Introduction to General, Organic and Biochemistry
12th Edition
ISBN: 9780357119303
Author: Bettelheim, Frederick A., Brown, William H., Campbell, Mary K., FARRELL, Shawn O., Torres, Omar
Publisher: Cengage Learning
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Chapter 2, Problem 44P
2-51 What is the correlation between the group number of the main-group elements (those in the A columns of the Mendeleyev system) and the number of valence electrons in an element in the group?
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A hydrogen-like ion is an ion containing only one electron. The energies of the electron in a hydrogen-like ion are given by
(2.180 × 10-¹5 1) 2² (1)
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E =
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where n is the principal quantum number, and Z is the atomic number of the element. Calculate the ionization energy, in
your answer to 4 significant digits.
mol
Note: Reference the Fundamental constants table for additional information.
·2+
of the Li²+ ion. Round
I
(b) A new element, "X", is discovered and found to have 2 electrons in its outer level.
Is X a metal or non-metal? Predict the formula its ion would have in any ionic
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Chapter 2 Solutions
Introduction to General, Organic and Biochemistry
Ch. 2.2 - Problem 2-1 Write the formulas of compounds in...Ch. 2.4 - Problem 2-2 What is the mass number of an atom...Ch. 2.4 - Problem 2-3 Name the elements given in Problem...Ch. 2.4 - Problem 2-4 (a) What are the atomic numbers of...Ch. 2.4 - Prob. 2.5QCCh. 2.4 - Problem 2-6 The atomic weight of lithium is 6.941...Ch. 2.6 - Problem 2-7 Write the Lewis dot structure for the...Ch. 2 - Prob. 1PCh. 2 - 9 Answer true or false. (a) Matter is divided into...Ch. 2 - Prob. 3P
Ch. 2 - Prob. 4PCh. 2 - 2-12 The elements game, Part 1. Name and give the...Ch. 2 - Prob. 6PCh. 2 - Prob. 7PCh. 2 - Prob. 8PCh. 2 - Prob. 9PCh. 2 - 2-17 How does Dalton’s atomic theory explain: (a)...Ch. 2 - Prob. 11PCh. 2 - Prob. 12PCh. 2 - 2-20 Calculate the percentage of hydrogen and...Ch. 2 - Prob. 14PCh. 2 - Prob. 15PCh. 2 - 2-23 It has been said, “The number of protons...Ch. 2 - Prob. 17PCh. 2 - Prob. 18PCh. 2 - 2-26 Given these mass numbers and number of...Ch. 2 - If each atom in Problem 19 acquired two more...Ch. 2 - Prob. 21PCh. 2 - 2-29 How many protons and how many neutrons does...Ch. 2 - Prob. 23PCh. 2 - 2-31 Tin-118 is one of the isotopes of tin. Name...Ch. 2 - Prob. 25PCh. 2 - Prob. 26PCh. 2 - 2-34 There are only two naturally occurring...Ch. 2 - 2-35 The two most abundant naturally occurring...Ch. 2 - Prob. 29PCh. 2 - Prob. 30PCh. 2 - Prob. 31PCh. 2 - Prob. 32PCh. 2 - Prob. 33PCh. 2 - Prob. 34PCh. 2 - Prob. 35PCh. 2 - 2-43 Which group(s) of the Periodic Table...Ch. 2 - 2-44 Which period(s) in the Periodic Table...Ch. 2 - Prob. 38PCh. 2 - Prob. 39PCh. 2 - 2-47 Which element in each pair is more metallic?...Ch. 2 - Prob. 41PCh. 2 - Prob. 42PCh. 2 - Prob. 43PCh. 2 - 2-51 What is the correlation between the group...Ch. 2 - Prob. 45PCh. 2 - Prob. 46PCh. 2 - Prob. 47PCh. 2 - Prob. 48PCh. 2 - Prob. 49PCh. 2 - Prob. 50PCh. 2 - Prob. 51PCh. 2 - 2-59 You are presented with a Lewis dot structure...Ch. 2 - Prob. 53PCh. 2 - Prob. 54PCh. 2 - Prob. 55PCh. 2 - Prob. 56PCh. 2 - 2-64 Consider the elements B, C, and N. Using only...Ch. 2 - Prob. 58PCh. 2 - Prob. 59PCh. 2 - 2-67 Account for the fact that the first...Ch. 2 - Prob. 61PCh. 2 - 2-69 (Chemical Connections 2A) Why does the body...Ch. 2 - Prob. 63PCh. 2 - Prob. 64PCh. 2 - Prob. 65PCh. 2 - 2-73 (Chemical Connections 2D) Copper is a soft...Ch. 2 - Prob. 67PCh. 2 - Prob. 68PCh. 2 - Prob. 69PCh. 2 - Prob. 70PCh. 2 - Prob. 71PCh. 2 - Prob. 72PCh. 2 - Prob. 73PCh. 2 - Prob. 74PCh. 2 - Prob. 75PCh. 2 - 2-83 The natural abundance of boron isotopes is as...Ch. 2 - Prob. 77PCh. 2 - 2-85 The mass of a proton is 1.67 × 10-24g. The...Ch. 2 - Prob. 79PCh. 2 - Prob. 80PCh. 2 - Prob. 81PCh. 2 - Prob. 82PCh. 2 - Prob. 83PCh. 2 - 2-91 These are the first two ionization energy for...Ch. 2 - Prob. 85PCh. 2 - Prob. 86PCh. 2 - 2-94 Using your knowledge of trends in element...Ch. 2 - Prob. 88PCh. 2 - Prob. 89PCh. 2 - 2-97 Explain why the Ca3+ ion is not found in...Ch. 2 - 2-98 Explain how the ionization energy of atoms...Ch. 2 - 2-99 A 7.12 g sample of magnesium is heated with...Ch. 2 - 2-100 A 0.100 g sample of magnesium, when combined...Ch. 2 - 2-101 Complete the following table: Symbol Atomic...Ch. 2 - 2-102 An element consists of 90.51% of an isotope...Ch. 2 - 2-103 The element silver has two naturally...Ch. 2 - 2-104 The average atomic weight of lithium is...Ch. 2 - Prob. 98PCh. 2 - Prob. 99PCh. 2 - Consider the Period 3 elements of the Periodic...Ch. 2 - Name the element that corresponds to each of the...
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- 2-59 You are presented with a Lewis dot structure of element X as X.. To which two groups in the Periodic Table might this element belong?arrow_forward2-47 Which element in each pair is more metallic? (a) Silicon or aluminum (b) Arsenic or phosphorus (c) Gallium or germanium (d) Gallium or aluminumarrow_forward2-89 Assume that a new element has been discovered with atomic number 117. Its chemical properties should be similar to those of astatine (At). Predict whether the new element’s ionization energy will be greater than, the same as, or smaller than that of: (a)At (b)Raarrow_forward
- 2-91 These are the first two ionization energy for lithium: Li(g) Li+(g) + e-(g) Ionization energy = 523 kJ/mol Li+(g) Li2+(g) + e-(g) Ionization energy = 7298 kJ/mol (a) Explain the large increase in ionization energy that occurs for the removal of the second electron. (b) The radius of Li is 78 pm (1 pm = 10-12 m) while that of a lithium atom, Li, is 152 pm. Exp lain why the radius of Li is so much smaller than the radius of Li.arrow_forward2-94 Using your knowledge of trends in element sizes in going across a period of the Periodic Table, exp lain why the density of the elements increases from potassium through vanadium. (Recall from Section 1-7 that specific gravity is numerically the same as density but has no units.) Element Specific Gravity K 0.862 Ca1.55 Se 2.99 Ti 4.54 V 6.11arrow_forward2-12 The elements game, Part 1. Name and give the symbol of the element that is named for each person. (a) Niels Bohr (1885—1962), Nobel Prize for physics in 1922 (b) Pierre and Marie Curie, Nobel Prize for chemistry in 1903 (c) Albert Einstein (1879—1955), Nobel Prize for physics in 1921 (d) Enrico Fermi (1901—1954), Nobel Prize for physics in 1938 (e) Ernest Lawrence (1901—1958), Nobel Prize for physics in 1939 (f) Lise Meitner (1868—1968, codiscoverer of nuclear fission (g) Dmitri Mendeleyev (1834—1907), first person to formulate a workable Periodic Table h) Alfred Nobel (1833—1896), discoverer of dynamite (i) Ernest Rutherford (1871—1937), Nobel Prize for chemistry in 1908 (j) Glen Seaborg (1912—1999), Nobel Prize for chemistry in 1951arrow_forward
- 2-64 Consider the elements B, C, and N. Using only the Periodic Table, predict which of these three elements has: (a) the largest atomic radius. (b) the smallest atomic radius. (c) the largest ionization energy (d) the smallest ionization energyarrow_forward2-102 An element consists of 90.51% of an isotope with a mass of 19.992 amu, 0.27% of an isotope with a mass of 20.994 amu, and 9.22% of an isotope with a mass of 21.990 amu. Calculate the average atomic mass and identify the element.arrow_forward2-104 The average atomic weight of lithium is 6.941 amu. The two naturally occurring isotopes of lithium have the following masses: 6Li, 6.01512 amu; 7Li, 7.01600 amu. Calculate the percent abundance of 6Li and 7Li in naturally occurring lithium.arrow_forward
- 2-43 Which group(s) of the Periodic Table contain(s): (a) Only metals? (b) Only metalloids? (c) Only nonmetals?arrow_forward1-An atomic cation with a charge of +2 has the following electron configuration: [He] 2s22p4 What is the chemical symbol for the ion? How many electrons does the ion have? How many 2s electrons are in the ion? 2- Ammonium perchlorate (NH4ClO4) is powerful solid rocket fuel, used in the Space Shuttle boosters. It decomposes into nitrogen (N2) gas, chlorine (Cl2) gas, oxygen (O2) gas, and water vapor, releasing a great deal of energy. Calculate the moles of chlorine produced by the reaction of 0.90mol of ammonium perchlorate. Be sure your answer has a unit symbol, if necessary, and round it to the correct number of significant digits. _____________ 3-How many protons and neutrons are in an atom of Th-229 ? Number of protons= ________ Number of neutrons= _______ 4- The chemical formula for beryllium sulfide is BeS. A chemist determined by measurements that 0.055 moles of beryllium sulfide…arrow_forwardBoron, atomic number 5, occurs naturally as two isotopes, 10B and 11B, with natural abundances of 19.9% and 80.1%, respectively. (a) In what ways do the two isotopes differ from each other? Does the electronic configuration of 10B differ from that of 11B? (b) Draw the orbital diagram for an atom of 11B. Which electrons are the valence electrons? (c) Indicate three ways in which the 1s electrons in boron differ from its 2s electrons. (d) Elemental boron reacts with fluorine to form BF3, a gas. Write a balanced chemical equation for the reaction of solid boron with fluorine gas. (e) ΔHf° for BF3(g) is -1135.6 kj/mol. Calculate the standard enthalpy change in the reaction of boron with fluorine. (f) Will the mass percentage of F be the same in 10BF3 and 11BF3? If not, why is that the case?arrow_forward
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