Chemistry (7th Edition)
Chemistry (7th Edition)
7th Edition
ISBN: 9780321943170
Author: John E. McMurry, Robert C. Fay, Jill Kirsten Robinson
Publisher: PEARSON
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Chapter 20, Problem 20.113SP
Interpretation Introduction

Interpretation:

It should be explained as why the dxy and dx2-y2orbitals different energies in an octahedral complex.

Concept introduction:

There are five d-orbitals: dxy,dyz, dzx, dx2-y2,dz2

To determine:

Explain why the dxy and dx2-y2orbitals different energies in an octahedral complex.

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LTS Solid: AT=Te-Ti Trial 1 Trial 2 Trial 3 Average ΔΗ Mass water, g 24.096 23.976 23.975 Moles of solid, mol 0.01763 001767 0101781 Temp. change, °C 2.9°C 11700 2.0°C Heat of reaction, J -292.37J -170.473 -193.26J AH, kJ/mole 16.58K 9.647 kJ 10.85 kr 16.58K59.64701 KJ mol 12.35k Minimum AS, J/mol K 41.582 mol-k Remember: q = mCsAT (m = mass of water, Cs=4.184J/g°C) & qsin =-qrxn & Show your calculations for: AH in J and then in kJ/mole for Trial 1: qa (24.0969)(4.1845/g) (-2.9°C)=-292.37J qsin = qrxn = 292.35 292.37J AH in J = 292.375 0.2923kJ 0.01763m01 =1.65×107 AH in kJ/mol = = 16.58K 0.01763mol mol qrx Minimum AS in J/mol K (Hint: use the average initial temperature of the three trials, con Kelvin.) AS=AHIT (1.65×10(9.64×103) + (1.0 Jimai
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Chapter 20 Solutions

Chemistry (7th Edition)

Ch. 20 - Prob. 20.11PCh. 20 - Prob. 20.12ACh. 20 - Prob. 20.13PCh. 20 - Prob. 20.14ACh. 20 - Prob. 20.15PCh. 20 - Prob. 20.16ACh. 20 - Prob. 20.17PCh. 20 - Prob. 20.18ACh. 20 - Prob. 20.19PCh. 20 - Prob. 20.20PCh. 20 - Prob. 20.21ACh. 20 - Prob. 20.22PCh. 20 - Prob. 20.23ACh. 20 - Prob. 20.24PCh. 20 - Prob. 20.25ACh. 20 - Prob. 20.26PCh. 20 - Prob. 20.27PCh. 20 - Prob. 20.28PCh. 20 - Prob. 20.29PCh. 20 - Prob. 20.30CPCh. 20 - Prob. 20.31CPCh. 20 - Prob. 20.32CPCh. 20 - Prob. 20.33CPCh. 20 - Prob. 20.34CPCh. 20 - Prob. 20.35CPCh. 20 - Prob. 20.36CPCh. 20 - Prob. 20.37CPCh. 20 - Prob. 20.38CPCh. 20 - Prob. 20.39CPCh. 20 - Prob. 20.40SPCh. 20 - Prob. 20.41SPCh. 20 - Prob. 20.42SPCh. 20 - Prob. 20.43SPCh. 20 - Titanium, used to make jet aircraft engines, is...Ch. 20 - Prob. 20.45SPCh. 20 - Prob. 20.46SPCh. 20 - Prob. 20.47SPCh. 20 - Prob. 20.48SPCh. 20 - Prob. 20.49SPCh. 20 - Prob. 20.50SPCh. 20 - Prob. 20.51SPCh. 20 - Prob. 20.52SPCh. 20 - Prob. 20.53SPCh. 20 - Prob. 20.54SPCh. 20 - Prob. 20.55SPCh. 20 - Prob. 20.56SPCh. 20 - Prob. 20.57SPCh. 20 - Prob. 20.58SPCh. 20 - Prob. 20.59SPCh. 20 - Prob. 20.60SPCh. 20 - Prob. 20.61SPCh. 20 - Prob. 20.62SPCh. 20 - Prob. 20.63SPCh. 20 - Prob. 20.64SPCh. 20 - Prob. 20.65SPCh. 20 - Prob. 20.66SPCh. 20 - Prob. 20.67SPCh. 20 - Prob. 20.68SPCh. 20 - Prob. 20.69SPCh. 20 - Prob. 20.70SPCh. 20 - Prob. 20.71SPCh. 20 - Prob. 20.72SPCh. 20 - Prob. 20.73SPCh. 20 - Prob. 20.74SPCh. 20 - Prob. 20.75SPCh. 20 - Prob. 20.76SPCh. 20 - Prob. 20.77SPCh. 20 - Prob. 20.78SPCh. 20 - Prob. 20.79SPCh. 20 - Prob. 20.80SPCh. 20 - Prob. 20.81SPCh. 20 - Prob. 20.82SPCh. 20 - Prob. 20.83SPCh. 20 - Prob. 20.84SPCh. 20 - Prob. 20.85SPCh. 20 - Prob. 20.86SPCh. 20 - Prob. 20.87SPCh. 20 - Prob. 20.88SPCh. 20 - Prob. 20.89SPCh. 20 - Prob. 20.90SPCh. 20 - Prob. 20.91SPCh. 20 - Prob. 20.92SPCh. 20 - Prob. 20.93SPCh. 20 - Prob. 20.94SPCh. 20 - Prob. 20.95SPCh. 20 - Prob. 20.96SPCh. 20 - Prob. 20.97SPCh. 20 - Prob. 20.98SPCh. 20 - Prob. 20.99SPCh. 20 - Prob. 20.100SPCh. 20 - Prob. 20.101SPCh. 20 - Prob. 20.102SPCh. 20 - Prob. 20.103SPCh. 20 - Prob. 20.104SPCh. 20 - Prob. 20.105SPCh. 20 - Prob. 20.106SPCh. 20 - Prob. 20.107SPCh. 20 - Prob. 20.108SPCh. 20 - Prob. 20.109SPCh. 20 - Prob. 20.110SPCh. 20 - Prob. 20.111SPCh. 20 - Prob. 20.112SPCh. 20 - Prob. 20.113SPCh. 20 - Prob. 20.114SPCh. 20 - Prob. 20.115SPCh. 20 - Prob. 20.116SPCh. 20 - Prob. 20.117SPCh. 20 - Prob. 20.118SPCh. 20 - Prob. 20.119SPCh. 20 - Prob. 20.120SPCh. 20 - Prob. 20.121SPCh. 20 - Prob. 20.122SPCh. 20 - Prob. 20.123SPCh. 20 - Prob. 20.124CPCh. 20 - Prob. 20.125CPCh. 20 - Prob. 20.126CPCh. 20 - Prob. 20.127CPCh. 20 - Prob. 20.128CPCh. 20 - Prob. 20.129CPCh. 20 - Prob. 20.130CPCh. 20 - Prob. 20.131CPCh. 20 - Prob. 20.132CPCh. 20 - Prob. 20.133CPCh. 20 - Prob. 20.134CPCh. 20 - Prob. 20.135CPCh. 20 - Prob. 20.136CPCh. 20 - Prob. 20.137CPCh. 20 - Prob. 20.138CPCh. 20 - Prob. 20.139CPCh. 20 - Prob. 20.140CPCh. 20 - Prob. 20.141CPCh. 20 - Prob. 20.142CPCh. 20 - Prob. 20.143CPCh. 20 - Prob. 20.144CPCh. 20 - Prob. 20.145CPCh. 20 - Prob. 20.146CPCh. 20 - Prob. 20.147CPCh. 20 - Prob. 20.148CPCh. 20 - Prob. 20.149MPCh. 20 - Prob. 20.150MPCh. 20 - Prob. 20.151MPCh. 20 - Prob. 20.152MPCh. 20 - Prob. 20.153MPCh. 20 - Prob. 20.154MPCh. 20 - Prob. 20.155MPCh. 20 - Prob. 20.156MPCh. 20 - Prob. 20.157MP
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