Organic Chemistry
12th Edition
ISBN: 9781118875766
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Textbook Question
Chapter 2, Problem 48P
The IR spectrum of propanoic acid (Fig. 2.16) indicates that the absorption for the O–H stretch of the
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. (a) Write the molecular formula of acetylsalicylic acid (see Fig. 7.34a).(b) An aspirin tablet contains 325 mg acetylsalicylic acid. Calculate the number of moles of that compound in the tablet.
Explain why salicylic acid has a higher melting point than benzoic acid.
Read and answer the ff queries:
1.) Arrange ice, liquid water, or water vapor according to their decreasing strength of intermolecular forces. Explain why are they arranged like that.
2.) What is amphiphilic substance? What special properties do they have that strictly polar or strictly nonpolar substances lack? Give three examples of amphiphilic substances.
3.) While there is nothing wrong in using room temperature or cold water to wash and rinse dishesand utensils, how is it that using hot (but not really boiled) water effectively removes the grease and stains attached to the dishes and utensils?
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Chapter 2 Solutions
Organic Chemistry
Ch. 2 - Practice Problem 2.1
Propose structures for two...Ch. 2 - Prob. 2PPCh. 2 - Prob. 3PPCh. 2 - Prob. 4PPCh. 2 - Prob. 5PPCh. 2 - Practice Problem 2.6
Using a three-dimensional...Ch. 2 - Practice Problem 2.7
Trichloromethane (, also...Ch. 2 - Prob. 8PPCh. 2 - Prob. 9PPCh. 2 - Practice Problem 2.10
Write bond-line structural...
Ch. 2 - Practice Problem 2.11 Although we shall discuss...Ch. 2 - Practice Problem 2.12 Write bond-line structural...Ch. 2 - Prob. 13PPCh. 2 - Practice Problem 2.14
One way of naming ethers is...Ch. 2 - Practice Problem 2.15 Eugenol is the main...Ch. 2 - Practice Problem 2.16
One way of naming amines is...Ch. 2 - Practice Problem 2.17 Which amines in Practice...Ch. 2 - Prob. 18PPCh. 2 - Prob. 19PPCh. 2 - Practice Problem 2.20
Write bond-line formulas for...Ch. 2 - Practice Problem 2.21
Write bond-line formulas for...Ch. 2 - Practice Problem 2.22
Write bond-line formulas for...Ch. 2 - Prob. 23PPCh. 2 - Practice Problem 2.24 Write another resonance...Ch. 2 - Prob. 25PPCh. 2 - Practice Problem 2.26
Which compound would you...Ch. 2 - Practice Problem 2.27 Arrange the following...Ch. 2 - Prob. 28PPCh. 2 - Prob. 29PCh. 2 - Identify all of the functional groups in each of...Ch. 2 - 2.31 There are four alkyl bromides with the...Ch. 2 - Prob. 32PCh. 2 - Classify the following alcohols as primary,...Ch. 2 - 2.34 Classify the following amines as primary,...Ch. 2 - Prob. 35PCh. 2 - Identify all of the functional groups in Crixivan,...Ch. 2 - 2.37 Identify all of the functional groups in...Ch. 2 - 2.38 (a) Indicate the hydrophobic and hydrophilic...Ch. 2 - Hydrogen fluoride has a dipole moment of 1.83 D;...Ch. 2 - 2.40 Why does one expect the cis isomer of an...Ch. 2 - Prob. 41PCh. 2 - Prob. 42PCh. 2 - Prob. 43PCh. 2 - 2.44 Consider each of the following molecules in...Ch. 2 - True or false: For a molecule to be polar, the...Ch. 2 - 2.46 Which compound in each of the following...Ch. 2 - Prob. 47PCh. 2 - The IR spectrum of propanoic acid (Fig. 2.16)...Ch. 2 - Prob. 49PCh. 2 - Write structural formulas for four compounds with...Ch. 2 - There are four amides with the formula C3H7NO. (a)...Ch. 2 - Prob. 52PCh. 2 - Prob. 53PCh. 2 - Prob. 54PCh. 2 - Prob. 55PCh. 2 - 2.56 Compound C is asymmetric, has molecular...Ch. 2 - 2.57 Examine the diagram showing an -helical...Ch. 2 - Prob. 1LGPCh. 2 - Prob. 2LGPCh. 2 - Prob. 3LGPCh. 2 - Consider the molecular formula C4H8O2. Predict...Ch. 2 - Consider the molecular formula C4H8O2. If any of...Ch. 2 - Prob. 6LGPCh. 2 - Consider the molecular formula.
7. Pick five...Ch. 2 - Prob. 8LGP
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- Consider the structures of salicylic acid and acetylsalicylic acid. What structural features are most likely responsible for the difference in the melting points of the two molecules? Explain briefly.arrow_forwardDescribe the trends in the physical properties of carboxylic acids, and contrast theirphysical properties with those of their salts.arrow_forwardWrite the Lewis dot structure for dicarbon tetrahydride.arrow_forward
- A hydrogen bond is a special case of which intermolecular force? Provide some examples of functional groups that are capable of participating in hydrogen bonding.arrow_forwardWhat are the hybridization and bond angles of the oxygens in benzoic acid?arrow_forwardWhy is water more acidic than ethanol but slightly less acidic than methanol?arrow_forward
- Write an equation for the reaction of chloroacetic acid (Ka=1.5103) with trimethylamine (Kb=5.9105) . Calculate the equilibrium constant for the reaction. If 0.10 M solutions of these two species are mixed, what will be their concentrations at equilibrium?arrow_forwardGiven the following pairs of organic compounds, underline which one boils at a highertemperature and explain why it is so. benzene, benzaldehydearrow_forwardGive the general structures of an ester, carboxylic acid, and alcohol. If you aregiven each sample or these compounds with comparable size, arrange thenaccording to decreasing boiling points.arrow_forward
- Please describe the polarity, hydrogen bonding, and nucleophilicity of water molecules.arrow_forwardwhy Acetanilide after cooling back at room temperature forms a crystal?arrow_forward. (a) The insecticide methoprene (see Fig. 7.32d) is an ester. Write the structural formulas for the alcohol and the carboxylic acid that react to form it. Name the alcohol.(b) Suppose that the carboxylic acid from part (a) is changed chemically so that the OCH3 group is replaced by a hydrogen atom and the COOH group is replaced by a CH3 group. Name the hydrocarbon that would result.arrow_forward
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