(a) Interpretation: The structure of adduct A formed in the given reaction is to be shown. Concept Introduction: Pyridoxal phosphate (PLP) is a coenzyme. PLP is used in different reactions of amino acids. The transamination reaction of amino acid takes place in presence of PLP. PLP contain an aldehyde group which reacts with amino acid to form imine.

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Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 20, Problem 20.54AP

Interpretation Introduction

(a)

Interpretation:

The structure of adduct A formed in the given reaction is to be shown.

Concept Introduction:

Pyridoxal phosphate (PLP) is a coenzyme. PLP is used in different reactions of amino acids. The transamination reaction of amino acid takes place in presence of PLP. PLP contain an aldehyde group which reacts with amino acid to form imine.

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanism for the decarboxylation reaction of A to form new imine intermediate X is to be shown.

Concept Introduction:

Pyridoxal phosphate (PLP) is a coenzyme. PLP is used in different reactions of amino acids. The transamination reaction of amino acid takes place in presence of PLP. PLP contain an aldehyde group which reacts with amino acid to form imine.

Interpretation Introduction

(c)

Interpretation:

The curved-arrow mechanism for the acid-base reaction of imine X to form new imine Y is to be shown.

Concept Introduction:

Pyridoxal phosphate (PLP) is a coenzyme. PLP is used in different reactions of amino acids. The transamination reaction of amino acid takes place in presence of PLP. PLP contain an aldehyde group which reacts with amino acid to form imine.

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Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 20, Problem 20.54AP

Interpretation Introduction

(a)

Interpretation:

The structure of adduct A formed in the given reaction is to be shown.

Concept Introduction:

Pyridoxal phosphate (PLP) is a coenzyme. PLP is used in different reactions of amino acids. The transamination reaction of amino acid takes place in presence of PLP. PLP contain an aldehyde group which reacts with amino acid to form imine.

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanism for the decarboxylation reaction of A to form new imine intermediate X is to be shown.

Concept Introduction:

Pyridoxal phosphate (PLP) is a coenzyme. PLP is used in different reactions of amino acids. The transamination reaction of amino acid takes place in presence of PLP. PLP contain an aldehyde group which reacts with amino acid to form imine.

Interpretation Introduction

(c)

Interpretation:

The curved-arrow mechanism for the acid-base reaction of imine X to form new imine Y is to be shown.

Concept Introduction:

Pyridoxal phosphate (PLP) is a coenzyme. PLP is used in different reactions of amino acids. The transamination reaction of amino acid takes place in presence of PLP. PLP contain an aldehyde group which reacts with amino acid to form imine.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 20, Problem 20.54AP

Interpretation Introduction

(a)

Interpretation:

The structure of adduct A formed in the given reaction is to be shown.

Concept Introduction:

Pyridoxal phosphate (PLP) is a coenzyme. PLP is used in different reactions of amino acids. The transamination reaction of amino acid takes place in presence of PLP. PLP contain an aldehyde group which reacts with amino acid to form imine.

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanism for the decarboxylation reaction of A to form new imine intermediate X is to be shown.

Concept Introduction:

Pyridoxal phosphate (PLP) is a coenzyme. PLP is used in different reactions of amino acids. The transamination reaction of amino acid takes place in presence of PLP. PLP contain an aldehyde group which reacts with amino acid to form imine.

Interpretation Introduction

(c)

Interpretation:

The curved-arrow mechanism for the acid-base reaction of imine X to form new imine Y is to be shown.

Concept Introduction:

Pyridoxal phosphate (PLP) is a coenzyme. PLP is used in different reactions of amino acids. The transamination reaction of amino acid takes place in presence of PLP. PLP contain an aldehyde group which reacts with amino acid to form imine.

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 20, Problem 20.54AP

Interpretation Introduction

(a)

Interpretation:

The structure of adduct A formed in the given reaction is to be shown.

Concept Introduction:

Pyridoxal phosphate (PLP) is a coenzyme. PLP is used in different reactions of amino acids. The transamination reaction of amino acid takes place in presence of PLP. PLP contain an aldehyde group which reacts with amino acid to form imine.

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanism for the decarboxylation reaction of A to form new imine intermediate X is to be shown.

Concept Introduction:

Pyridoxal phosphate (PLP) is a coenzyme. PLP is used in different reactions of amino acids. The transamination reaction of amino acid takes place in presence of PLP. PLP contain an aldehyde group which reacts with amino acid to form imine.

Interpretation Introduction

(c)

Interpretation:

The curved-arrow mechanism for the acid-base reaction of imine X to form new imine Y is to be shown.

Concept Introduction:

Pyridoxal phosphate (PLP) is a coenzyme. PLP is used in different reactions of amino acids. The transamination reaction of amino acid takes place in presence of PLP. PLP contain an aldehyde group which reacts with amino acid to form imine.

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Answer 5

Chapter 20, Problem 20.54AP

Interpretation Introduction

(a)

Interpretation:

The structure of adduct A formed in the given reaction is to be shown.

Concept Introduction:

Pyridoxal phosphate (PLP) is a coenzyme. PLP is used in different reactions of amino acids. The transamination reaction of amino acid takes place in presence of PLP. PLP contain an aldehyde group which reacts with amino acid to form imine.

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanism for the decarboxylation reaction of A to form new imine intermediate X is to be shown.

Concept Introduction:

Pyridoxal phosphate (PLP) is a coenzyme. PLP is used in different reactions of amino acids. The transamination reaction of amino acid takes place in presence of PLP. PLP contain an aldehyde group which reacts with amino acid to form imine.

Interpretation Introduction

(c)

Interpretation:

The curved-arrow mechanism for the acid-base reaction of imine X to form new imine Y is to be shown.

Concept Introduction:

Pyridoxal phosphate (PLP) is a coenzyme. PLP is used in different reactions of amino acids. The transamination reaction of amino acid takes place in presence of PLP. PLP contain an aldehyde group which reacts with amino acid to form imine.

Answer 6

Chapter 20, Problem 20.54AP

Interpretation Introduction

(a)

Interpretation:

The structure of adduct A formed in the given reaction is to be shown.

Concept Introduction:

Pyridoxal phosphate (PLP) is a coenzyme. PLP is used in different reactions of amino acids. The transamination reaction of amino acid takes place in presence of PLP. PLP contain an aldehyde group which reacts with amino acid to form imine.

Answer 7

Chapter 20, Problem 20.54AP

Interpretation Introduction

(a)

Interpretation:

The structure of adduct A formed in the given reaction is to be shown.

Concept Introduction:

Pyridoxal phosphate (PLP) is a coenzyme. PLP is used in different reactions of amino acids. The transamination reaction of amino acid takes place in presence of PLP. PLP contain an aldehyde group which reacts with amino acid to form imine.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanism for the decarboxylation reaction of A to form new imine intermediate X is to be shown.

Concept Introduction:

Pyridoxal phosphate (PLP) is a coenzyme. PLP is used in different reactions of amino acids. The transamination reaction of amino acid takes place in presence of PLP. PLP contain an aldehyde group which reacts with amino acid to form imine.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanism for the decarboxylation reaction of A to form new imine intermediate X is to be shown.

Concept Introduction:

Pyridoxal phosphate (PLP) is a coenzyme. PLP is used in different reactions of amino acids. The transamination reaction of amino acid takes place in presence of PLP. PLP contain an aldehyde group which reacts with amino acid to form imine.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The curved-arrow mechanism for the acid-base reaction of imine X to form new imine Y is to be shown.

Concept Introduction:

Pyridoxal phosphate (PLP) is a coenzyme. PLP is used in different reactions of amino acids. The transamination reaction of amino acid takes place in presence of PLP. PLP contain an aldehyde group which reacts with amino acid to form imine.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The curved-arrow mechanism for the acid-base reaction of imine X to form new imine Y is to be shown.

Concept Introduction:

Pyridoxal phosphate (PLP) is a coenzyme. PLP is used in different reactions of amino acids. The transamination reaction of amino acid takes place in presence of PLP. PLP contain an aldehyde group which reacts with amino acid to form imine.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 20 - Prob. 20.1P Ch. 20 - Prob. 20.2P Ch. 20 - Prob. 20.3P Ch. 20 - Prob. 20.4P Ch. 20 - Prob. 20.5P Ch. 20 - Prob. 20.6P Ch. 20 - Prob. 20.7P Ch. 20 - Prob. 20.8P Ch. 20 - Prob. 20.9P Ch. 20 - Prob. 20.10P

Solution Summary: The author explains that Pyridoxal phosphate (PLP) is a coenzyme and is used in different reactions of amino acids.

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