(a) Interpretation: The different ways to prepare given ketone from an acid chloride and an organocuprate reagent are to be drawn. Concept introduction: Acid chlorides, which contains good leaving group Cl , on reaction with organocuprate give ketone as a product. Alkyl group from organocuprate occupies the position of leaving group Cl .

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Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 20, Problem 20.31P

Interpretation Introduction

(a)

Interpretation: The different ways to prepare given ketone from an acid chloride and an organocuprate reagent are to be drawn.

Concept introduction: Acid chlorides, which contains good leaving group Cl, on reaction with organocuprate give ketone as a product. Alkyl group from organocuprate occupies the position of leaving group Cl.

Interpretation Introduction

(b)

Interpretation: The different ways to prepare given ketone from an acid chloride and an organocuprate reagent are to be drawn.

Concept introduction: Acid chlorides, which contains good leaving group Cl, on reaction with organocuprate give ketone as a product. Alkyl group from organocuprate occupies the position of leaving group Cl.

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81. a. Propose a mechanism for the following reaction: OH CH2=CHCHC=N b. What is the product of the following reaction? HO H₂O N=CCH2CH2CH OH HO CH3CCH=CH2 H₂O C=N 82. Unlike a phosphonium ylide that reacts with an aldehyde or a ketone to form an alkene a sulfonium ulia

For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. ? NH2 MgBr Will the first product that forms in this reaction create a new CC bond? ○ Yes ○ No MgBr ? Will the first product that forms in this reaction create a new CC bond? O Yes O No Click and drag to start drawing a structure. :☐ G x c olo Ar HE

Predicting As the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule with a new C - C bond as its major product: H₂N O H 1. ? 2. H3O+ If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry. 0 If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank. فا Explanation Check Click and drag to start drawing a structure.

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 20, Problem 20.31P

Interpretation Introduction

(a)

Interpretation: The different ways to prepare given ketone from an acid chloride and an organocuprate reagent are to be drawn.

Concept introduction: Acid chlorides, which contains good leaving group Cl, on reaction with organocuprate give ketone as a product. Alkyl group from organocuprate occupies the position of leaving group Cl.

Interpretation Introduction

(b)

Interpretation: The different ways to prepare given ketone from an acid chloride and an organocuprate reagent are to be drawn.

Concept introduction: Acid chlorides, which contains good leaving group Cl, on reaction with organocuprate give ketone as a product. Alkyl group from organocuprate occupies the position of leaving group Cl.

Expert Solution & Answer

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 20, Problem 20.31P

Interpretation Introduction

(a)

Interpretation: The different ways to prepare given ketone from an acid chloride and an organocuprate reagent are to be drawn.

Concept introduction: Acid chlorides, which contains good leaving group Cl, on reaction with organocuprate give ketone as a product. Alkyl group from organocuprate occupies the position of leaving group Cl.

Interpretation Introduction

(b)

Interpretation: The different ways to prepare given ketone from an acid chloride and an organocuprate reagent are to be drawn.

Concept introduction: Acid chlorides, which contains good leaving group Cl, on reaction with organocuprate give ketone as a product. Alkyl group from organocuprate occupies the position of leaving group Cl.

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 20, Problem 20.31P

Interpretation Introduction

(a)

Interpretation: The different ways to prepare given ketone from an acid chloride and an organocuprate reagent are to be drawn.

Concept introduction: Acid chlorides, which contains good leaving group Cl, on reaction with organocuprate give ketone as a product. Alkyl group from organocuprate occupies the position of leaving group Cl.

Interpretation Introduction

(b)

Interpretation: The different ways to prepare given ketone from an acid chloride and an organocuprate reagent are to be drawn.

Concept introduction: Acid chlorides, which contains good leaving group Cl, on reaction with organocuprate give ketone as a product. Alkyl group from organocuprate occupies the position of leaving group Cl.

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Answer 5

Chapter 20, Problem 20.31P

Interpretation Introduction

(a)

Interpretation: The different ways to prepare given ketone from an acid chloride and an organocuprate reagent are to be drawn.

Concept introduction: Acid chlorides, which contains good leaving group Cl, on reaction with organocuprate give ketone as a product. Alkyl group from organocuprate occupies the position of leaving group Cl.

Interpretation Introduction

(b)

Interpretation: The different ways to prepare given ketone from an acid chloride and an organocuprate reagent are to be drawn.

Concept introduction: Acid chlorides, which contains good leaving group Cl, on reaction with organocuprate give ketone as a product. Alkyl group from organocuprate occupies the position of leaving group Cl.

Answer 6

Chapter 20, Problem 20.31P

Interpretation Introduction

(a)

Interpretation: The different ways to prepare given ketone from an acid chloride and an organocuprate reagent are to be drawn.

Concept introduction: Acid chlorides, which contains good leaving group Cl, on reaction with organocuprate give ketone as a product. Alkyl group from organocuprate occupies the position of leaving group Cl.

Answer 7

Chapter 20, Problem 20.31P

Interpretation Introduction

(a)

Interpretation: The different ways to prepare given ketone from an acid chloride and an organocuprate reagent are to be drawn.

Concept introduction: Acid chlorides, which contains good leaving group Cl, on reaction with organocuprate give ketone as a product. Alkyl group from organocuprate occupies the position of leaving group Cl.

Answer 8

Interpretation Introduction

(b)

Interpretation: The different ways to prepare given ketone from an acid chloride and an organocuprate reagent are to be drawn.

Concept introduction: Acid chlorides, which contains good leaving group Cl, on reaction with organocuprate give ketone as a product. Alkyl group from organocuprate occupies the position of leaving group Cl.

Answer 9

Interpretation Introduction

(b)

Interpretation: The different ways to prepare given ketone from an acid chloride and an organocuprate reagent are to be drawn.

Concept introduction: Acid chlorides, which contains good leaving group Cl, on reaction with organocuprate give ketone as a product. Alkyl group from organocuprate occupies the position of leaving group Cl.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 20 - Prob. 20.1P Ch. 20 - Which carbonyl groups in the anticancer drug taxol...Ch. 20 - Prob. 20.3P Ch. 20 - Problem 20.4 What alcohol is formed when each...Ch. 20 - Problem 20.5 What aldehyde or ketone is needed to...Ch. 20 - Prob. 20.6P Ch. 20 - Problem 20.7 Draw the products formed when is...Ch. 20 - Problem 20.8 Draw the products formed (including...Ch. 20 - Prob. 20.9P Ch. 20 - Problem 20.10 Draw a stepwise mechanism for the...

Solution Summary: The author explains the different ways to prepare given ketone from an acid chloride and an organocuprate reagent.

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