Chemical Principles
8th Edition
ISBN: 9781337247269
Author: Steven S. Zumdahl; Donald J. DeCoste
Publisher: Cengage Learning US
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Chapter 2, Problem 77AE
Interpretation Introduction
Interpretation: The value of
Concept introduction: In a neutral atom, the number of electrons present is equal to protons. These two are also equivalent to the
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In a sample of any metal, spherical atoms pack closelytogether, but the space between them means that the density of thesample is less than that of the atoms themselves. Iridium (Ir) isone of the densest elements: 22.56 g/cm³. The atomic mass of Iris 192.22 amu, and the mass of the nucleus is 192.18 amu.Determine the density (in g/cm³) of (a) an Ir atom and (b) an Irnucleus. (c) How many Ir atoms placed in a row would extend1.00 cm [radius of Ir atom = 1.36 Å; radius of Ir nucleus = 1.5 femtometers (fm); V of a sphere =(4/3)πr³]?
You have two distinct gaseous compounds made from element X and element Y. The mass percents are as follows
Compound I: 32.66% X, 67.34% Y
Compound II: 65.99% X, 34.01% Y
In their natural standard states, element X and element Y exist as gases. (Monatomic? Diatomic? Triatomic? That is for you to determine.) When you
react "gas X" with "gas Y" to make the products, you get the following data (all at the same pressure and temperature):
I volume "gas X" +2 volumes "gas Y"2 volumes compound I
2 volumes "gas XI volume "gas Y"2 volumes compound II
Assume the simplest possible formulas for reactants and products in these chemical equations, Then determine the relative atomic masses of element X
and element Y
Atomic mass Y
Atomic mass X
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✔Question 25
Which of the following formula and chemical nan combin tions is correctly shown?
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N₂O₂; nitrogen dioxide
N₂O; dinitrogen pentoxide
Ca₂P; dicalclum diphosphide
PCI; phosphorus tetrachloride
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Chapter 2 Solutions
Chemical Principles
Ch. 2 - You may have noticed that when water boils, you...Ch. 2 - Which of the following is true about an individual...Ch. 2 - How would you go about finding the number of...Ch. 2 - These questions concern the work of J. J. Thomson:...Ch. 2 - Heat is applied to an ice cube in a closed...Ch. 2 - You have a chemical in a sealed glass container...Ch. 2 - Prob. 7DQCh. 2 - One of the best indications of a useful theory is...Ch. 2 - Prob. 9DQCh. 2 - How does Dalton’s atomic theory account for each...
Ch. 2 - What refinements had to be made in Dalton’s...Ch. 2 - Which (if any) of the following can be determined...Ch. 2 - The average mass of a carbon atom is 12.011....Ch. 2 - Which of the following explain how an ion is...Ch. 2 - Prob. 15DQCh. 2 - Prob. 16DQCh. 2 - Why is calcium dichloride not the correct...Ch. 2 - Explain the law of conservation of mass, the law...Ch. 2 - Prob. 19ECh. 2 - When mixtures of gaseous H2 and gaseous Cl2 react,...Ch. 2 - Observations of the reaction between nitrogen gas...Ch. 2 - Prob. 22ECh. 2 - Hydrazine, ammonia, and hydrogen azide all contain...Ch. 2 - Consider 80.0-g samples of two different compounds...Ch. 2 - Early tables of atomic weights (masses) were...Ch. 2 - What evidence led to the conclusion that cathode...Ch. 2 - Prob. 27ECh. 2 - Prob. 28ECh. 2 - A chemist in a galaxy far, far away performed the...Ch. 2 - Do the proton and the neutron have exactly the...Ch. 2 - Consider Ernest Rutherford’s a-particle...Ch. 2 - Distinguish between the following terms. a....Ch. 2 - What is the distinction between atomic number and...Ch. 2 - Prob. 34ECh. 2 - a. List the noble gas elements. Which of the noble...Ch. 2 - Consider the elements of the carbon family: C, Si,...Ch. 2 - Prob. 37ECh. 2 - The number of protons in an atom determines the...Ch. 2 - For lighter, stable isotopes, the ratio of the...Ch. 2 - For each of the following sets of elements, label...Ch. 2 - Prob. 41ECh. 2 - Write the atomic symbol (ZAX) for each of the...Ch. 2 - Prob. 43ECh. 2 - Prob. 44ECh. 2 - Prob. 45ECh. 2 - Prob. 46ECh. 2 - Would you expect each of the following atoms to...Ch. 2 - Prob. 48ECh. 2 - The compounds AlCl3,CrCl3,andICl3 have similar...Ch. 2 - Each of the following compounds has three...Ch. 2 - Prob. 51ECh. 2 - Prob. 52ECh. 2 - Prob. 53ECh. 2 - Prob. 54ECh. 2 - Prob. 55ECh. 2 - Prob. 56ECh. 2 - Prob. 57ECh. 2 - Prob. 58ECh. 2 - Prob. 59ECh. 2 - Prob. 60ECh. 2 - Prob. 61ECh. 2 - Prob. 62AECh. 2 - Prob. 63AECh. 2 - What discoveries were made by J. J. Thomson,...Ch. 2 - Prob. 65AECh. 2 - Prob. 66AECh. 2 - A sample of chloroform is found to contain 12.0 g...Ch. 2 - In a reaction, 34.0 g of chromium(III) oxide...Ch. 2 - Prob. 69AECh. 2 - Prob. 70AECh. 2 - Prob. 71AECh. 2 - Prob. 72AECh. 2 - Prob. 73AECh. 2 - Prob. 74AECh. 2 - Prob. 75AECh. 2 - Prob. 76AECh. 2 - Prob. 77AECh. 2 - Prob. 78AECh. 2 - Prob. 79AECh. 2 - Identify each of the following elements. a. a...Ch. 2 - A certain element has only two naturally occurring...Ch. 2 - Prob. 82AECh. 2 - Which of the following is(are) correct? a. 40Ca2+...Ch. 2 - Prob. 84AECh. 2 - Prob. 85AECh. 2 - Complete the following table to predict whether...Ch. 2 - Which of the following statements is(are) correct?...Ch. 2 - Prob. 88CPCh. 2 - Each of the statements below is true, but Dalton...Ch. 2 - You take three compounds, each consisting of two...Ch. 2 - Two elements, R and Q, combine to form two...Ch. 2 - A single molecule has a mass of 7.3110223g ....Ch. 2 - A combustion reaction involves the reaction of a...Ch. 2 - You have two distinct gaseous compounds made from...Ch. 2 - You have gone back in time and are working with...
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- In Groups 4A-6A, there are several elements whose symbols begin with S. Name these elements, and for each one give its symbol, atomic number, group number, and period. Describe each as a metal, metalloid, or nonmetal.arrow_forwardIndium oxide contains 4.784 g of indium for every 1.000 g of oxygen. In 1869, when Mendeleev first presented his version of the periodic table, he proposed the formula ln2O3 for indium oxide. Before that time it was thought that the formula was InO. What values for the atomic mass of indium are obtained using these two formulas? Assume that oxygen has an atomic mass of 16.00.arrow_forwardCalculate the average density of a single Al-27 atom by assuming that it is a sphere with a radius of 0.143 nm. The masses of a proton, electron, and neutron are 1.67261024g,9.10941028g, and 1.67491024g, respectively. The volume of a sphere is 4r3/3, where r is its radius. Express the answer in grams per cubic centimeter. The density of aluminum is found experimentally to be 2.70 g/cm3. What does that suggest about the packing of aluminum atoms in the metal?arrow_forward
- You have two distinct gaseous compounds made from element X and element Y. The mass percents are as follows: Compound I: 30.43% X, 69.57% Y Compound II: 63.64% X, 36.36% Y In their natural standard states, element X and element Y exist as gases. (Monatomic? Diatomic? Triatomic? That is for you to determine.) When you react gas X with gas Y to make the products, you get the following data (all at the same pressure and temperature): 1. volume gas X + 2 volumes gas Y2 volumes compound I 2. volumes gas X + 1 volume gas Y2 volumes compound II Assume the simplest possible formulas for reactants and products in the chemical equations above. Then, determine the relative atomic masses of element X and element Y.arrow_forwardIn 1886 Eugene Goldstein observed positively charged particles moving in the opposite direction to electrons in a cathode ray tube (illustrated below). From their mass, he concluded that these particles were formed from residual gas in the tube. For example, if the cathode ray tube contained helium, the canal rays consisted of He+ ions. Describe a process that could lead to these ions. Canal rays. In 1886, Eugene Goldstein detected a stream of particles traveling in the direction opposite to that of the negatively charged cathode rays (electrons). He called this stream of positive particles "canal rays:"arrow_forwardA gaseous binary compound has a vapor density that is 1.94 times that of oxygen at the same temperature and pressure. When 1.39 g of the gas is burned in an excess of oxygen, 1.21 g water is formed, removing all the hydrogen originally present. (a) Estimate the molecular mass of the gaseous compound. (b) How many hydrogen atoms are there in a molecule of the compound? (c) What is the maximum possible value of the atomic mass of the second element in the compound? (d) Are other values possible for the atomic mass of the second element? Use a table of atomic masses to identify the element that best fits the data. (e) What is the molecular formula of the compound?arrow_forward
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- Copper atoms. (a) What is the average mass of one copper atom? (b) Students in a college computer science class once sued the college because they were asked to calculate the cost of one atom and could not do it. But you are in a chemistry course, and you can do this. (See E. Felsenthal, Wall Street Journal, May 9, 1995.) If the cost of 2.0-mm diameter copper wire (99.9995% pure] is currently 41.70 for 7.0 g, what is the cost of one copper atom?arrow_forwardTwo basic laws of chemistry are the law of conservation of mass and the law of constant composition. Which of these laws (if any) do the following statements illustrate? (a) Lavoisier found that when mercury(ll) oxide, HgO, decomposes, the total mass of mercury (Hg) and oxygen formed equals the mass of mercury(ll) oxide decomposed. (b) Analysis of the calcium carbonate found in the marble mined in Carrara, Italy, and in the stalactites of the Carlsbad Caverns in New Mexico gives the same value for the percentage of calcium in calcium carbonate. (c) Hydrogen occurs as a mixture of two isotopes, one of which is twice as heavy as the other.arrow_forwardReference Section 5-2 to find the atomic masses of 12C and 13C, the relative abundance of 12C and 13C in natural carbon, and the average mass (in u) of a carbon atom. If you had a sample of natural carbon containing exactly 10,000 atoms, determine the number of 12C and 13C atoms present. What would be the average mass (in u) and the total mass (in u) of the carbon atoms in this 10,000-atom sample? If you had a sample of natural carbon containing 6.0221 1023 atoms, determine the number of 12C and 13C atoms present What would be the average mass (in u) and the total mass (in u) of this 6.0221 1023 atom sample? Given that 1 g = 6.0221 1023 u, what is the total mass of I mole of natural carbon in units of grams?arrow_forward
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