Student Solutions Manual for Bettelheim/Brown/Campbell/Farrell/Torres' Introduction to General, Organic and Biochemistry, 11th
11th Edition
ISBN: 9781305081055
Author: Bettelheim, Frederick A.
Publisher: Cengage Learning
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Textbook Question
Chapter 2, Problem 2.9P
9 Answer true or false.
(a) Matter is divided into elements and pure substances.
(b) Matter is anything that has mass and volume (occupies space).
(C) A mixture is composed of two or more pure substances.
(d) An element is a pure substance.
(e) A heterogeneous mixture can be separated into pure substances, but a homogeneous mixture cannot.
(f) A compound consists of elements combined in a fixed ratio.
(g) A compound is a pure substance.
(h) All matter has mass.
(I) All of the 118 known elements occur naturally on Earth.
(j) The first six elements in the Periodic Table are the most important for human life.
(k) The combining ratio of a compound tells you how many atoms of each element are combined in the compound.
(I) The combining ratio of 1:2 in the compound CO2 tells you that this compound is formed by the combination of one gram of carbon with two grams of oxygen.
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5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the
product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15%
glycerin by weight.
If the original charge is 500 kg, evaluate;
e. The ratio of sucrose to water in the original charge (wt/wt).
f. Moles of CO2 evolved.
g. Maximum possible amount of ethanol that could be formed.
h. Conversion efficiency.
i. Per cent excess of excess reactant.
Reactions:
Inversion reaction: C12H22O11 + H2O →2C6H12O6
Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2
Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3
Show work. don't give Ai generated solution. How many carbons and hydrogens are in the structure?
13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
2°C. +2°C. cleavage
Bond A
•CH3 + 26.← Cleavage
2°C. +
Bond C
+3°C•
CH3 2C
Cleavage
E
2°C. 26.
weakest bond
Intact molecule
Strongest 3°C 20.
Gund
Largest
argest
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
C
Weakest
bond
A
Produces
Most
Bond
Strongest
Bond
Strongest Gund
produces least stable
radicals
Weakest
Stable radical
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
13°C. formed in
bound C
cleavage
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
• CH3
methyl radical
Formed in Gund A Cleavage
c.…
Chapter 2 Solutions
Student Solutions Manual for Bettelheim/Brown/Campbell/Farrell/Torres' Introduction to General, Organic and Biochemistry, 11th
Ch. 2.2 - Problem 2-1 Write the formulas of compounds in...Ch. 2.4 - Problem 2-2 What is the mass number of an atom...Ch. 2.4 - Problem 2-3 Name the elements given in Problem...Ch. 2.4 - Problem 2-4 (a) What are the atomic numbers of...Ch. 2.4 - Prob. 2.5PCh. 2.4 - Problem 2-6 The atomic weight of lithium is 6.941...Ch. 2.6 - Problem 2-7 Write the Lewis dot structure for the...Ch. 2 - Prob. 2.8PCh. 2 - 9 Answer true or false. (a) Matter is divided into...Ch. 2 - Prob. 2.10P
Ch. 2 - Prob. 2.11PCh. 2 - 2-12 The elements game, Part 1. Name and give the...Ch. 2 - Prob. 2.13PCh. 2 - Prob. 2.14PCh. 2 - Prob. 2.15PCh. 2 - Prob. 2.16PCh. 2 - 2-17 How does Dalton’s atomic theory explain: (a)...Ch. 2 - Prob. 2.18PCh. 2 - Prob. 2.19PCh. 2 - 2-20 Calculate the percentage of hydrogen and...Ch. 2 - Prob. 2.21PCh. 2 - Prob. 2.22PCh. 2 - 2-23 It has been said, “The number of protons...Ch. 2 - Prob. 2.24PCh. 2 - Prob. 2.25PCh. 2 - 2-26 Given these mass numbers and number of...Ch. 2 - 2-27 If each atom in Problem 2-26 acquired two...Ch. 2 - Prob. 2.28PCh. 2 - 2-29 How many protons and how many neutrons does...Ch. 2 - Prob. 2.30PCh. 2 - 2-31 Tin-118 is one of the isotopes of tin. Name...Ch. 2 - Prob. 2.32PCh. 2 - Prob. 2.33PCh. 2 - 2-34 There are only two naturally occurring...Ch. 2 - 2-35 The two most abundant naturally occurring...Ch. 2 - Prob. 2.36PCh. 2 - Prob. 2.37PCh. 2 - Prob. 2.38PCh. 2 - Prob. 2.39PCh. 2 - Prob. 2.40PCh. 2 - Prob. 2.41PCh. 2 - Prob. 2.42PCh. 2 - 2-43 Which group(s) of the Periodic Table...Ch. 2 - 2-44 Which period(s) in the Periodic Table...Ch. 2 - Prob. 2.45PCh. 2 - Prob. 2.46PCh. 2 - 2-47 Which element in each pair is more metallic?...Ch. 2 - Prob. 2.48PCh. 2 - Prob. 2.49PCh. 2 - Prob. 2.50PCh. 2 - 2-51 What is the correlation between the group...Ch. 2 - Prob. 2.52PCh. 2 - Prob. 2.53PCh. 2 - Prob. 2.54PCh. 2 - Prob. 2.55PCh. 2 - Prob. 2.56PCh. 2 - Prob. 2.57PCh. 2 - Prob. 2.58PCh. 2 - 2-59 You are presented with a Lewis dot structure...Ch. 2 - Prob. 2.60PCh. 2 - Prob. 2.61PCh. 2 - Prob. 2.62PCh. 2 - Prob. 2.63PCh. 2 - 2-64 Consider the elements B, C, and N. Using only...Ch. 2 - Prob. 2.65PCh. 2 - Prob. 2.66PCh. 2 - 2-67 Account for the fact that the first...Ch. 2 - Prob. 2.68PCh. 2 - 2-69 (Chemical Connections 2A) Why does the body...Ch. 2 - Prob. 2.70PCh. 2 - Prob. 2.71PCh. 2 - Prob. 2.72PCh. 2 - 2-73 (Chemical Connections 2D) Copper is a soft...Ch. 2 - Prob. 2.74PCh. 2 - Prob. 2.75PCh. 2 - Prob. 2.76PCh. 2 - Prob. 2.77PCh. 2 - Prob. 2.78PCh. 2 - Prob. 2.79PCh. 2 - Prob. 2.80PCh. 2 - Prob. 2.81PCh. 2 - Prob. 2.82PCh. 2 - 2-83 The natural abundance of boron isotopes is as...Ch. 2 - Prob. 2.84PCh. 2 - 2-85 The mass of a proton is 1.67 × 10-24g. The...Ch. 2 - Prob. 2.86PCh. 2 - Prob. 2.87PCh. 2 - Prob. 2.88PCh. 2 - 2-89 Assume that a new element has been discovered...Ch. 2 - Prob. 2.90PCh. 2 - 2-91 These are the first two ionization energy for...Ch. 2 - Prob. 2.92PCh. 2 - Prob. 2.93PCh. 2 - 2-94 Using your knowledge of trends in element...Ch. 2 - Prob. 2.95PCh. 2 - Prob. 2.96PCh. 2 - 2-97 Explain why the Ca3+ ion is not found in...Ch. 2 - 2-98 Explain how the ionization energy of atoms...Ch. 2 - 2-99 A 7.12 g sample of magnesium is heated with...Ch. 2 - 2-100 A 0.100 g sample of magnesium, when combined...Ch. 2 - 2-101 Complete the following table: Symbol Atomic...Ch. 2 - 2-102 An element consists of 90.51% of an isotope...Ch. 2 - 2-103 The element silver has two naturally...Ch. 2 - 2-104 The average atomic weight of lithium is...Ch. 2 - Prob. 2.105PCh. 2 - Prob. 2.106P
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