Chemistry Atoms First2e
2nd Edition
ISBN: 9781947172647
Author: OpenStax
Publisher: OpenStax College
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Chapter 2, Problem 26E
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Draw the stepwise mechanism for the reactions
Part I.
a)
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone
b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
(3,3-dimethyl-2-butanone) and 2, 3-dimethyl - 1,3-butadiene. Give reasonable mechanism
the formation of
the products
For
3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below:
Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life).
2
CH3
H
NO2
NO2
3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s)
H
a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.
Chapter 2 Solutions
Chemistry Atoms First2e
Ch. 2 - In the following drawing, the green spheres...Ch. 2 - Which postulate of Dalton’s theory is consistent...Ch. 2 - Identify the postulate of Dalton’s theory that is...Ch. 2 - Samples of compound X, Y, and Z are analyzed, with...Ch. 2 - The existence of isotopes violates one of the...Ch. 2 - How are electrons and protons similar? How are...Ch. 2 - How are protons and neutrons similar? How are they...Ch. 2 - Predict and test the behavior of a particles fired...Ch. 2 - Predict and test the behavior of a particles fired...Ch. 2 - In what way are isotopes of a given element always...
Ch. 2 - Write the symbol for each of the following ions:...Ch. 2 - Write the symbol for each of the following ions:...Ch. 2 - Open the Build an Atom simulation...Ch. 2 - Open the Build an Atom simulation...Ch. 2 - Open the Build an Atom simulation...Ch. 2 - Determine the number of protons, neutrons, and...Ch. 2 - The following are properties of isotopes of two...Ch. 2 - Give the number of protons, electrons, and...Ch. 2 - Give the number of protons, electrons, and...Ch. 2 - Click on the site...Ch. 2 - Click on the site...Ch. 2 - An element has the following natural abundances...Ch. 2 - Average atomic masses listed by JUPAC are based on...Ch. 2 - Variations in average atomic mass may be observed...Ch. 2 - The average atomic masses of some elements may...Ch. 2 - The 18O:16O abundance ratio in some meteorites is...Ch. 2 - Explain why the symbol for an atom of the element...Ch. 2 - Explain why the symbol for the element sulfur and...Ch. 2 - Write the molecular and empirical formulas of the...Ch. 2 - Write the molecular and empirical formulas of the...Ch. 2 - Determine the empirical formulas for the following...Ch. 2 - Determine the empirical formulas for the following...Ch. 2 - Write the empirical formulas for the following...Ch. 2 - Open the Build a Molecule simulation...Ch. 2 - Use the Build a Molecule simulation...Ch. 2 - Use the Build a Molecule simulation...Ch. 2 - Write a sentence that describes how to determine...Ch. 2 - Compare 1 mole of H2, 1 mole of o2, and 1 mole of...Ch. 2 - Which contains the greatest mass of oxygen: 0.75...Ch. 2 - Which contains the greatest number of moles of...Ch. 2 - How are the molecular mass and the molar mass of a...Ch. 2 - Calculate the molar mass of each of the following...Ch. 2 - Calculate the molar mass of each of the following:...Ch. 2 - Calculate the empirical or molecular formula mass...Ch. 2 - Calculate the molar mass of each of the following:...Ch. 2 - Determine the number of moles of compound and the...Ch. 2 - Determine the mass of each of the following: (a)...Ch. 2 - Determine the number of moles of the compound and...Ch. 2 - Determine the mass of each of the following: (a)...Ch. 2 - The approximate minimum daily dietary requirement...Ch. 2 - Determine the mass in grams of each of the...Ch. 2 - A 55-kg woman has 7.5103 mol of hemoglobin (...Ch. 2 - Determine the number of atoms and the mass of...Ch. 2 - Determine which of the following contains the...Ch. 2 - Determine which of the following contains the...Ch. 2 - Diamond is one form of elemental carbon. An...Ch. 2 - The Cullinan diamond was the largest natural...Ch. 2 - One 53-gram serving of a particular cereal...Ch. 2 - A certain nut crunch cereal contains 11.0 grams of...Ch. 2 - A tube of toothpaste contains 0.76 g of sodium...Ch. 2 - Which of the following represents the least number...
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- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone and (3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forwardShow the mechanism for these reactionsarrow_forwardDraw the stepwise mechanismarrow_forward
- Draw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forwardDraw the stepwise mechanism for the reactionsarrow_forwardDraw stepwise mechanismarrow_forward
- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: a) Give the major reason for the exposure of benzophenone al isopropyl alcohol (w/acid) to direct sunlight of pina colone Mechanism For b) Pinacol (2,3-dimethy 1, 1-3-butanediol) on treatment w/ acid gives a mixture (3,3-dimethyl-2-butanone) and 2, 3-dimethyl-1,3-butadiene. Give reasonable the formation of the productsarrow_forwardwhat are the Iupac names for each structurearrow_forwardWhat are the IUPAC Names of all the compounds in the picture?arrow_forward
- 1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)arrow_forward19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+arrow_forwardLi+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiClarrow_forward
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