Introduction to General, Organic and Biochemistry
11th Edition
ISBN: 9781285869759
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Chapter 20, Problem 20.12P
Interpretation Introduction
Interpretation:
The meaning of the designations D and L as used to specify the configuration of a monosaccharide should be explained.
Concept Introduction:
In a monosaccharide, if at the last stereocenter the hydroxyl group is at right in the Fischer projection, the monosaccharide is known to have D configuration. Opposite to it if the hydroxyl group is at left, the monosaccharide will have L configuration.
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Draw the major substitution products you would expect for the reaction shown below. If substitution would not occur at a significant
rate under these conditions, check the box underneath the drawing area instead.
Be sure you use wedge and dash bonds where necessary, for example to distinguish between major products.
Note for advanced students: you can assume that the reaction mixture is heated mildly, somewhat above room temperature, but
strong heat or reflux is not used.
Cl
Substitution will not occur at a significant rate.
Explanation
Check
:☐
O-CH
+
Х
Click and drag to start
drawing a structure.
Draw the major substitution products you would expect for the reaction shown below. If substitution would not occur at a significant
rate under these conditions, check the box underneath the drawing area instead.
Be sure you use wedge and dash bonds where necessary, for example to distinguish between major products.
Note for advanced students: you can assume that the reaction mixture is heated mildly, somewhat above room temperature, but
strong heat or reflux is not used.
Cl
C
O Substitution will not occur at a significant rate.
Explanation
Check
+
O-CH3
Х
Click and drag to start
drawing a structure.
✓ aw the major substitution products you would expect for the reaction shown below. If substitution would not occur at a significant
rate under these conditions, check the box underneath the drawing area instead.
Be sure you use wedge and dash bonds where necessary, for example to distinguish between major products.
Note for advanced students: you can assume that the reaction mixture is heated mildly, somewhat above room temperature, but
strong heat or reflux is not used.
C
Cl
HO–CH
O Substitution will not occur at a significant rate.
Explanation
Check
-3
☐ :
+
D
Click and drag to start
drawing a structure.
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Chapter 20 Solutions
Introduction to General, Organic and Biochemistry
Ch. 20.1 - Prob. 20.1PCh. 20.2 - Prob. 20.2PCh. 20.2 - Prob. 20.3PCh. 20.3 - Prob. 20.4PCh. 20.4 - Prob. 20.5PCh. 20 - Prob. 20.6PCh. 20 - Prob. 20.7PCh. 20 - Prob. 20.8PCh. 20 - Prob. 20.9PCh. 20 - Prob. 20.10P
Ch. 20 - Prob. 20.11PCh. 20 - Prob. 20.12PCh. 20 - Prob. 20.13PCh. 20 - Prob. 20.14PCh. 20 - Prob. 20.15PCh. 20 - Prob. 20.16PCh. 20 - Prob. 20.17PCh. 20 - Prob. 20.18PCh. 20 - .19 What is an amino sugar? Name the three amino...Ch. 20 - Prob. 20.20PCh. 20 - Prob. 20.21PCh. 20 - Prob. 20.22PCh. 20 - Prob. 20.23PCh. 20 - Prob. 20.24PCh. 20 - Prob. 20.25PCh. 20 - Prob. 20.26PCh. 20 - Prob. 20.27PCh. 20 - Prob. 20.28PCh. 20 - Prob. 20.29PCh. 20 - Prob. 20.30PCh. 20 - Prob. 20.31PCh. 20 - Prob. 20.32PCh. 20 - Prob. 20.33PCh. 20 - Prob. 20.34PCh. 20 - Prob. 20.35PCh. 20 - Prob. 20.36PCh. 20 - Prob. 20.37PCh. 20 - Prob. 20.38PCh. 20 - Prob. 20.39PCh. 20 - Prob. 20.40PCh. 20 - Prob. 20.41PCh. 20 - Prob. 20.42PCh. 20 - Prob. 20.43PCh. 20 - Prob. 20.44PCh. 20 - Prob. 20.45PCh. 20 - 6 Where is glycogen stored in the human body?Ch. 20 - Prob. 20.47PCh. 20 - 8 How is it possible that cows can digest grass...Ch. 20 - Prob. 20.49PCh. 20 - Prob. 20.50PCh. 20 - 1 Hyaluronic acid acts as a lubricant in the...Ch. 20 - 2 The anticlotting property of heparin is partly...Ch. 20 - Prob. 20.53PCh. 20 - Prob. 20.54PCh. 20 - Prob. 20.55PCh. 20 - Prob. 20.56PCh. 20 - Prob. 20.57PCh. 20 - Prob. 20.58PCh. 20 - Prob. 20.59PCh. 20 - Prob. 20.60PCh. 20 - Prob. 20.61PCh. 20 - 2 In making candy or sugar syrups, sucrose is...Ch. 20 - Prob. 20.63PCh. 20 - Prob. 20.64PCh. 20 - Prob. 20.65PCh. 20 - Prob. 20.66PCh. 20 - Prob. 20.67PCh. 20 - Prob. 20.68PCh. 20 - Prob. 20.69PCh. 20 - 0 What are the structural differences between...Ch. 20 - Prob. 20.71PCh. 20 - Prob. 20.72PCh. 20 - Prob. 20.73PCh. 20 - Prob. 20.74PCh. 20 - Prob. 20.75PCh. 20 - Prob. 20.76PCh. 20 - Prob. 20.77PCh. 20 - Prob. 20.78PCh. 20 - Prob. 20.79PCh. 20 - Prob. 20.80PCh. 20 - Prob. 20.81PCh. 20 - Prob. 20.82PCh. 20 - Prob. 20.83PCh. 20 - Prob. 20.84PCh. 20 - Prob. 20.85PCh. 20 - Prob. 20.86PCh. 20 - Prob. 20.87PCh. 20 - Prob. 20.88PCh. 20 - Prob. 20.89P
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