...Ch. 20 - Digestive processes are first-order processes. The...Ch. 20 - Prob. 20.18ECh. 20 - Derive equation 20.15.Ch. 20 - Prob. 20.20ECh. 20 - To a very good approximation, the cooling of a hot...Ch. 20 - Assume that thermal decomposition of mercuric...Ch. 20 - Prob. 20.23ECh. 20 - Prob. 20.24ECh. 20 - Derive equation 20.22.Ch. 20 - a Write a rate law and an integrated rate law for...Ch. 20 - Derive an expression for the half-life of a a...Ch. 20 - Prob. 20.28ECh. 20 - Rewrite equation 20.27 so that it has the form of...Ch. 20 - One can also define a third-life, t1/3, which is...Ch. 20 - The decomposition of NH3: 2NH3N2+3H2 is a...Ch. 20 - Prob. 20.32ECh. 20 - Prob. 20.33ECh. 20 - When ionic compounds crystallize from a...Ch. 20 - An aqueous reaction that uses the solvent H2O as a...Ch. 20 - The rate law for the reaction...Ch. 20 - If a reaction has the same rate constant, what...Ch. 20 - List at least four experimentally determined...Ch. 20 - Prob. 20.39ECh. 20 - Prob. 20.40ECh. 20 - Prob. 20.41ECh. 20 - Prob. 20.42ECh. 20 - What is the value of the equilibrium constant of a...Ch. 20 - Prob. 20.44ECh. 20 - Prob. 20.45ECh. 20 - Show how equation 20.33 reduces to a simpler form...Ch. 20 - Write expressions like equation 20.37 for a set of...Ch. 20 - Prob. 20.48ECh. 20 - Prob. 20.49ECh. 20 - Prob. 20.50ECh. 20 - Prob. 20.51ECh. 20 - Prob. 20.52ECh. 20 - Prob. 20.53ECh. 20 - Prob. 20.54ECh. 20 - For what values of time, t, will 210Bi and 206Pb...Ch. 20 - Prob. 20.56ECh. 20 - An interesting pair of consecutive reactions...Ch. 20 - Find limiting forms of equation 20.47 for a k1>>k2...Ch. 20 - Prob. 20.59ECh. 20 - Prob. 20.60ECh. 20 - Prob. 20.61ECh. 20 - Prob. 20.62ECh. 20 - At room temperature (22C), the rate constant for...Ch. 20 - Recently, researchers studying the kinetics of...Ch. 20 - A reaction has k=1.771061/(Ms) at 25.0C and an...Ch. 20 - Prob. 20.66ECh. 20 - Prob. 20.67ECh. 20 - Prob. 20.68ECh. 20 - Nitric oxide, NO, is known to break down ozone,...Ch. 20 - a Suggest a mechanism for the bromination of...Ch. 20 - Prob. 20.71ECh. 20 - Prob. 20.72ECh. 20 - Determine a rate law for the chlorination of...Ch. 20 - Determine a rate law for the chlorination of...Ch. 20 - A proposed mechanism for the gas-phase...Ch. 20 - Prob. 20.76ECh. 20 - The nitration of methanol, CH3OH, by nitrous acid...Ch. 20 - Prob. 20.78ECh. 20 - Many gas-phase reactions require some inert body,...Ch. 20 - Prob. 20.80ECh. 20 - Carbonic anhydrase, an enzyme whose substrate is...Ch. 20 - Show that another form of the Michaelis-Menten...Ch. 20 - Prob. 20.83ECh. 20 - Prob. 20.84ECh. 20 - Prob. 20.85ECh. 20 - Prob. 20.86ECh. 20 - Pyrolysis involves heating compounds to break them...Ch. 20 - Prob. 20.88ECh. 20 - Label the elementary processes for the reaction...Ch. 20 - Prob. 20.90ECh. 20 - What are the rate laws of mechanisms 1 and 2 for...Ch. 20 - Estimate G for an elementary process whose rate...Ch. 20 - Prob. 20.93ECh. 20 - Prob. 20.94ECh. 20 - Prob. 20.95ECh. 20 - For the following two reactions H+Cl2HCl+Cl...Ch. 20 - Prob. 20.97ECh. 20 - Prob. 20.98ECh. 20 - Prob. 20.99ECh. 20 - Consider a reaction that has two parallel pathways...Ch. 20 - Consider a set of first-order consecutive...Ch. 20 - Prob. 20.102E
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Identify the unknown compound from its IR and proton NMR spectra. C4H6O: 'H NMR: 82.43 (1H, t, J = 2 Hz); 8 3.41 (3H, s); 8 4.10 (2H, d, J = 2 Hz) IR: 2125, 3300 cm¹ The C4H6O compound liberates a gas when treated with C2H5 MgBr. Draw the unknown compound. Select Draw с H Templates Morearrow_forwardPlease help with number 6 I got a negative number could that be right?arrow_forward1,4-Dimethyl-1,3-cyclohexadiene can undergo 1,2- or 1,4-addition with hydrogen halides. (a) 1,2-Addition i. Draw the carbocation intermediate(s) formed during the 1,2-addition of hydrobromic acid to 1,4-dimethyl-1,3-cyclohexadiene. ii. What is the major 1,2-addition product formed during the reaction in (i)? (b) 1,4-Addition i. Draw the carbocation intermediate(s) formed during the 1,4-addition of hydrobromic acid to 1,4-dimethyl-1,3-cyclohexadiene. ii. What is the major 1,4-addition product formed from the reaction in (i)? (c) What is the kinetic product from the reaction of one mole of hydrobromic acid with 1,4-dimethyl-1,3-cyclohexadiene? Explain your reasoning. (d) What is the thermodynamic product from the reaction of one mole of hydrobro-mic acid with 1,4-dimethyl-1,3-cyclohexadiene? Explain your reasoning. (e) What major product will result when 1,4-dimethyl-1,3-cyclohexadiene is treated with one mole of hydrobromic acid at - 78 deg * C ? Explain your reasoning.arrow_forward
- Give the product of the bimolecular elimination from each of the isomeric halogenated compounds. Reaction A Reaction B. КОВ CH₂ HotBu +B+ ко HOIBU +Br+ Templates More QQQ Select Cv Templates More Cras QQQ One of these compounds undergoes elimination 50x faster than the other. Which one and why? Reaction A because the conformation needed for elimination places the phenyl groups and to each other Reaction A because the conformation needed for elimination places the phenyl groups gauche to each other. ◇ Reaction B because the conformation needed for elimination places the phenyl groups gach to each other. Reaction B because the conformation needed for elimination places the phenyl groups anti to each other.arrow_forwardFive isomeric alkenes. A through each undergo catalytic hydrogenation to give 2-methylpentane The IR spectra of these five alkenes have the key absorptions (in cm Compound Compound A –912. (§), 994 (5), 1643 (%), 3077 (1) Compound B 833 (3), 1667 (W), 3050 (weak shoulder on C-Habsorption) Compound C Compound D) –714 (5), 1665 (w), 3010 (m) 885 (3), 1650 (m), 3086 (m) 967 (5), no aharption 1600 to 1700, 3040 (m) Compound K Match each compound to the data presented. Compound A Compound B Compound C Compound D Compoundarrow_forward7. The three sets of replicate results below were accumulated for the analysis of the same sample. Pool these data to obtain the most efficient estimate of the mean analyte content and the standard deviation. Lead content/ppm: Set 1 Set 2 Set 3 1. 9.76 9.87 9.85 2. 9.42 9.64 9.91 3. 9.53 9.71 9.42 9.81 9.49arrow_forward
- Draw the Zaitsev product famed when 2,3-dimethylpentan-3-of undergoes an El dehydration. CH₂ E1 OH H₁PO₁ Select Draw Templates More QQQ +H₂Oarrow_forwardComplete the clean-pushing mechanism for the given ether synthesia from propanol in concentrated sulfurica140°C by adding any mining aloms, bands, charges, nonbonding electron pairs, and curved arrows. Draw hydrogen bonded to cayan, when applicable. ore 11,0 HPC Step 1: Draw curved arrows Step 2: Complete the intend carved Q2Q 56 QQQ Step 3: Complete the intermediate and add curved Step 4: Modify the structures to draw the QQQ QQQarrow_forward6. In an experiment the following replicate set of volume measurements (cm3) was recorded: (25.35, 25.80, 25.28, 25.50, 25.45, 25.43) A. Calculate the mean of the raw data. B. Using the rejection quotient (Q-test) reject any questionable results. C. Recalculate the mean and compare it with the value obtained in 2(a).arrow_forward
- A student proposes the transformation below in one step of an organic synthesis. There may be one or more reactants missing from the left-hand side, but there are no products missing from the right-hand side. There may also be catalysts, small inorganic reagents, and other important reaction conditions missing from the arrow. • Is the student's transformation possible? If not, check the box under the drawing area. • If the student's transformation is possible, then complete the reaction by adding any missing reactants to the left-hand side, and adding required catalysts, inorganic reagents, or other important reaction conditions above and below the arrow. • You do not need to balance the reaction, but be sure every important organic reactant or product is shown. + T G OH де OH This transformation can't be done in one step.arrow_forwardMacmillan Leaming Draw the major organic product of the reaction. 1. CH3CH2MgBr 2. H+ - G Select Draw Templates More H о QQarrow_forwardDraw the condensed structure of 3-hydroxy-2-butanone. Click anywhere to draw the first atom of your structure.arrow_forward
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Kinetics: Initial Rates and Integrated Rate Laws; Author: Professor Dave Explains;https://www.youtube.com/watch?v=wYqQCojggyM;License: Standard YouTube License, CC-BY