CHEMISTRY:PRIN.+REACTIONS-OWLV2 ACCESS
8th Edition
ISBN: 9781305079298
Author: Masterton
Publisher: Cengage Learning
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Chapter 2, Problem 83QAP
Scientists are trying to synthesize elements with more than 114 protons. State the expected
(a) the newest inert gas.
(b) the new element with properties similar to those of the alkaline earth metals.
(c) the new element that will behave like the halogens.
(d) the new (nontransition) metal whose ion will have a +2 charge.
(e) the new element that will start period 8.
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10.
Stereochemistry. Assign R/S stereochemistry for the chiral center indicated on the
following compound. In order to recieve full credit, you MUST SHOW YOUR WORK!
H₂N
CI
OH
CI
カー
11. () Stereochemistry. Draw all possible stereoisomers of the following compound. Assign
R/S configurations for all stereoisomers and indicate the relationship between each as
enantiomer, diastereomer, or meso.
NH2
H
HNH,
-18
b)
8.
Indicate whether the following carbocation rearrangements are likely to occur
Please explain your rational using 10 words or less
not likely to occur
• The double bond is still in the
Same position
+
Likely
to oc
occur
WHY?
-3
H3C
Brave
Chair Conformers. Draw the chair conformer of the following substituted
cyclohexane. Peform a RING FLIP and indicate the most stable
conformation and briefly explain why using 20 words or less.
CI
2
-cobs ??
MUST INDICATE H -2
-2
Br
EQ
Cl
OR
AT
Br
H&
most stable
WHY?
- 4
CH
12
Conformational Analysis. Draw all 6 conformers (one above each letter) of the
compound below looking down the indicated bond. Write the letter of the
conformer with the HIGHEST and LOWEST in energies on the lines provided.
NOTE: Conformer A MUST be the specific conformer of the structure as drawn below
-4 NOT
HOH
OH
3
Conformer A:
Br
OH
A
Samo
Br H
04
Br
H
H3
CH₂
H
anti
stagere
Br CH
clipsed
H
Brott
H
IV
H
MISSING 2
-2
B
C
D
E
F
X
6
Conformer with HIGHEST ENERGY:
13. (1
structure
LOWEST ENERGY:
Nomenclature. a) Give the systematic (IUPAC) name structure. b) Draw the
corresponding to this name. HINT: Do not forget to indicate stereochemistry
when applicable.
a)
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Parent name (noname)
4 Bromo
Sub = 2-methylethyl-4 Bromo nonane
b) (3R,4S)-3-chloro-4-ethyl-2,7-dimethyloctane
# -2
-2
Chapter 2 Solutions
CHEMISTRY:PRIN.+REACTIONS-OWLV2 ACCESS
Ch. 2 - Atomic Theory and Laws State in your own words the...Ch. 2 - State in your own words the law of constant...Ch. 2 - Two basic laws of chemistry are the law of...Ch. 2 - Two basic laws of chemistry are the law of...Ch. 2 - Who discovered the electron? Describe the...Ch. 2 - Who discovered the nucleus? Describe the...Ch. 2 - Selenium is widely sold as a dietary supplement....Ch. 2 - Radon is a radioactive gas that can cause lung...Ch. 2 - How do the isotopes of argon, Ar-36, Ar-38, and...Ch. 2 - Consider two isotopes Fe-54 and Fe-56. (a) Write...
Ch. 2 - Uranium-235 is the isotope of uranium commonly...Ch. 2 - An isotope of americium (Am) with 146 neutrons is...Ch. 2 - Prob. 13QAPCh. 2 - Prob. 14QAPCh. 2 - Prob. 15QAPCh. 2 - See the definition for isobars in Question 15....Ch. 2 - Calculate the mass ratio of a bromine atom to an...Ch. 2 - Arrange the following in the order of increasing...Ch. 2 - Cerium is the most abundant rare earth metal. Pure...Ch. 2 - Consider the three stable isotopes of oxygen with...Ch. 2 - Bromine has two occuring isotopes: 79Br with...Ch. 2 - Rubidium has two naturally occurring isotopes:...Ch. 2 - Strontium has four isotopes with the following...Ch. 2 - Neon is an inert gas with three stable isotopes....Ch. 2 - Naturally occurring silver (Ag) consists of two...Ch. 2 - Copper has two naturally occurring isotopes. Cu-63...Ch. 2 - Silicon (averageatomicmass=28.0855amu) has three...Ch. 2 - Magnesium (averageatomicmass=24.305amu) consists...Ch. 2 - Zinc has four stable isotopes: Zn-64, Zn-66,...Ch. 2 - Chlorine has two isotopes, Cl-35 and Cl-37. Their...Ch. 2 - Lead is a heavy metal that remains in the...Ch. 2 - Silversmiths are warned to limit their exposure to...Ch. 2 - Determine (a) the number of atoms in 0.185 g of...Ch. 2 - For bismuth (Bi), determine (a) the number of...Ch. 2 - The isotope Si-28 has a mass of 27.977 amu. For...Ch. 2 - Myocardial perfusion imaging (MPI) is the latest...Ch. 2 - A cube of sodium has length 1.25 in. How many...Ch. 2 - A cylindrical piece of pure copper (d=8.92g/cm2)...Ch. 2 - Give the symbols for (a) potassium (b) cadmium (c)...Ch. 2 - Prob. 40QAPCh. 2 - Prob. 41QAPCh. 2 - Prob. 42QAPCh. 2 - How many metals are in the following groups? (a)...Ch. 2 - How many nonmetals are in the following periods?...Ch. 2 - Which group in the periodic table (a) has one...Ch. 2 - Which period of the periodic table (a) has no...Ch. 2 - Prob. 47QAPCh. 2 - Prob. 48QAPCh. 2 - Prob. 49QAPCh. 2 - Prob. 50QAPCh. 2 - Prob. 51QAPCh. 2 - Complete the table given below.Ch. 2 - Classify the following compounds as electrolytes...Ch. 2 - Prob. 54QAPCh. 2 - Prob. 55QAPCh. 2 - Prob. 56QAPCh. 2 - Prob. 57QAPCh. 2 - Write the names of the following molecules. (a)...Ch. 2 - Prob. 59QAPCh. 2 - Prob. 60QAPCh. 2 - Prob. 61QAPCh. 2 - Prob. 62QAPCh. 2 - Prob. 63QAPCh. 2 - Prob. 64QAPCh. 2 - Write the names of the following ionic compounds....Ch. 2 - Prob. 66QAPCh. 2 - Complete the following table.Ch. 2 - Complete the following table.Ch. 2 - Prob. 69QAPCh. 2 - Prob. 70QAPCh. 2 - Prob. 71QAPCh. 2 - Prob. 72QAPCh. 2 - Criticize each of the following statements: (a)...Ch. 2 - Which of the following statements is/are always...Ch. 2 - Some brands of salami contain 0.090% sodium...Ch. 2 - Carbon tetrachloride, CCl4, was a popular...Ch. 2 - Prob. 77QAPCh. 2 - Prob. 78QAPCh. 2 - Prob. 79QAPCh. 2 - Use the law of conservation of mass to determine...Ch. 2 - Prob. 81QAPCh. 2 - Prob. 82QAPCh. 2 - Scientists are trying to synthesize elements with...Ch. 2 - Write the nuclear symbol for the element whose...Ch. 2 - Prob. 85QAPCh. 2 - Write the atomic symbol for the element whose ion...Ch. 2 - Prob. 87QAPCh. 2 - Three compounds containing only carbon and...Ch. 2 - Ethane and ethylene are two gases containing only...Ch. 2 - Calculate the average density of a single Al-27...Ch. 2 - Prob. 91QAPCh. 2 - Each time you inhale, you take in about 500 mL...Ch. 2 - Hydrogen gas is prepared in a lab experiment. In...
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