ORGANIC CHEMISTRY SAPLING ACCESS + ETEX
ORGANIC CHEMISTRY SAPLING ACCESS + ETEX
6th Edition
ISBN: 9781319306977
Author: LOUDON
Publisher: INTER MAC
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Chapter 20, Problem 20.41AP
Interpretation Introduction

Interpretation:

A reaction scheme for determining the fraction of 14C at the carbonyl carbon and the other fraction of 14C present elsewhere position in phenylacetic acid (PhCH2CO2H) molecule is to be stated.

Concept introduction:

Atoms of the same elements that have different masses and different number of neutrons are known as isotopes. The isotopes of carbon atom are 13C and 14C.

The reduction of an acid in the presence of a hydride like LiAlH4 and NaBH4 forms the corresponding alcohol. Among LiAlH4 and NaBH4, LiAlH4 is mostly preferred for the reduction of acids because it is strong reducing agent.

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2. Name the following hydrocarbons. (9 marks) a) HHHHHHHH H-C-C- H-O-S b) HCEC-CH3 H H H H H d) c) H C=C- H H H e) CH3 CH3 CH2CH=CH-CH=CHCH3 HHHH H-C-C-C-C-H H HH H f) large CH2CH3 pola H3C section lovels tower, able ocart firs g) Tower H3C-CH2 then in H3C-CH-CH-CH3 enblbano bne noitsidab Copyright © 2008. Durham Continuing Education CH3
Name the molecules & Identify any chiral center CH3CH2CH2CHCH₂CH₂CH₂CH₂ OH CH₂CHCH2CH3 Br CH3 CH3CHCH2CHCH2CH3 CH3
Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electrons-pushing arrows for the following reaction or mechanistic step(s).
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