
CHEMISTRY:SCI.IN CONTEXT (CL)-PACKAGE
5th Edition
ISBN: 9780393628173
Author: Gilbert
Publisher: NORTON
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Chapter 20, Problem 20.38QP
(a)
Interpretation Introduction
Interpretation: The condensed structural formula of tyrosine at the give condition of
Concept introduction: At acidic
At basic
At
To determine: The condensed structure of tyrosine representing its existence in the strongly acidic solution.
(b)
Interpretation Introduction
To determine: The condensed structure of tyrosine representing its existence in the strongly basic solution.
(c)
Interpretation Introduction
To determine: The condensed structure of tyrosine representing its existence in the solution in which
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Part I.
a)
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone
b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
(3,3-dimethyl-2-butanone) and 2, 3-dimethyl - 1,3-butadiene. Give reasonable mechanism
the formation of
the products
For
3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below:
Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life).
2
CH3
H
NO2
NO2
3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s)
H
a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.
Part I.
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff:
Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
and
(3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism
the formation of the products
For
Chapter 20 Solutions
CHEMISTRY:SCI.IN CONTEXT (CL)-PACKAGE
Ch. 20.2 - Prob. 1PECh. 20.2 - Prob. 2PECh. 20.2 - Prob. 3PECh. 20.3 - Prob. 4PECh. 20.3 - Prob. 5PECh. 20.3 - Prob. 6PECh. 20.6 - Prob. 7PECh. 20.6 - Prob. 8PECh. 20 - Prob. 20.1VPCh. 20 - Prob. 20.2VP
Ch. 20 - Prob. 20.3VPCh. 20 - Prob. 20.4VPCh. 20 - Prob. 20.5VPCh. 20 - Prob. 20.6VPCh. 20 - Prob. 20.7VPCh. 20 - Prob. 20.8VPCh. 20 - Prob. 20.9VPCh. 20 - Prob. 20.10VPCh. 20 - Prob. 20.11QPCh. 20 - Prob. 20.12QPCh. 20 - Prob. 20.13QPCh. 20 - Prob. 20.14QPCh. 20 - Prob. 20.15QPCh. 20 - Prob. 20.16QPCh. 20 - Prob. 20.17QPCh. 20 - Prob. 20.18QPCh. 20 - Prob. 20.19QPCh. 20 - Prob. 20.20QPCh. 20 - Prob. 20.21QPCh. 20 - Prob. 20.22QPCh. 20 - Prob. 20.23QPCh. 20 - Prob. 20.24QPCh. 20 - Prob. 20.25QPCh. 20 - Prob. 20.26QPCh. 20 - Prob. 20.27QPCh. 20 - Prob. 20.28QPCh. 20 - Prob. 20.29QPCh. 20 - Prob. 20.30QPCh. 20 - Prob. 20.31QPCh. 20 - Prob. 20.32QPCh. 20 - Prob. 20.33QPCh. 20 - Prob. 20.34QPCh. 20 - Prob. 20.35QPCh. 20 - Prob. 20.36QPCh. 20 - Prob. 20.37QPCh. 20 - Prob. 20.38QPCh. 20 - Prob. 20.39QPCh. 20 - Prob. 20.40QPCh. 20 - Prob. 20.41QPCh. 20 - Prob. 20.42QPCh. 20 - Prob. 20.43QPCh. 20 - Prob. 20.44QPCh. 20 - Prob. 20.45QPCh. 20 - Prob. 20.46QPCh. 20 - Prob. 20.47QPCh. 20 - Prob. 20.48QPCh. 20 - Prob. 20.49QPCh. 20 - Prob. 20.50QPCh. 20 - Prob. 20.51QPCh. 20 - Prob. 20.52QPCh. 20 - Prob. 20.53QPCh. 20 - Prob. 20.54QPCh. 20 - Prob. 20.55QPCh. 20 - Prob. 20.56QPCh. 20 - Prob. 20.57QPCh. 20 - Prob. 20.58QPCh. 20 - Prob. 20.59QPCh. 20 - Prob. 20.60QPCh. 20 - Prob. 20.61QPCh. 20 - Prob. 20.62QPCh. 20 - Prob. 20.63QPCh. 20 - Prob. 20.64QPCh. 20 - Prob. 20.65QPCh. 20 - Prob. 20.66QPCh. 20 - Prob. 20.67QPCh. 20 - Prob. 20.68QPCh. 20 - Prob. 20.69QPCh. 20 - Prob. 20.70QPCh. 20 - Prob. 20.71QPCh. 20 - Prob. 20.72QPCh. 20 - Prob. 20.73QPCh. 20 - Prob. 20.74QPCh. 20 - Prob. 20.75QPCh. 20 - Prob. 20.76QPCh. 20 - Prob. 20.77QPCh. 20 - Prob. 20.78QPCh. 20 - Prob. 20.79QPCh. 20 - Prob. 20.80QPCh. 20 - Prob. 20.81APCh. 20 - Prob. 20.82APCh. 20 - Prob. 20.83APCh. 20 - Prob. 20.84APCh. 20 - Prob. 20.85APCh. 20 - Prob. 20.86APCh. 20 - Prob. 20.87APCh. 20 - Prob. 20.88APCh. 20 - Prob. 20.89APCh. 20 - Prob. 20.90APCh. 20 - Prob. 20.91APCh. 20 - Prob. 20.92APCh. 20 - Prob. 20.93APCh. 20 - Prob. 20.94APCh. 20 - Prob. 20.95APCh. 20 - Prob. 20.96APCh. 20 - Prob. 20.97APCh. 20 - Prob. 20.98APCh. 20 - Prob. 20.99APCh. 20 - Prob. 20.100AP
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- Show the mechanism for these reactionsarrow_forwardDraw the stepwise mechanismarrow_forwardDraw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forward
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- 19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+arrow_forwardLi+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiClarrow_forwardQ4: Write organic product(s) of the following reactions and show the curved-arrow mechanism of the reactions. Br MeOH OSO2CH3 MeOHarrow_forward
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