EBK PHYSICAL CHEMISTRY
2nd Edition
ISBN: 8220100477560
Author: Ball
Publisher: Cengage Learning US
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Chapter 20, Problem 20.14E
What must the units on
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Chapter 20 Solutions
EBK PHYSICAL CHEMISTRY
Ch. 20 - Prob. 20.1ECh. 20 - The oxidation-reduction reaction between iron...Ch. 20 - The oxidation-reduction reaction between iron...Ch. 20 - The rate of the reaction...Ch. 20 - For a certain reaction between NO and O2, the rate...Ch. 20 - For a reaction between SO2 and Cl2, the rate law...Ch. 20 - Consider the chemical reaction A+B+Cproducts...Ch. 20 - For the chemical reaction...Ch. 20 - Explain how a species might be part of a rate law...Ch. 20 - Refer to Example 20.2 and explain whether any...
Ch. 20 - Rate law experiments dont always give data in the...Ch. 20 - Prob. 20.12ECh. 20 - What must the units on k be for the following rate...Ch. 20 - What must the units on k be for the following rate...Ch. 20 - The reaction 2O33O2 has first-order kinetics and a...Ch. 20 - Digestive processes are first-order processes. The...Ch. 20 - Prob. 20.18ECh. 20 - Derive equation 20.15.Ch. 20 - Prob. 20.20ECh. 20 - To a very good approximation, the cooling of a hot...Ch. 20 - Assume that thermal decomposition of mercuric...Ch. 20 - Prob. 20.23ECh. 20 - Prob. 20.24ECh. 20 - Derive equation 20.22.Ch. 20 - a Write a rate law and an integrated rate law for...Ch. 20 - Derive an expression for the half-life of a a...Ch. 20 - Prob. 20.28ECh. 20 - Rewrite equation 20.27 so that it has the form of...Ch. 20 - One can also define a third-life, t1/3, which is...Ch. 20 - The decomposition of NH3: 2NH3N2+3H2 is a...Ch. 20 - Prob. 20.32ECh. 20 - Prob. 20.33ECh. 20 - When ionic compounds crystallize from a...Ch. 20 - An aqueous reaction that uses the solvent H2O as a...Ch. 20 - The rate law for the reaction...Ch. 20 - If a reaction has the same rate constant, what...Ch. 20 - List at least four experimentally determined...Ch. 20 - Prob. 20.39ECh. 20 - Prob. 20.40ECh. 20 - Prob. 20.41ECh. 20 - Prob. 20.42ECh. 20 - What is the value of the equilibrium constant of a...Ch. 20 - Prob. 20.44ECh. 20 - Prob. 20.45ECh. 20 - Show how equation 20.33 reduces to a simpler form...Ch. 20 - Write expressions like equation 20.37 for a set of...Ch. 20 - Prob. 20.48ECh. 20 - Prob. 20.49ECh. 20 - Prob. 20.50ECh. 20 - Prob. 20.51ECh. 20 - Prob. 20.52ECh. 20 - Prob. 20.53ECh. 20 - Prob. 20.54ECh. 20 - For what values of time, t, will 210Bi and 206Pb...Ch. 20 - Prob. 20.56ECh. 20 - An interesting pair of consecutive reactions...Ch. 20 - Find limiting forms of equation 20.47 for a k1>>k2...Ch. 20 - Prob. 20.59ECh. 20 - Prob. 20.60ECh. 20 - Prob. 20.61ECh. 20 - Prob. 20.62ECh. 20 - At room temperature (22C), the rate constant for...Ch. 20 - Recently, researchers studying the kinetics of...Ch. 20 - A reaction has k=1.771061/(Ms) at 25.0C and an...Ch. 20 - Prob. 20.66ECh. 20 - Prob. 20.67ECh. 20 - Prob. 20.68ECh. 20 - Nitric oxide, NO, is known to break down ozone,...Ch. 20 - a Suggest a mechanism for the bromination of...Ch. 20 - Prob. 20.71ECh. 20 - Prob. 20.72ECh. 20 - Determine a rate law for the chlorination of...Ch. 20 - Determine a rate law for the chlorination of...Ch. 20 - A proposed mechanism for the gas-phase...Ch. 20 - Prob. 20.76ECh. 20 - The nitration of methanol, CH3OH, by nitrous acid...Ch. 20 - Prob. 20.78ECh. 20 - Many gas-phase reactions require some inert body,...Ch. 20 - Prob. 20.80ECh. 20 - Carbonic anhydrase, an enzyme whose substrate is...Ch. 20 - Show that another form of the Michaelis-Menten...Ch. 20 - Prob. 20.83ECh. 20 - Prob. 20.84ECh. 20 - Prob. 20.85ECh. 20 - Prob. 20.86ECh. 20 - Pyrolysis involves heating compounds to break them...Ch. 20 - Prob. 20.88ECh. 20 - Label the elementary processes for the reaction...Ch. 20 - Prob. 20.90ECh. 20 - What are the rate laws of mechanisms 1 and 2 for...Ch. 20 - Estimate G for an elementary process whose rate...Ch. 20 - Prob. 20.93ECh. 20 - Prob. 20.94ECh. 20 - Prob. 20.95ECh. 20 - For the following two reactions H+Cl2HCl+Cl...Ch. 20 - Prob. 20.97ECh. 20 - Prob. 20.98ECh. 20 - Prob. 20.99ECh. 20 - Consider a reaction that has two parallel pathways...Ch. 20 - Consider a set of first-order consecutive...Ch. 20 - Prob. 20.102E
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- Potential Energy (kJ) 1. Consider these three reactions as the elementary steps in the mechanism for a chemical reaction. AH = -950 kJ AH = 575 kJ (i) Cl₂ (g) + Pt (s) 2C1 (g) + Pt (s) Ea = 1550 kJ (ii) Cl (g)+ CO (g) + Pt (s) → CICO (g) + Pt (s) (iii) Cl (g) + CICO (g) → Cl₂CO (g) Ea = 2240 kJ Ea = 2350 kJ AH = -825 kJ 2600 2400 2200 2000 1800 1600 1400 1200 1000 a. Draw the potential energy diagram for the reaction. Label the data points for clarity. The potential energy of the reactants is 600 kJ 800 600 400 200 0 -200- -400 -600- -800- Reaction Progressarrow_forwardCan u help me figure out the reaction mechanisms for these, idk where to even startarrow_forwardHi, I need your help with the drawing, please. I have attached the question along with my lab instructions. Please use the reaction from the lab only, as we are not allowed to use outside sources. Thank you!arrow_forward
- Hi, I need your help i dont know which one to draw please. I’ve attached the question along with my lab instructions. Please use the reaction from the lab only, as we are not allowed to use outside sources. Thank you!arrow_forward5. Write the formation reaction of the following complex compounds from the following reactants: 6. AgNO₃ + K₂CrO₂ + NH₄OH → 7. HgNO₃ + excess KI → 8. Al(NO₃)₃ + excess NaOH →arrow_forwardIndicate whether the product formed in the reaction exhibits tautomerism. If so, draw the structure of the tautomers. CO₂C2H5 + CH3-NH-NH,arrow_forward
- Draw the major product of this reaction N-(cyclohex-1-en-1-yl)-1-(pyrrolidino) reacts with CH2=CHCHO, heat, H3O+arrow_forwardDraw the starting material that would be needed to make this product through an intramolecular Dieckmann reactionarrow_forwardDraw the major product of this reaction. Nitropropane reacts + pent-3-en-2-one reacts with NaOCH2CH3, CH3CHOHarrow_forward
- Indicate whether the product formed in the reaction exhibits tautomerism. If so, draw the structure of the tautomers. OC2H5 + CoHs-NH-NH,arrow_forwardExplain how substitutions at the 5-position of barbituric acid increase the compound's lipophilicity.arrow_forwardExplain how substitutions at the 5-position of phenobarbital increase the compound's lipophilicity.arrow_forward
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Kinetics: Initial Rates and Integrated Rate Laws; Author: Professor Dave Explains;https://www.youtube.com/watch?v=wYqQCojggyM;License: Standard YouTube License, CC-BY