Explanation (i) The dissociation of the following compound is, NH 4 NO 3 ( a q ) ⇌ NH 4 + ( a q ) + NO 3 − ( a q ) The conjugate base of strong acid does not alter the pH . NO 3 − is a conjugate base of strong base. So, it does not affect the pH of the solution. NH 4 + is a conjugate acid of weak base. So, it decreases the pH . Hence, the pH of the solution is acidic. (ii) The dissociation of the following compound is, NaNO 3 ( a q ) ⇌ Na + ( a q ) + NO 3 − ( a q ) The conjugate base of strong acid does not alter the pH . NO 3 − is a conjugate base of strong base. So, it does not affect the pH of the solution. Na belongs to group I and it is extremely weak acid such that it not even reacts with water so, it does not alter the pH of the reaction. Hence, the pH of the solution is neutral. (iii) The dissociation of the following compound is, NH 4 C 2 H 3 O 2 ( a q ) ⇌ NH 4 + ( a q ) + C 2 H 3 O 2 − ( a q ) The conjugate base of strong acid does not alter the pH . NH 4 + is a conjugate acid of weak base. C 2 H 3 O 2 − is a conjugate base of weak acid, the ions are extremely weak acid such that it not even reacts with water so, they does not alter the pH of the reaction Hence, the pH of the solution is neutral

Chemistry: The Central Science (13th Edition)

13th Edition

ISBN: 9780321910417

Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus

Publisher: PEARSON

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Chapter 2, Problem 85E

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To determine: The correct order of increasing acidity for the given compounds.

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Chapter 2, Problem 84E

Chapter 2, Problem 86E

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Chapter 2 Solutions

Chemistry: The Central Science (13th Edition)

Ch. 2.3 - Prob. 2.1.1PE Ch. 2.3 - Prob. 2.1.2PE Ch. 2.3 - Prob. 2.2.1PE Ch. 2.3 - Prob. 2.2.2PE Ch. 2.3 - Prob. 2.3.1PE Ch. 2.3 - Prob. 2.3.2PE Ch. 2.4 - Practice Exercise 1 The atomic weight of copper,...Ch. 2.4 - Prob. 2.4.2PE Ch. 2.5 - Prob. 2.5.1PE Ch. 2.5 - Prob. 2.5.2PE

Ch. 2.6 - 11.93 The vapor pressure of ethanol (C2H5OH) at 19...Ch. 2.6 - Prob. 2.6.2PE Ch. 2.7 - Prob. 2.7.1PE Ch. 2.7 - Prob. 2.7.2PE Ch. 2.7 - Prob. 2.8.1PE Ch. 2.7 - Consider the two-dimensional square lattice of...Ch. 2.7 - Prob. 2.9.1PE Ch. 2.7 - Given the ionic radii and molar masses of Sc3+...Ch. 2.7 - Prob. 2.10.1PE Ch. 2.7 - Prob. 2.10.2PE Ch. 2.8 - Prob. 2.11.1PE Ch. 2.8 - Prob. 2.11.2PE Ch. 2.8 - Prob. 2.12.1PE Ch. 2.8 - Prob. 2.12.2PE Ch. 2.8 - Prob. 2.13.1PE Ch. 2.8 - The table below shows the normal boiling points of...Ch. 2.8 - Prob. 2.14.1PE Ch. 2.8 - Prob. 2.14.2PE Ch. 2.9 - Prob. 2.15.1PE Ch. 2.9 - Prob. 2.15.2PE Ch. 2 - Prob. 1E Ch. 2 - At 280C, raw milk sours in 4.0 h but takes 48 h to...Ch. 2 - At 900 o C, Kc = 0.0108 for the reaction CaCO3(g) ...Ch. 2 - Calculate the molar concentration of OH- in a...Ch. 2 - Pyridinium bromide (C5H5NHBr) is a strong...Ch. 2 - Prob. 6E Ch. 2 - Prob. 7E Ch. 2 - Prob. 8E Ch. 2 - Prob. 9E Ch. 2 - Indicate whether each statement is true or false:...Ch. 2 - Prob. 11E Ch. 2 - Prob. 12E Ch. 2 - Prob. 13E Ch. 2 - At 20 oC, the vapor pressure of benzene (C6 H6) is...Ch. 2 - Summarize the evidence used by J. J. Thomson to...Ch. 2 - Prob. 16E Ch. 2 - Prob. 17E Ch. 2 - Prob. 18E Ch. 2 - Suppose the rate law for the reaction in this...Ch. 2 - Practice Exercise 1 Using the data in Sample...Ch. 2 - Which of the following linear plots do you expect...Ch. 2 - A flask is charged with 0.100 mol of A and allowed...Ch. 2 - Prob. 23E Ch. 2 - Prob. 24E Ch. 2 - Prob. 25E Ch. 2 - Prob. 26E Ch. 2 - The addition of No accelerates the decomposition...Ch. 2 - Prob. 28E Ch. 2 - Prob. 29E Ch. 2 - The rates of many atmospheric reactions are...Ch. 2 - Prob. 31E Ch. 2 - Prob. 32E Ch. 2 - Prob. 33E Ch. 2 - 15.23 The equilibrium constant for the...Ch. 2 - A mixture of 0.10 mol of NO, 0.050 mol of H2, and...Ch. 2 - Prob. 36E Ch. 2 - Prob. 37E Ch. 2 - Prob. 38E Ch. 2 - Prob. 39E Ch. 2 - Prob. 40E Ch. 2 - Practice Exercise 1 Order the following three...Ch. 2 - Practice Exercise 1 What is the pH of a 0.28 M...Ch. 2 - Prob. 43E Ch. 2 - Which of the following diagrams best represent an...Ch. 2 - Prob. 45E Ch. 2 - Prob. 46E Ch. 2 - Prob. 47E Ch. 2 - Prob. 48E Ch. 2 - Prob. 49E Ch. 2 - 16.72 Calculate the molar concentration of OH- in...Ch. 2 - Prob. 51E Ch. 2 - Prob. 52E Ch. 2 - Prob. 53E Ch. 2 - Prob. 54E Ch. 2 - a. Given that Ka for acetic acid is 1.8 10-5 and...Ch. 2 - 16.78 a. Given that Kb for ammonia is 1.8 X 10 -5...Ch. 2 - Prob. 57E Ch. 2 - Prob. 58E Ch. 2 - Prob. 59E Ch. 2 - Prob. 60E Ch. 2 - Prob. 61E Ch. 2 - Prob. 62E Ch. 2 - 16.86 An unknown salt is either KBr, NH4 C1, KCN,...Ch. 2 - Prob. 64E Ch. 2 - Prob. 65E Ch. 2 - 16.89 Based on their compositions and structures...Ch. 2 - Prob. 67E Ch. 2 - 16.91 Indicate whether each of the following...Ch. 2 - Prob. 69E Ch. 2 - Prob. 70E Ch. 2 - Prob. 71E Ch. 2 - Prob. 72E Ch. 2 - Prob. 73E Ch. 2 - Prob. 74E Ch. 2 - Prob. 75E Ch. 2 - Prob. 76E Ch. 2 - Prob. 77E Ch. 2 - Prob. 78E Ch. 2 - Prob. 79E Ch. 2 - Benzoic acid (C6H5COOH) and aniline (C6H5NH2) are...Ch. 2 - Prob. 81E Ch. 2 - Prob. 82E Ch. 2 - Prob. 83E Ch. 2 - Butyric acid is responsible for the foul smell of...Ch. 2 - Prob. 85E Ch. 2 - Prob. 86E Ch. 2 - Prob. 87AE Ch. 2 - 1S.113 Many moderately large organic molecules...Ch. 2 - Prob. 89AE Ch. 2 - Prob. 90AE Ch. 2 - Prob. 91AE Ch. 2 - Prob. 92AE Ch. 2 - Prob. 93AE Ch. 2 - 16.120 At 50 oC, the ion-product constant for H2...Ch. 2 - Prob. 95AE Ch. 2 - Prob. 96AE Ch. 2 - Prob. 97AE Ch. 2 - Prob. 98AE Ch. 2 - Prob. 99AE Ch. 2 - Which two statements about gas mixtures are true?...Ch. 2 - Prob. 101AE Ch. 2 - 13.6 If you compare the solubilities of the noble...Ch. 2 - Prob. 103AE Ch. 2 - Prob. 104AE Ch. 2 - Suppose you had a balloon made of some highly...Ch. 2 - Prob. 106AE Ch. 2 - Indicate whether each statement is true or false:...Ch. 2 - Indicate the type of solute-solvent interaction...Ch. 2 - An ionic compound has a very negative H soln in...Ch. 2 - Prob. 110AE Ch. 2 - Prob. 111AE Ch. 2 - The solubility of Cr (NO3)3 . 9 H2O in water is...

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