Consider exercise 2.5. Would the work be more or less if it were performed against different external pressures found (a) at the top of Mount Everest, (b) at the bottom of Death Valley, (c) in space?
(a)
Interpretation:
Predict whether the work will be more or less when it is performed at the top of the Mount Everest.
Concept introduction:
The work is performed on an object when an object moves a certain distance s due to the force F. Mathematically, it is indicated by the dot product of the force vector F and the distance vector s. The mathematical equation is given below,
Where Ѳ is the angle between the vectors F and s. The unit of work is joules. Work is a way to transfer the energy. The energy is defined as the ability to do work and so energy and work are described using the same unit in joules.
Answer to Problem 2.6E
The work would be less because the external pressure is less.
Explanation of Solution
Gases do expansion or compression work by following the equation.
The given statement is like a person lifting a book or any other material from ground state to higher state does work against the gravity.
The gases can do the work through expansion or compression against the constant external pressure. Thus when the gas does the work in a piston and move it against the external pressure. Then the volume increase and so the work is negative as the external pressure is less.
Thus the work would be less because the external pressure is less.
(b)
Interpretation:
Predict whether the work will be more or less when it is performed at the bottom of the Death valley.
Concept introduction:
The work is performed on an object when an object moves a certain distance s due to the force F. Mathematically, it is indicated by the dot product of the force vector F and the distance vector s. The mathematical equation is given below,
Where Ѳ is the angle between the vectors F and s. The unit of work is joules. Work is a way to transfer the energy. The energy is defined as the ability to do work and so energy and work are described using the same unit in joules.
Answer to Problem 2.6E
The work would be more because the external pressure is more.
Explanation of Solution
Gases do expansion or compression work by following the equation.
The given statement is like a person lifting a book or any other material from ground state to same state does work with the gravity.
The gases can do the work through expansion or compression against the constant external pressure. Thus when the gas does the work in a piston and move it with the external pressure. Then the volume decrease and so the work is positive as the external pressure is more.
Thus the work would be more because the external pressure is more.
(c)
Interpretation:
Predict whether the work will be more or less when it is performed at space.
Concept introduction:
The work is performed on an object when an object moves a certain distance s due to the force F. Mathematically, it is indicated by the dot product of the force vector F and the distance vector s. The mathematical equation is given below,
Where Ѳ is the angle between the vectors F and s. The unit of work is joules. Work is a way to transfer the energy. The energy is defined as the ability to do work and so energy and work are described using the same unit in joules.
Answer to Problem 2.6E
No work would be performed because the external pressure is zero.
Explanation of Solution
Gases do expansion or compression work by following the equation.
Considering the expansion of a gas into a larger volume, which is an initially a vacuum. In this, the gas is expanding against a Pext of 0, where the work done by the gas is equals to zero. Such a process is called a free expansion. Hence, work = 0 for free expansion.
Thus no work would be performed because the external pressure is zero.
Want to see more full solutions like this?
Chapter 2 Solutions
Bundle: Physical Chemistry, 2nd + Student Solutions Manual
- Nido-boranes are structures with the molecular formula BnHn+4 that exhibit B-B, B-H-B and B-H bonds. Correct?arrow_forward8:07 AM Wed Dec 18 Final Exam 2024 copy Home Insert Draw Page Layout Formulas Data Review AA 田 General A G fx Alexis Cozort ☑ ⚫ 61% A B D E F H K M N P R S T U 3+ 10 125 mM that yielded peak heights of Aa = 9 1-(a)A sample solution was examined under XRF to quantify the analyte Ce³+. Find the response factor F, when standardized concentration of analyte [Ce³+]A = concentration of internal standard S i.e. [In³*]s = 151 mM was spiked with standardized 1600 and As = 3015 respectively? 11 12 (i)Define F, F = Aa As [A] [S] + X 13 (*Define with variables) 4000 14 15 (ii)Calculate F, F = numeral (You will use the F value in part 1-(b) below) As 16 (*Calculate with numerals) 17 18 1-(b)To determine the unknown conc of analyte [Ce³+], a volume of 15 mL of internal standard S having a concentration [In³+]s = 0.264 M 19 20 was added to 45 mL of unknown, and the mixture was diluted to 100 mL in a volumetric flask. XRF analysis yielded a spectrum, Figure-1, where peak heights A and As are…arrow_forwardAll structural types of Boron hydrides exhibit B-B, B-H-B and B-H bonds. Correct?arrow_forward
- N-nitrosodimethylamine (NDMA) is a suspected carcinogen that can form via reactions between dimethylamine (DMA) and monochloramine (NH2Cl). The relevant elementary reactions and the corresponding rate constants are as shown below. Reaction Rate constant (M¹s¹) DMA + NH2Cl = DMCA + NH3 k =1.4×10-1, kr = 5.83×10-3 1.28×10-3 DMA + NH2Cl → UDMH UDMH + NH2Cl → NDMA -> 1.11×10-1 If the initial concentrations of DMA and NH2Cl are given, you should be able to predict the concentrations of all species at any given reaction time. Please write down the rate equations for DMA, NH2C1, DMCA, UDMH and NDMA.arrow_forwardYou wish to add enough NaOCl (sodium hypochlorite) to a 150 m³ swimming pool to provide a dose of 5.0 mg/L TOTOCI as Cl2. (a) How much NaOCI (kg) should you add? (Note: the equivalent weight of NaOCl is based on the reaction: NaOCl + 2H + 2 e→CI + Na +H₂O.) (10 pts) (atomic weight: Na 23, O 16, C1 35.5) (b) The pH in the pool after the NaOCl addition is 8.67. To improve disinfection, you want at least 90% of the TOTOCI to be in the form of HOCI (pKa 7.53). Assuming that HOCI/OCI is the only weak acid/base group in solution, what volume (L) of 10 N HCl must be added to achieve the goal? (15 pts) Note that part a) is a bonus question for undergraduate students. If you decide not to work on this part of the question, you many assume TOTOCI = 7×10-5 M for part b).arrow_forwardPart A 2K(s)+Cl2(g)+2KCI(s) Express your answer in grams to three significant figures. Part B 2K(s)+Br2(1)→2KBr(s) Express your answer in grams to three significant figures. Part C 4Cr(s)+302(g)+2Cr2O3(s) Express your answer in grams to three significant figures. Part D 2Sr(s)+O2(g) 2SrO(s) Express your answer in grams to three significant figures. Thank you!arrow_forward
- A solution contains 10-28 M TOTCO3 and is at pH 8.1. How much HCI (moles per liter of solution) is required to titrate the solution to pH 7.0? (H2CO3: pKa1=6.35, pKa2=10.33)arrow_forwardDon't used Ai solutionarrow_forwardThe standard Gibbs energies of formation of CaO(s), CaCO3 (calcite), and CO2 (g) are -604.04, -1128.80, and -394.37 kJ/mol, respectively. Find the value of AG, and Keq for the following reaction: CaCO3 CaO (s) + CO2 (g) [ap A dry mixture containing 1 g of each solid [CaCO3(s) and CaO(s)] is on the lab bench in contact with the atmosphere, which contains a partial pressure of 10-35 bar CO2 (g). What is the total Gibbs free energy of the system containing all three species before any reaction has happened? Does the equilibrium driving force favor conversion of one of the solids into the other, or are the solids equilibrated with one another?arrow_forward
- Classification of boranes.arrow_forwardWhat is the pH of a solution made by adding 10-2 M sodium benzoate (C6H5COONa) to pure water, taking into account nonideal solute behavior? Benzoate is the conjugate base of benzoic acid (Ka = 6.25×10-5), a common preservative added to food and beverages.arrow_forwardShow work. don't give Ai generated solutionarrow_forward
- Physical ChemistryChemistryISBN:9781133958437Author:Ball, David W. (david Warren), BAER, TomasPublisher:Wadsworth Cengage Learning,Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningChemistry for Engineering StudentsChemistryISBN:9781337398909Author:Lawrence S. Brown, Tom HolmePublisher:Cengage Learning
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning