Chemistry
7th Edition
ISBN: 9780321940872
Author: John E. McMurry, Robert C. Fay, Jill Kirsten Robinson
Publisher: PEARSON
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Chapter 2, Problem 2.42CP
Interpretation Introduction
To determine:
Identify the given ions and atoms from the sample pictures.
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There is an instrument in Johnson 334 that measures total-reflectance x-ray fluorescence (TXRF) to do elemental analysis (i.e., determine what elements are present in a sample). A researcher is preparing a to measure calcium content in a series of well water samples by TXRF with an internal standard of vanadium (atomic symbol: V). She has prepared a series of standard solutions to ensure a linear instrument response over the expected Ca concentration range of 40-80 ppm. The concentrations of Ca and V (ppm) and the instrument response (peak area, arbitrary units) are shown below. Also included is a sample spectrum. Equation 1 describes the response factor, K, relating the analyte signal (SA) and the standard signal (SIS) to their respective concentrations (CA and CIS).
Ca, ppm
V, ppm
SCa, arb. units
SV, arb. units
20.0
10.0
14375.11
14261.02
40.0
10.0
36182.15
17997.10
60.0
10.0
39275.74
12988.01
80.0
10.0
57530.75
14268.54
100.0…
A mixture of 0.568 M H₂O, 0.438 M Cl₂O, and 0.710 M HClO are enclosed in a vessel at 25 °C.
H₂O(g) + C₁₂O(g) = 2 HOCl(g)
K = 0.0900 at 25°C
с
Calculate the equilibrium concentrations of each gas at 25 °C.
[H₂O]=
[C₁₂O]=
[HOCI]=
M
Σ
M
What units (if any) does the response factor (K) have? Does the response factor (K) depend upon how the concentration is expressed (e.g. molarity, ppm, ppb, etc.)?
Chapter 2 Solutions
Chemistry
Ch. 2 - Conceptual PRACTICE 2.1 An element is a shiny,...Ch. 2 - Prob. 2.2ACh. 2 - PRACTICE 2.3Compounds A and B are colorless gases...Ch. 2 - APPLY 2.4If the chemical formula of compound A in...Ch. 2 - PRACTICE 2.5The gold foil that Rutherford used in...Ch. 2 - Prob. 2.6ACh. 2 - PRACTICE 2.7The isotope 3475Se is used medically...Ch. 2 - APPLY 2.8Element X is toxic to humans in high...Ch. 2 - PRACTICE 2.9Copper metal has two naturally occur-...Ch. 2 - Prob. 2.10A
Ch. 2 - Prob. 2.11PCh. 2 - APPLY 2.12If 2.26 1022 atoms Of element Y have a...Ch. 2 - Prob. 2.13PCh. 2 - Prob. 2.14ACh. 2 - Prob. 2.15PCh. 2 - Prob. 2.16ACh. 2 - Prob. 2.17PCh. 2 - Prob. 2.18ACh. 2 - Prob. 2.19PCh. 2 - Prob. 2.20ACh. 2 - Prob. 2.21PCh. 2 - Prob. 2.22ACh. 2 - Prob. 2.23PCh. 2 - Prob. 2.24ACh. 2 - Prob. 2.25PCh. 2 - Prob. 2.26PCh. 2 - Prob. 2.27PCh. 2 - Prob. 2.28PCh. 2 - Prob. 2.29PCh. 2 - Prob. 2.30PCh. 2 - Prob. 2.31CPCh. 2 - Prob. 2.32CPCh. 2 - Prob. 2.33CPCh. 2 - Prob. 2.34CPCh. 2 - Prob. 2.35CPCh. 2 - Prob. 2.36CPCh. 2 - Prob. 2.37CPCh. 2 - Prob. 2.38CPCh. 2 - Prob. 2.39CPCh. 2 - Prob. 2.40CPCh. 2 - Prob. 2.41CPCh. 2 - Prob. 2.42CPCh. 2 - Prob. 2.43CPCh. 2 - Prob. 2.44SPCh. 2 - Prob. 2.45SPCh. 2 - Prob. 2.46SPCh. 2 - Prob. 2.47SPCh. 2 - Prob. 2.48SPCh. 2 - Prob. 2.49SPCh. 2 - Prob. 2.50SPCh. 2 - Prob. 2.51SPCh. 2 - Prob. 2.52SPCh. 2 - Prob. 2.53SPCh. 2 - Prob. 2.54SPCh. 2 - Prob. 2.55SPCh. 2 - Where in the periodic table are the metallic...Ch. 2 - Prob. 2.57SPCh. 2 - Prob. 2.58SPCh. 2 - Prob. 2.59SPCh. 2 - 2.60 List several general properties of the...Ch. 2 - Prob. 2.61SPCh. 2 - Prob. 2.62SPCh. 2 - Prob. 2.63SPCh. 2 - At room temperature, a certain element is found to...Ch. 2 - Prob. 2.65SPCh. 2 - At room temperature, a certain element is yellow...Ch. 2 - Prob. 2.67SPCh. 2 - Prob. 2.68SPCh. 2 - Prob. 2.69SPCh. 2 - How does Dalton’s atomic theory account for the...Ch. 2 - Prob. 2.71SPCh. 2 - A sample of mercury with a mass of 114.0 g was...Ch. 2 - Prob. 2.73SPCh. 2 - In methane, one part hydrogen combine with three...Ch. 2 - In borane, one part hydrogen combine with 3.6...Ch. 2 - Benzene, ethane, and ethylene are just three of a...Ch. 2 - Prob. 2.77SPCh. 2 - Prob. 2.78SPCh. 2 - 2.79 In addition to carbon monoxide (CO) and...Ch. 2 - Prob. 2.80SPCh. 2 - Prob. 2.81SPCh. 2 - Prob. 2.82SPCh. 2 - What affects the magnitude of the deflection of...Ch. 2 - Prob. 2.84SPCh. 2 - Prob. 2.85SPCh. 2 - Which of the following charges is NOT possible for...Ch. 2 - What discovery about atomic structure was made...Ch. 2 - Prior to Rutherford’s gold foil experiment, the...Ch. 2 - A period at the end of sentence written with a...Ch. 2 - A 1/4 inch thick lead sheet is used for protection...Ch. 2 - Prob. 2.91SPCh. 2 - What is the difference between an atom’s atomic...Ch. 2 - Prob. 2.93SPCh. 2 - Prob. 2.94SPCh. 2 - Prob. 2.95SPCh. 2 - Prob. 2.96SPCh. 2 - The radioactive isotope cesium-137 was produced in...Ch. 2 - Prob. 2.98SPCh. 2 - Prob. 2.99SPCh. 2 - How many protons, neutrons, and electrons are in...Ch. 2 - Prob. 2.101SPCh. 2 - Prob. 2.102SPCh. 2 - Prob. 2.103SPCh. 2 - Prob. 2.104SPCh. 2 - Prob. 2.105SPCh. 2 - Prob. 2.106SPCh. 2 - Prob. 2.107SPCh. 2 - Prob. 2.108SPCh. 2 - Naturally occurring silver consists of two...Ch. 2 - Prob. 2.110SPCh. 2 - Prob. 2.111SPCh. 2 - Prob. 2.112SPCh. 2 - Prob. 2.113SPCh. 2 - Prob. 2.114SPCh. 2 - Prob. 2.115SPCh. 2 - Prob. 2.116SPCh. 2 - Prob. 2.117SPCh. 2 - Prob. 2.118SPCh. 2 - Prob. 2.119SPCh. 2 - Prob. 2.120SPCh. 2 - Which of the following bonds are likely to be...Ch. 2 - The symbol CO stands for carbon monoxide, but the...Ch. 2 - Prob. 2.123SPCh. 2 - Prob. 2.124SPCh. 2 - Prob. 2.125SPCh. 2 - Prob. 2.126SPCh. 2 - Prob. 2.127SPCh. 2 - Prob. 2.128SPCh. 2 - Prob. 2.129SPCh. 2 - Prob. 2.130SPCh. 2 - Prob. 2.131SPCh. 2 - Give systematic names for the following binary...Ch. 2 - Give systematic names for the following binary...Ch. 2 - Prob. 2.134SPCh. 2 - Prob. 2.135SPCh. 2 - Prob. 2.136SPCh. 2 - Prob. 2.137SPCh. 2 - Give systematic names for the following compounds:...Ch. 2 - Name the following ions: (a) Ba2+ (b) Cs+ (c) V3+...Ch. 2 - Prob. 2.140SPCh. 2 - Prob. 2.141SPCh. 2 - Prob. 2.142SPCh. 2 - Prob. 2.143SPCh. 2 - Prob. 2.144SPCh. 2 - Prob. 2.145SPCh. 2 - Prob. 2.146SPCh. 2 - Prob. 2.147SPCh. 2 - Prob. 2.148SPCh. 2 - Prob. 2.149SPCh. 2 - Prob. 2.150SPCh. 2 - Prob. 2.151SPCh. 2 - Germanium has five naturally occurring isotopes:...Ch. 2 - Prob. 2.153CPCh. 2 - Ammonia (NH3) and hydrazine (N2H4) are both...Ch. 2 - Prob. 2.155CPCh. 2 - Prob. 2.156CPCh. 2 - Prob. 2.157CPCh. 2 - Prob. 2.158CPCh. 2 - What was the mass in atomic mass units of a 40Ca...Ch. 2 - Prob. 2.160CPCh. 2 - Prob. 2.161CPCh. 2 - Prob. 2.162CPCh. 2 - Prob. 2.163CP
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