Inorganic Chemistry
Inorganic Chemistry
5th Edition
ISBN: 9780321811059
Author: Gary L. Miessler, Paul J. Fischer, Donald A. Tarr
Publisher: Prentice Hall
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Chapter 2, Problem 2.47P

(a)

Interpretation Introduction

Interpretation: The number of orbital present in one set g-orbital should be determined.

Concept introduction: The electrons that are present in an outermost orbital are known as valence electrons whereas those present in the orbitals with lower quantum numbers are termed as core electrons. Electrons are filled within orbitals by following three rules: Aufbau principle, Hund’s rule, and Pauli’s exclusion principle. Aufbau principle states, electrons are filled in the orbitals from lower to higher energy level as follows:

  1s<2s<2p<3s<3p<4s<3d<4p<5s<4d<5p<6s<4f<5d<6p<7s

Hund’s rule states, initially each orbital is singly occupied and then pairing occurs and Pauli’s exclusion principle states, spin of two different electrons in one orbital is always different.

(b)

Interpretation Introduction

Interpretation: The angular nodes of g-orbital should be explained.

Concept introduction: The electrons that are present in an outermost orbital are known as valence electrons whereas those present in the orbitals with lower quantum numbers are termed as core electrons. Electrons are filled within orbitals by following three rules: Aufbau principle, Hund’s rule, and Pauli’s exclusion principle. Aufbau principle states, electrons are filled in the orbitals from lower to higher energy level as follows:

  1s<2s<2p<3s<3p<4s<3d<4p<5s<4d<5p<6s<4f<5d<6p<7s

Hund’s rule states, initially each orbital is singly occupied and then pairing occurs and Pauli’s exclusion principle states, spin of two different electrons in one orbital is always different.

(c)

Interpretation Introduction

Interpretation: The relation between principal quantum number and radial nodes should be explained.

Concept introduction: The electrons that are present in an outermost orbital are known as valence electrons whereas those present in the orbitals with lower quantum numbers are termed as core electrons. Electrons are filled within orbitals by following three rules: Aufbau principle, Hund’s rule, and Pauli’s exclusion principle. Aufbau principle states, electrons are filled in the orbitals from lower to higher energy level as follows:

  1s<2s<2p<3s<3p<4s<3d<4p<5s<4d<5p<6s<4f<5d<6p<7s

Hund’s rule states, initially each orbital is singly occupied and then pairing occurs and Pauli’s exclusion principle states, spin of two different electrons in one orbital is always different.

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Assign all integrated peaks

Chapter 2 Solutions

Inorganic Chemistry

Ch. 2 - The transition from the n=7 to the n=2 level of...Ch. 2 - Emissions are observed at wavelengths of 383.65...Ch. 2 - What is the least amount of energy that can be...Ch. 2 - Hydrogen atom emission spectra measured from the...Ch. 2 - The Rydberg constant equation has two terms that...Ch. 2 - For the 3pz and 4dxz hydrogen-like atomic...Ch. 2 - Repeat the exercise in Problem 2.7 for the 4s and...Ch. 2 - Repeat the exercise in Problem 2.7 for the 5s and...Ch. 2 - The 4fz(x2y2) orbital has the angular function...Ch. 2 - Prob. 2.13PCh. 2 - The label for an fz2 orbital, like that for a dz2...Ch. 2 - a. Determine the possible values for the l and ml...Ch. 2 - a. What are the values of quantum numbers I and n...Ch. 2 - a. At most, how many electrons in an atom can have...Ch. 2 - Determine the Coulombic and exchange energies for...Ch. 2 - Prob. 2.19PCh. 2 - Prob. 2.20PCh. 2 - What states are possible for a d3 configuration?...Ch. 2 - Provide explanations of the following phenomena:...Ch. 2 - Give electron configurations for the following:...Ch. 2 - Predict the electron configurations of the...Ch. 2 - Radial probability plots shed insight on issues of...Ch. 2 - Briefly explain the following on the basis of...Ch. 2 - Briefly explain the following on the basis of...Ch. 2 - a. Which 2+ ion has two 3d electrons? Which has...Ch. 2 - A sample calculation in this chapter showed that,...Ch. 2 - Ionization energies should depend on the effective...Ch. 2 - Prepare a diagram such as the one in Figure (a)...Ch. 2 - Why are the ionization energies of the alkali...Ch. 2 - The second ionization of carbon (C+C2++e) and the...Ch. 2 - Prob. 2.35PCh. 2 - Prob. 2.36PCh. 2 - The second ionization energy involves removing an...Ch. 2 - Prob. 2.38PCh. 2 - On the basis of electron configurations, explain...Ch. 2 - a. The graph of ionization energy versus atomic...Ch. 2 - The second ionization energy of He ¡s almost...Ch. 2 - The size of the transition-metal atoms decreases...Ch. 2 - Predict the largest and smallest radius in each...Ch. 2 - Select the best choice, and briefly indicate the...Ch. 2 - Select the best choice, and briefly indicate the...Ch. 2 - There are a number of Web sites that display...Ch. 2 - Prob. 2.47P
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