Chemical Principles
8th Edition
ISBN: 9781337247269
Author: Steven S. Zumdahl; Donald J. DeCoste
Publisher: Cengage Learning US
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Textbook Question
Chapter 2, Problem 6DQ
You have a chemical in a sealed glass container filled withair. The setup is sitting on a balance, as shown. The chemicalis ignited by means of a magnifying glass focusing sunlighton the reactant. After the chemical has completely burned,which of the following is true? Explain your answer.
a. The balance will read less than 250.0 g.
b. The balance will read 250.0 g.
c. The balance will read greater than 250.0 g.
d. Cannot be determined without knowing the identityof the chemical.
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each pair of substrates below, choose the one that will react faster in a substitution reaction, assuming that:
1. the rate of substitution doesn't depend on nucleophile concentration and
2. the products are a roughly 50/50 mixture of enantiomers.
Substrate A
Substrate B
Faster Rate
X
Ś
CI
(Choose one)
(Choose one)
CI
Br
Explanation
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Br
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NMR spectrum of ethyl acetate has signals whose chemical shifts are indicated below. Which hydrogen or set of hydrogens corresponds to the signal at
4.1 ppm? Select the single best answer.
The
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A
ethyl acetate
H NMR: 1.3 ppm, 2.0 ppm, 4.1 ppm
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C
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How many signals do you expect in the H NMR spectrum for this molecule?
Br Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red
Note for advanced students: In this question, any multiplet is counted as one signal.
1
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
O
✓
No additional Hs to color in top
molecule
ง
No additional Hs to color in bottom…
Chapter 2 Solutions
Chemical Principles
Ch. 2 - You may have noticed that when water boils, you...Ch. 2 - Which of the following is true about an individual...Ch. 2 - How would you go about finding the number of...Ch. 2 - These questions concern the work of J. J. Thomson:...Ch. 2 - Heat is applied to an ice cube in a closed...Ch. 2 - You have a chemical in a sealed glass container...Ch. 2 - Prob. 7DQCh. 2 - One of the best indications of a useful theory is...Ch. 2 - Prob. 9DQCh. 2 - How does Dalton’s atomic theory account for each...
Ch. 2 - What refinements had to be made in Dalton’s...Ch. 2 - Which (if any) of the following can be determined...Ch. 2 - The average mass of a carbon atom is 12.011....Ch. 2 - Which of the following explain how an ion is...Ch. 2 - Prob. 15DQCh. 2 - Prob. 16DQCh. 2 - Why is calcium dichloride not the correct...Ch. 2 - Explain the law of conservation of mass, the law...Ch. 2 - Prob. 19ECh. 2 - When mixtures of gaseous H2 and gaseous Cl2 react,...Ch. 2 - Observations of the reaction between nitrogen gas...Ch. 2 - Prob. 22ECh. 2 - Hydrazine, ammonia, and hydrogen azide all contain...Ch. 2 - Consider 80.0-g samples of two different compounds...Ch. 2 - Early tables of atomic weights (masses) were...Ch. 2 - What evidence led to the conclusion that cathode...Ch. 2 - Prob. 27ECh. 2 - Prob. 28ECh. 2 - A chemist in a galaxy far, far away performed the...Ch. 2 - Do the proton and the neutron have exactly the...Ch. 2 - Consider Ernest Rutherford’s a-particle...Ch. 2 - Distinguish between the following terms. a....Ch. 2 - What is the distinction between atomic number and...Ch. 2 - Prob. 34ECh. 2 - a. List the noble gas elements. Which of the noble...Ch. 2 - Consider the elements of the carbon family: C, Si,...Ch. 2 - Prob. 37ECh. 2 - The number of protons in an atom determines the...Ch. 2 - For lighter, stable isotopes, the ratio of the...Ch. 2 - For each of the following sets of elements, label...Ch. 2 - Prob. 41ECh. 2 - Write the atomic symbol (ZAX) for each of the...Ch. 2 - Prob. 43ECh. 2 - Prob. 44ECh. 2 - Prob. 45ECh. 2 - Prob. 46ECh. 2 - Would you expect each of the following atoms to...Ch. 2 - Prob. 48ECh. 2 - The compounds AlCl3,CrCl3,andICl3 have similar...Ch. 2 - Each of the following compounds has three...Ch. 2 - Prob. 51ECh. 2 - Prob. 52ECh. 2 - Prob. 53ECh. 2 - Prob. 54ECh. 2 - Prob. 55ECh. 2 - Prob. 56ECh. 2 - Prob. 57ECh. 2 - Prob. 58ECh. 2 - Prob. 59ECh. 2 - Prob. 60ECh. 2 - Prob. 61ECh. 2 - Prob. 62AECh. 2 - Prob. 63AECh. 2 - What discoveries were made by J. J. Thomson,...Ch. 2 - Prob. 65AECh. 2 - Prob. 66AECh. 2 - A sample of chloroform is found to contain 12.0 g...Ch. 2 - In a reaction, 34.0 g of chromium(III) oxide...Ch. 2 - Prob. 69AECh. 2 - Prob. 70AECh. 2 - Prob. 71AECh. 2 - Prob. 72AECh. 2 - Prob. 73AECh. 2 - Prob. 74AECh. 2 - Prob. 75AECh. 2 - Prob. 76AECh. 2 - Prob. 77AECh. 2 - Prob. 78AECh. 2 - Prob. 79AECh. 2 - Identify each of the following elements. a. a...Ch. 2 - A certain element has only two naturally occurring...Ch. 2 - Prob. 82AECh. 2 - Which of the following is(are) correct? a. 40Ca2+...Ch. 2 - Prob. 84AECh. 2 - Prob. 85AECh. 2 - Complete the following table to predict whether...Ch. 2 - Which of the following statements is(are) correct?...Ch. 2 - Prob. 88CPCh. 2 - Each of the statements below is true, but Dalton...Ch. 2 - You take three compounds, each consisting of two...Ch. 2 - Two elements, R and Q, combine to form two...Ch. 2 - A single molecule has a mass of 7.3110223g ....Ch. 2 - A combustion reaction involves the reaction of a...Ch. 2 - You have two distinct gaseous compounds made from...Ch. 2 - You have gone back in time and are working with...
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