Chemistry Atoms First2e
2nd Edition
ISBN: 9781947172647
Author: OpenStax
Publisher: OpenStax College
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Chapter 2, Problem 59E
A certain nut crunch cereal contains 11.0 grams of sugar
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NMR spectrum of ethyl acetate has signals whose chemical shifts are indicated below. Which hydrogen or set of hydrogens corresponds to the signal at
4.1 ppm? Select the single best answer.
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ethyl acetate
H NMR: 1.3 ppm, 2.0 ppm, 4.1 ppm
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How many signals do you expect in the H NMR spectrum for this molecule?
Br Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red
Note for advanced students: In this question, any multiplet is counted as one signal.
1
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
O
✓
No additional Hs to color in top
molecule
ง
No additional Hs to color in bottom…
in the kinetics experiment, what were the values calculated? Select all that apply.a) equilibrium constantb) pHc) order of reactiond) rate contstant
Chapter 2 Solutions
Chemistry Atoms First2e
Ch. 2 - In the following drawing, the green spheres...Ch. 2 - Which postulate of Dalton’s theory is consistent...Ch. 2 - Identify the postulate of Dalton’s theory that is...Ch. 2 - Samples of compound X, Y, and Z are analyzed, with...Ch. 2 - The existence of isotopes violates one of the...Ch. 2 - How are electrons and protons similar? How are...Ch. 2 - How are protons and neutrons similar? How are they...Ch. 2 - Predict and test the behavior of a particles fired...Ch. 2 - Predict and test the behavior of a particles fired...Ch. 2 - In what way are isotopes of a given element always...
Ch. 2 - Write the symbol for each of the following ions:...Ch. 2 - Write the symbol for each of the following ions:...Ch. 2 - Open the Build an Atom simulation...Ch. 2 - Open the Build an Atom simulation...Ch. 2 - Open the Build an Atom simulation...Ch. 2 - Determine the number of protons, neutrons, and...Ch. 2 - The following are properties of isotopes of two...Ch. 2 - Give the number of protons, electrons, and...Ch. 2 - Give the number of protons, electrons, and...Ch. 2 - Click on the site...Ch. 2 - Click on the site...Ch. 2 - An element has the following natural abundances...Ch. 2 - Average atomic masses listed by JUPAC are based on...Ch. 2 - Variations in average atomic mass may be observed...Ch. 2 - The average atomic masses of some elements may...Ch. 2 - The 18O:16O abundance ratio in some meteorites is...Ch. 2 - Explain why the symbol for an atom of the element...Ch. 2 - Explain why the symbol for the element sulfur and...Ch. 2 - Write the molecular and empirical formulas of the...Ch. 2 - Write the molecular and empirical formulas of the...Ch. 2 - Determine the empirical formulas for the following...Ch. 2 - Determine the empirical formulas for the following...Ch. 2 - Write the empirical formulas for the following...Ch. 2 - Open the Build a Molecule simulation...Ch. 2 - Use the Build a Molecule simulation...Ch. 2 - Use the Build a Molecule simulation...Ch. 2 - Write a sentence that describes how to determine...Ch. 2 - Compare 1 mole of H2, 1 mole of o2, and 1 mole of...Ch. 2 - Which contains the greatest mass of oxygen: 0.75...Ch. 2 - Which contains the greatest number of moles of...Ch. 2 - How are the molecular mass and the molar mass of a...Ch. 2 - Calculate the molar mass of each of the following...Ch. 2 - Calculate the molar mass of each of the following:...Ch. 2 - Calculate the empirical or molecular formula mass...Ch. 2 - Calculate the molar mass of each of the following:...Ch. 2 - Determine the number of moles of compound and the...Ch. 2 - Determine the mass of each of the following: (a)...Ch. 2 - Determine the number of moles of the compound and...Ch. 2 - Determine the mass of each of the following: (a)...Ch. 2 - The approximate minimum daily dietary requirement...Ch. 2 - Determine the mass in grams of each of the...Ch. 2 - A 55-kg woman has 7.5103 mol of hemoglobin (...Ch. 2 - Determine the number of atoms and the mass of...Ch. 2 - Determine which of the following contains the...Ch. 2 - Determine which of the following contains the...Ch. 2 - Diamond is one form of elemental carbon. An...Ch. 2 - The Cullinan diamond was the largest natural...Ch. 2 - One 53-gram serving of a particular cereal...Ch. 2 - A certain nut crunch cereal contains 11.0 grams of...Ch. 2 - A tube of toothpaste contains 0.76 g of sodium...Ch. 2 - Which of the following represents the least number...
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- true or false, given that a 20.00 mL sample of NaOH took 24.15 mL of 0.141 M HCI to reach the endpoint in a titration, the concentration of the NaOH is 1.17 M.arrow_forwardin the bromothymol blue experiment, pKa was measured. A closely related compound has a Ka of 2.10 x 10-5. What is the pKa?a) 7.1b) 4.7c) 2.0arrow_forwardcalculate the equilibrium concentration of H2 given that K= 0.017 at a constant temperature for this reaction. The inital concentration of HBr is 0.050 M.2HBr(g) ↔ H2(g) + Br2(g)a) 4.48 x 10-2 M b) 5.17 x 10-3 Mc) 1.03 x 10-2 Md) 1.70 x 10-2 Marrow_forward
- true or falsegiven these two equilibria with their equilibrium constants:H2(g) + CI2(l) ↔ 2HCI(g) K= 0.006 CI2(l) ↔ CI2(g) K= 0.30The equilibrium contstant for the following reaction is 1.8H2(g) + CI2 ↔ 2HCI(g)arrow_forwardI2(g) + CI2(g) ↔ 2ICIK for this reaction is 81.9. Find the equilibrium concentration of I2 if the inital concentration of I2 and CI2 are 0.010 Marrow_forwardtrue or false,the equilibrium constant for this reaction is 0.50.PCI5(g) ↔ PCI3(g) + CI2(g)Based on the above, the equilibrium constant for the following reaction is 0.25.2PCI5(g) ↔. 2PCI3(g) + 2CI2(g)arrow_forward
- true or false, using the following equilibrium, if carbon dioxide is added the equilibrium will shift toward the productsC(s) + CO2(g) ↔ 2CO(g)arrow_forward2S2O2/3- (aq) + I2 (aq) ---> S4O2/6- (aq) +2I- (aq) Experiment I2 (M) S2O3- (M) Initital Rate (M/s) 1 0.01 0.01 0.0004 2 0.01 0.02 0.0004 3 0.02 0.01 0.0008 Calculate the overall order for this reaction using the table data a) 3b) 0c) 2d) 1arrow_forwardthe decomposition of N2O5 is the first order with a half-life of 1.98 minutes. If the inital concentration of N2O5 is 0.200 M, what is the concentration after 6 minutes?a) 0.612 Mb) 0.035 Mc) 0.024 Md) 0.100 Marrow_forward
- 20.00 mL of 0.150 M HCI is titrated with 0.075 M NaOH. What volume of NaOH is needed?a) 50 mLb) 20 mLc) 40 mLd) 26.66 mLarrow_forward20.00 mL of 0.150 M NaOH is titrated with 37.75 mL of HCI. What is the molarity of the HCI?a) 0.150 Mb) 0.079 Mc) 0.025 Md) 0.050 Marrow_forwardin the following reaction, the OH- acts as which of these?NO2- (aq) + H2O (l) ⇌ OH- (aq) + HNO2 (aq)a) not a weak acidb) basec) acidarrow_forward
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