General Chemistry
General Chemistry
11th Edition
ISBN: 9781305859142
Author: Ebbing, Darrell D., Gammon, Steven D.
Publisher: Cengage Learning,
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Chapter 20, Problem 20.69QP
Interpretation Introduction

Interpretation:

  • The fraction of Sodium-24 remains undecayed after 12.0h has to be determined.
  • If the sample has 6.0μg of Sodium-24, amount of micrograms remains after 12h has to be determined.

Concept introduction:

  • The decay constant (k) is independent of the quantity of radioactive material however depends only on the character of the nuclide.  Various nuclides have various decay constants.  The degree of radioactive decay depends on the decay constant and number of radioactive nuclei at specific time ( Nt ).  The rate of decay is directly proportional to the number of radioactive nuclei in a given sample; it is expressed mathematically as,

Rate = kNt

  • The decay constant used to define the quantity of radioactive material that remains after time period has gone.  The fraction of material that leftovers after a time period gas gone is the ratio of the number of radioactive nuclei ( Ng ) in the real sample when the measurement happening.  This segment is frequently expressed as a percent.

The equation relating fraction of nuclei after a period of time has elapsed to the decay constant (lnNtNg= -kt)

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Draw the complete mechanism for the reaction below. Please include appropriate arrows, intermediates, and formal charges.
(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to glucose, C6H12O6, and fructose C6H12O6, in acidic solution: C12H22O11 + H2O → C6H12O6 + C6H12O6 [sucrose]/mol dm³ t/min 0 0.316 14 0.300 39 0.274 60 0.256 80 0.238 110 0.211 (i) Graphically prove the order of the reaction and determine the rate constant of the reaction. (ii) Determine the half-life, t½ for the hydrolysis of sucrose.
(III) adsorbent (b) Adsorption of the hexacyanoferrate (III) ion, [Fe(CN)6] ³, on y-Al2O3 from aqueous solution was examined. The adsorption was modelled using a modified Langmuir isotherm, yielding the following values of Kat pH = 6.5: (ii) T/K 10-10 K 280 2.505 295 1.819 310 1.364 325 1.050 Determine the enthalpy of adsorption, AadsHⓇ. If the reported value of entropy of adsorption, Aads Se = 146 J K-1 mol-1 under the above conditions, determine Aads Gº.

Chapter 20 Solutions

General Chemistry

Ch. 20.4 - Prob. 20.9ECh. 20.4 - Prob. 20.10ECh. 20.4 - Prob. 20.11ECh. 20.4 - Prob. 20.3CCCh. 20.6 - Prob. 20.12ECh. 20 - Prob. 20.1QPCh. 20 - Prob. 20.2QPCh. 20 - Prob. 20.3QPCh. 20 - Prob. 20.4QPCh. 20 - Prob. 20.5QPCh. 20 - Prob. 20.6QPCh. 20 - Prob. 20.7QPCh. 20 - Prob. 20.8QPCh. 20 - Prob. 20.9QPCh. 20 - Prob. 20.10QPCh. 20 - Prob. 20.11QPCh. 20 - Prob. 20.12QPCh. 20 - Prob. 20.13QPCh. 20 - Prob. 20.14QPCh. 20 - Prob. 20.15QPCh. 20 - Prob. 20.16QPCh. 20 - Prob. 20.17QPCh. 20 - Prob. 20.18QPCh. 20 - Prob. 20.19QPCh. 20 - Prob. 20.20QPCh. 20 - Prob. 20.21QPCh. 20 - Prob. 20.22QPCh. 20 - Prob. 20.23QPCh. 20 - Prob. 20.24QPCh. 20 - Prob. 20.25QPCh. 20 - Prob. 20.26QPCh. 20 - Prob. 20.27QPCh. 20 - Prob. 20.28QPCh. 20 - Prob. 20.29QPCh. 20 - Prob. 20.30QPCh. 20 - Prob. 20.31QPCh. 20 - Prob. 20.32QPCh. 20 - Prob. 20.33QPCh. 20 - Prob. 20.34QPCh. 20 - Prob. 20.35QPCh. 20 - Prob. 20.36QPCh. 20 - Prob. 20.37QPCh. 20 - Prob. 20.38QPCh. 20 - Prob. 20.39QPCh. 20 - Prob. 20.40QPCh. 20 - Prob. 20.41QPCh. 20 - Prob. 20.42QPCh. 20 - Prob. 20.43QPCh. 20 - Prob. 20.44QPCh. 20 - Prob. 20.45QPCh. 20 - Prob. 20.46QPCh. 20 - Prob. 20.47QPCh. 20 - Prob. 20.48QPCh. 20 - Prob. 20.49QPCh. 20 - Prob. 20.50QPCh. 20 - Prob. 20.51QPCh. 20 - Prob. 20.52QPCh. 20 - Fill in the missing parts of the following...Ch. 20 - Fill in the missing parts of the following...Ch. 20 - Prob. 20.55QPCh. 20 - Prob. 20.56QPCh. 20 - Prob. 20.57QPCh. 20 - Prob. 20.58QPCh. 20 - Prob. 20.59QPCh. 20 - Prob. 20.60QPCh. 20 - Prob. 20.61QPCh. 20 - Prob. 20.62QPCh. 20 - Prob. 20.63QPCh. 20 - Prob. 20.64QPCh. 20 - Prob. 20.65QPCh. 20 - Prob. 20.66QPCh. 20 - Prob. 20.67QPCh. 20 - Prob. 20.68QPCh. 20 - Prob. 20.69QPCh. 20 - Prob. 20.70QPCh. 20 - Prob. 20.71QPCh. 20 - Prob. 20.72QPCh. 20 - Prob. 20.73QPCh. 20 - Prob. 20.74QPCh. 20 - Prob. 20.75QPCh. 20 - Prob. 20.76QPCh. 20 - Prob. 20.77QPCh. 20 - Prob. 20.78QPCh. 20 - Find the change of mass (in grams) resulting from...Ch. 20 - Find the change of mass (in grams) resulting from...Ch. 20 - Prob. 20.81QPCh. 20 - Prob. 20.82QPCh. 20 - Prob. 20.83QPCh. 20 - Prob. 20.84QPCh. 20 - Prob. 20.85QPCh. 20 - Prob. 20.86QPCh. 20 - Prob. 20.87QPCh. 20 - Prob. 20.88QPCh. 20 - Prob. 20.89QPCh. 20 - Prob. 20.90QPCh. 20 - Prob. 20.91QPCh. 20 - Prob. 20.92QPCh. 20 - Prob. 20.93QPCh. 20 - Prob. 20.94QPCh. 20 - Prob. 20.95QPCh. 20 - Prob. 20.96QPCh. 20 - Prob. 20.97QPCh. 20 - Prob. 20.98QPCh. 20 - Prob. 20.99QPCh. 20 - Prob. 20.100QPCh. 20 - Prob. 20.101QPCh. 20 - Prob. 20.102QPCh. 20 - Prob. 20.103QPCh. 20 - Prob. 20.104QPCh. 20 - Prob. 20.105QPCh. 20 - Prob. 20.106QPCh. 20 - Prob. 20.107QPCh. 20 - Prob. 20.108QPCh. 20 - Prob. 20.109QPCh. 20 - Prob. 20.110QPCh. 20 - Prob. 20.111QPCh. 20 - Prob. 20.112QPCh. 20 - Prob. 20.113QPCh. 20 - Prob. 20.114QPCh. 20 - Prob. 20.115QPCh. 20 - Prob. 20.116QPCh. 20 - Prob. 20.117QPCh. 20 - Prob. 20.118QPCh. 20 - Prob. 20.119QPCh. 20 - Prob. 20.120QPCh. 20 - Prob. 20.121QPCh. 20 - Prob. 20.122QPCh. 20 - Prob. 20.123QPCh. 20 - Prob. 20.124QPCh. 20 - Prob. 20.125QPCh. 20 - Prob. 20.126QPCh. 20 - Prob. 20.127QPCh. 20 - Prob. 20.128QP
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