Introduction to General, Organic and Biochemistry
12th Edition
ISBN: 9780357119303
Author: Bettelheim, Frederick A., Brown, William H., Campbell, Mary K., FARRELL, Shawn O., Torres, Omar
Publisher: Cengage Learning
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Question
Chapter 2, Problem 7P
Interpretation Introduction
Interpretation:
The name and symbol of the two elements which are named for planets should be identified.
Concept Introduction:
The symbols of chemical elements are abbreviated that are used to denote the chemical element. Most of the chemical symbols corresponds directly to the name of the element in English, although few are derived from the Latin or German.
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Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
C.
NaOMe,
Br
Br
Chapter 2 Solutions
Introduction to General, Organic and Biochemistry
Ch. 2.2 - Problem 2-1 Write the formulas of compounds in...Ch. 2.4 - Problem 2-2 What is the mass number of an atom...Ch. 2.4 - Problem 2-3 Name the elements given in Problem...Ch. 2.4 - Problem 2-4 (a) What are the atomic numbers of...Ch. 2.4 - Prob. 2.5QCCh. 2.4 - Problem 2-6 The atomic weight of lithium is 6.941...Ch. 2.6 - Problem 2-7 Write the Lewis dot structure for the...Ch. 2 - Prob. 1PCh. 2 - 9 Answer true or false. (a) Matter is divided into...Ch. 2 - Prob. 3P
Ch. 2 - Prob. 4PCh. 2 - 2-12 The elements game, Part 1. Name and give the...Ch. 2 - Prob. 6PCh. 2 - Prob. 7PCh. 2 - Prob. 8PCh. 2 - Prob. 9PCh. 2 - 2-17 How does Dalton’s atomic theory explain: (a)...Ch. 2 - Prob. 11PCh. 2 - Prob. 12PCh. 2 - 2-20 Calculate the percentage of hydrogen and...Ch. 2 - Prob. 14PCh. 2 - Prob. 15PCh. 2 - 2-23 It has been said, “The number of protons...Ch. 2 - Prob. 17PCh. 2 - Prob. 18PCh. 2 - 2-26 Given these mass numbers and number of...Ch. 2 - If each atom in Problem 19 acquired two more...Ch. 2 - Prob. 21PCh. 2 - 2-29 How many protons and how many neutrons does...Ch. 2 - Prob. 23PCh. 2 - 2-31 Tin-118 is one of the isotopes of tin. Name...Ch. 2 - Prob. 25PCh. 2 - Prob. 26PCh. 2 - 2-34 There are only two naturally occurring...Ch. 2 - 2-35 The two most abundant naturally occurring...Ch. 2 - Prob. 29PCh. 2 - Prob. 30PCh. 2 - Prob. 31PCh. 2 - Prob. 32PCh. 2 - Prob. 33PCh. 2 - Prob. 34PCh. 2 - Prob. 35PCh. 2 - 2-43 Which group(s) of the Periodic Table...Ch. 2 - 2-44 Which period(s) in the Periodic Table...Ch. 2 - Prob. 38PCh. 2 - Prob. 39PCh. 2 - 2-47 Which element in each pair is more metallic?...Ch. 2 - Prob. 41PCh. 2 - Prob. 42PCh. 2 - Prob. 43PCh. 2 - 2-51 What is the correlation between the group...Ch. 2 - Prob. 45PCh. 2 - Prob. 46PCh. 2 - Prob. 47PCh. 2 - Prob. 48PCh. 2 - Prob. 49PCh. 2 - Prob. 50PCh. 2 - Prob. 51PCh. 2 - 2-59 You are presented with a Lewis dot structure...Ch. 2 - Prob. 53PCh. 2 - Prob. 54PCh. 2 - Prob. 55PCh. 2 - Prob. 56PCh. 2 - 2-64 Consider the elements B, C, and N. Using only...Ch. 2 - Prob. 58PCh. 2 - Prob. 59PCh. 2 - 2-67 Account for the fact that the first...Ch. 2 - Prob. 61PCh. 2 - 2-69 (Chemical Connections 2A) Why does the body...Ch. 2 - Prob. 63PCh. 2 - Prob. 64PCh. 2 - Prob. 65PCh. 2 - 2-73 (Chemical Connections 2D) Copper is a soft...Ch. 2 - Prob. 67PCh. 2 - Prob. 68PCh. 2 - Prob. 69PCh. 2 - Prob. 70PCh. 2 - Prob. 71PCh. 2 - Prob. 72PCh. 2 - Prob. 73PCh. 2 - Prob. 74PCh. 2 - Prob. 75PCh. 2 - 2-83 The natural abundance of boron isotopes is as...Ch. 2 - Prob. 77PCh. 2 - 2-85 The mass of a proton is 1.67 × 10-24g. The...Ch. 2 - Prob. 79PCh. 2 - Prob. 80PCh. 2 - Prob. 81PCh. 2 - Prob. 82PCh. 2 - Prob. 83PCh. 2 - 2-91 These are the first two ionization energy for...Ch. 2 - Prob. 85PCh. 2 - Prob. 86PCh. 2 - 2-94 Using your knowledge of trends in element...Ch. 2 - Prob. 88PCh. 2 - Prob. 89PCh. 2 - 2-97 Explain why the Ca3+ ion is not found in...Ch. 2 - 2-98 Explain how the ionization energy of atoms...Ch. 2 - 2-99 A 7.12 g sample of magnesium is heated with...Ch. 2 - 2-100 A 0.100 g sample of magnesium, when combined...Ch. 2 - 2-101 Complete the following table: Symbol Atomic...Ch. 2 - 2-102 An element consists of 90.51% of an isotope...Ch. 2 - 2-103 The element silver has two naturally...Ch. 2 - 2-104 The average atomic weight of lithium is...Ch. 2 - Prob. 98PCh. 2 - Prob. 99PCh. 2 - Consider the Period 3 elements of the Periodic...Ch. 2 - Name the element that corresponds to each of the...
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