Inorganic Chemistry
5th Edition
ISBN: 9780321811059
Author: Gary L. Miessler, Paul J. Fischer, Donald A. Tarr
Publisher: Prentice Hall
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Textbook Question
Chapter 2, Problem 2.17P
a. At most, how many electrons in an atom can have both
b. A 5d electron has what possible values of the quantum number
c. What value of quantum number l do p orbitals have? For what values of n do p orbitals occur?
d. What is the quantum number l for g orbitals? How many orbitals are in a g subshell?
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Question 11 of 18 (1 point) Question Attempt: 3 of
How many signals do you expect in the 'H NMR spectrum for this molecule?
Br
Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red.
Note for advanced students: In this question, any multiplet is counted as one signal.
Number of signals in the 'H NMR spectrum.
1
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
No additional Hs to color in top
molecule
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box…
Organic Chemistry
Esterification reactions
1. Write the steps to prepare ester.
2. Write complete reaction of ethanol and acetic acid to make ester.
3. What does ester smell like? What are the uses of ester.
4. What the role of sulfuric acid in the esterification reaction
11. Complete the following esterification reaction with names of all the reactants and products under.
Hint: Remove the water and end up with ester
R-C-OH + ROH
R-C-OR + H₂O
A carboxylic acid
An alcohol
An ester
Water
BYJU'S
H-C-C
O-H
Нин
C-C-C-H
HAAA
H O-C-C-C-H
AAA
Ethanoic acid
Propanol
Water Propyl ethanoate
By com
CH3COOH + CH3CH2CH2CH₂CH₂OH →
Practice for alcohols aldehydes and ketones:
12. Draw the structures from the following names mixed of alcohol/aldehyde and ketone:
a. 4-methyl cyclohexanone
b. 3-methyl-2-pentenal
c. 2,3-dimethylcyclohexanone
d. 1,3propanediol or Propane 1,3 diol
13. Write systematic names for the following compounds identify
functional group:
a.
b. (CH3)2CH-C
OH
c) CH(CH₂)--
OH
-,-,
Chapter 2 Solutions
Inorganic Chemistry
Ch. 2.1 - Determine the energy of the transition from nh=3...Ch. 2.2 - Describe the angular nodal surfaces for a dz2...Ch. 2.2 - Prob. 2.3ECh. 2.2 - A third possible state for the p4 configuration...Ch. 2.2 - A nitrogen atom, with three 2p electrons, could...Ch. 2.2 - Calculate the effective nuclear charge on a 5s,...Ch. 2.2 - Calculate the effective nuclear charge on a 7s,...Ch. 2.3 - Explain why all three graphs in Figure 2.14 have...Ch. 2 - Determine the de Brogue wavelength of a. an...Ch. 2 - Using the equation E=RH(1221nh2) determine the...
Ch. 2 - The transition from the n=7 to the n=2 level of...Ch. 2 - Emissions are observed at wavelengths of 383.65...Ch. 2 - What is the least amount of energy that can be...Ch. 2 - Hydrogen atom emission spectra measured from the...Ch. 2 - The Rydberg constant equation has two terms that...Ch. 2 - For the 3pz and 4dxz hydrogen-like atomic...Ch. 2 - Repeat the exercise in Problem 2.7 for the 4s and...Ch. 2 - Repeat the exercise in Problem 2.7 for the 5s and...Ch. 2 - The 4fz(x2y2) orbital has the angular function...Ch. 2 - Prob. 2.13PCh. 2 - The label for an fz2 orbital, like that for a dz2...Ch. 2 - a. Determine the possible values for the l and ml...Ch. 2 - a. What are the values of quantum numbers I and n...Ch. 2 - a. At most, how many electrons in an atom can have...Ch. 2 - Determine the Coulombic and exchange energies for...Ch. 2 - Prob. 2.19PCh. 2 - Prob. 2.20PCh. 2 - What states are possible for a d3 configuration?...Ch. 2 - Provide explanations of the following phenomena:...Ch. 2 - Give electron configurations for the following:...Ch. 2 - Predict the electron configurations of the...Ch. 2 - Radial probability plots shed insight on issues of...Ch. 2 - Briefly explain the following on the basis of...Ch. 2 - Briefly explain the following on the basis of...Ch. 2 - a. Which 2+ ion has two 3d electrons? Which has...Ch. 2 - A sample calculation in this chapter showed that,...Ch. 2 - Ionization energies should depend on the effective...Ch. 2 - Prepare a diagram such as the one in Figure (a)...Ch. 2 - Why are the ionization energies of the alkali...Ch. 2 - The second ionization of carbon (C+C2++e) and the...Ch. 2 - Prob. 2.35PCh. 2 - Prob. 2.36PCh. 2 - The second ionization energy involves removing an...Ch. 2 - Prob. 2.38PCh. 2 - On the basis of electron configurations, explain...Ch. 2 - a. The graph of ionization energy versus atomic...Ch. 2 - The second ionization energy of He ¡s almost...Ch. 2 - The size of the transition-metal atoms decreases...Ch. 2 - Predict the largest and smallest radius in each...Ch. 2 - Select the best choice, and briefly indicate the...Ch. 2 - Select the best choice, and briefly indicate the...Ch. 2 - There are a number of Web sites that display...Ch. 2 - Prob. 2.47P
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- may you please show all steps! i am having a hard time understanding and applying in this format, thank you!arrow_forward10. Complete the substitution reaction of 2 pentanol with these reagents. Reagents & Reaction Conditions use practice sheet. Please write only major products, minor product like water, other gases are not required. Hint: In substitution of alcohol, we generally substitute OH group with Halogens like cl, Br, F using some reagent containing halogens. Ensure to add halogens to the same carbon number where you are removing OH from Examples Alcohols can be converted to Alkyl Halides with HX acids HBr H₂O HCI + H₂O HI + H₂O CH,CH₂OH + SOCI₂ CH,CH₂OH + PCI₁₂ A BBYJU'S CH CHCI + SO₂+ HCI CH₂CH CIP(OH), + HCI CH,CH₂OH + PCI CHCHCI + POCI + HCI CH,CH₂OH + PBr, CH,CH,Br + P(OH), + HBr 1. Reaction with HBr with 2 Pentanol 2.Reaction with HI with 2 pentanol © Byjus.com 3.Reaction with HCI+ZnCl,, with 2 pentanol (Zncl2 is catalyst no role) 4.Reaction with SOCI,, with 2 Pentanol 5.Reaction with PBr; or PCl, with 2 pentanolarrow_forward3. Is 2-methyl-2-propanol a primary, secondary, or tertiary alcohol? Write out the structures of 2-methyl-2-propanol and also any oxidation products of 2- methyl-2- propanol. If there is more than one oxidation product, give the structure of each of the products. 4. 2-Propanol is the IUPAC systematic name of this alcohol. It has a common name by which it is much better known (You'll see it in the grocery store or pharmacy). Give that common name 5. Aldehydes can be synthesized by the oxidation of. Please choose from below choices A. Primary alcohols B. Secondary alcohols C. Organic acids D. Inorganic acids 6. Tertiary alcohol Can undergo oxidation. yes or no. ? If yes then answer the product.arrow_forward
- Finish the reactions hand written pleasearrow_forwardPart A Identify each alcohol as primary, secondary, or tertiary Drag the appropriate items to their respective bins. CH₂ H₂C- -C-OH HO CH₂ Primary Он OH CH₂ OH CCH₂OH CH₂ сн Secondary Tertiary Reset Help CH,CH₂ (CH)CHCH,OH CH,CH,CH,CCH, CHOH CH₂ Different types of alcohol groups Alcohol and its reaction: 8. Combing two alcohol molecules below and completing the reaction with Product .( Hint Reaction called etherification as ether is formed and name the ether once you complete the reaction. Hint.: R-O-H+H-O-RR-O-R Do the reaction: CH₂OH + CH₂OH---→ + H-O-H 9. Write the reaction of formation of alcohol from alkene by adding water: Addition reaction also called hydration reaction as we are adding water which occur always in presence of acid Hint: Break the double bond and add H and OH if symmetrical then add anywhere if unsymmetrical then follow Markovnikov rule H should go to that double bone carbon which has more hydrogen CH2=CH2 + H₂O-→arrow_forwardComplete the reaction hand written pleasearrow_forward
- Predict the major products of this organic reaction: HBr (1 equiv) cold ? Some important notes: • Draw the major product, or products, of this reaction in the drawing area below. • You can draw the products in any arrangement you like. • Pay careful attention to the reaction conditions, and only include the major products. • Be sure to use wedge and dash bonds when necessary, for example to distinguish between major products that are enantiomers. • Note that there is only 1 equivalent of HBr reactant, so you need not consider the case of multiple additions. dm Re Explanation Check ©2025 McGraw Hill LLC. All Rights Reserved. Termarrow_forwardb) Use curved arrows to show the reaction of the radical with hydrogen bromide. Br: Br H .. Answer Bankarrow_forwardIndicate the reaction products when CH3COCH2COOCH2COOC2H5 (ethyl acetoacetoacetate) reacts with 1º OH-/H2O and 2º H3O+arrow_forward
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