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(a)
Interpretation:
The reason for the atomic radius of anion to be always larger than that of the atom from which it is derived is to be explained.
Concept Introduction:
Atomic radius is half the distance between two molecules of an atom. Cation is formed by removal of electron/s from an atom and anions are formed by addition of electron/s in an atom. For same atoms, cationic radius is always less than that of the neutral atom and anionic radius is always greater than that of the neutral atom.
(b)
Interpretation:
The reason for the atomic radius of cation to be always smaller than that of the atom from which it is derived is to be explained.
Concept Introduction:
Atomic radius is half the distance between two molecules of an atom. Cation is formed by removal of electron/s from an atom and anions are formed by addition of electron/s in an atom. For same atoms, cationic radius is always less than that of the neutral atom and anionic radius is always greater than that of the neutral atom.
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Chapter 2 Solutions
Bundle: Introduction to General, Organic and Biochemistry, 11th + OWLv2, 4 terms (24 months) Printed Access Card
- 6. Show how you would accomplish the following transformations. (Show the steps and reagents/solvents needed) 2-methylpropene →2,2-dimethyloxiran Iarrow_forward4) Answer the following exercise with curved arrows indicating who is a nucleophile or Who is the electrophile? 2.44 Predict the structure of the product formed in the reaction of the organic base pyridine with the organic acid acetic acid, and use curved arrows to indicate the direction of electron flow. 7 H3C OH N Pyridine Acetic acidarrow_forwardUsing the data provided please help me answer this question. Determine the concentration of the iron(Ill) salicylate in the unknown directly from to graph and from the best fit trend-line (least squares analysis) of the graph that yielded a straight line.arrow_forward
- Please help me figure out what the slope is and how to calculate the half life Using the data provided.arrow_forwardCurved arrows are used to illustrate the flow of electrons. Follow the curved arrows and draw the structure of the missing reactants, intermediates, or products in the following mechanism. Include all lone pairs. Ignore stereochemistry. Ignore inorganic byproducts. H Br2 (1 equiv) H- Select to Draw Starting Alkene Draw Major Product I I H2O 四: ⑦.. Q Draw Major Charged Intermediate Iarrow_forwardNH (aq)+CNO (aq) → CO(NH2)2(s) Experiment [NH4] (M) [CNO] (M) Initial rate (M/s) 1 0.014 0.02 0.002 23 0.028 0.02 0.008 0.014 0.01 0.001 Calculate the rate contant for this reaction using the data provided in the table.arrow_forward
- 2CIO2 + 20H-1 CIO31 + CIO2 + H2O Experiment [CIO2], M [OH-1], M 1 0.0500 0.100 23 2 0.100 0.100 3 0.100 0.0500 Initial Rate, M/s 0.0575 0.230 0.115 ... Given this date, calculate the overall order of this reaction.arrow_forward2 3 .(be)_[Ɔ+(be)_OI ← (b²)_IƆO+ (be)_I Experiment [1-] M 0.005 [OCI-] 0.005 Initial Rate M/min 0.000275 0.0025 0.005 0.000138 0.0025 0.0025 0.000069 4 0.0025 0.0025 0.000140 Calculate the rate constant of this reaction using the table data.arrow_forward1 2 3 4 I(aq) +OCl(aq) → IO¯¯(aq) + Cl¯(aq) Experiment [I-] M 0.005 [OCI-] 0.005 Initial Rate M/min 0.000275 0.0025 0.005 0.000138 0.0025 0.0025 Calculate the overall order of this reaction using the table data. 0.0025 0.000069 0.0025 0.000140arrow_forward
- H2O2(aq) +3 I¯(aq) +2 H+(aq) → 13(aq) +2 H₂O(l)· ••• Experiment [H2 O2]o (M) [I]o (M) [H+]。 (M) Initial rate (M/s) 1 0.15 0.15 0.05 0.00012 234 0.15 0.3 0.05 0.00024 0.3 0.15 0.05 0.00024 0.15 0.15 0.1 0.00048 Calculate the overall order of this reaction using the table data.arrow_forwardThe U. S. Environmental Protection Agency (EPA) sets limits on healthful levels of air pollutants. The maximum level that the EPA considers safe for lead air pollution is 1.5 μg/m³ Part A If your lungs were filled with air containing this level of lead, how many lead atoms would be in your lungs? (Assume a total lung volume of 5.40 L.) ΜΕ ΑΣΦ = 2.35 1013 ? atoms ! Check your rounding. Your final answer should be rounded to 2 significant figures in the last step. No credit lost. Try again.arrow_forwardY= - 0.039 (14.01) + 0.7949arrow_forward
- Introduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
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