Chemistry
7th Edition
ISBN: 9780321940872
Author: John E. McMurry, Robert C. Fay, Jill Kirsten Robinson
Publisher: PEARSON
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Chapter 2, Problem 2.27P
Interpretation Introduction
To determine:
- Highest % of atom economy
- Atom economy of each reaction
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Show how the following conversions might be accomplished. Show all reagents and all intermediate
ructures. More than one step may be required [2 ONLY]:
A.
B.
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A 20.3 mL sample of 0.263 M
triethylamine, (C2H5)3N, is titrated
with 0.252 M hydrochloric acid.
(1) At the titration midpoint, the pH is
. (2) At the equivalence point, the pH
is .
d. 3,4,5-trimethoxybenzoyl chloride
. What is the order of decreasing reactivity towards nucleophilic acyl substitution for the
arboxylic acid derivatives? (most reactive first)
A.
B.
0
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O
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H3C-C-O-C-CH3 H3C-C-N(CH3)2 H3C-C-OCH 3
(CH3)2CH-C-OCH3
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IV
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R-C-O C-R R-C-NH2
R-C OR
R-C-CI
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III
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c.
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IV, I, III, II
Chapter 2 Solutions
Chemistry
Ch. 2 - Conceptual PRACTICE 2.1 An element is a shiny,...Ch. 2 - Prob. 2.2ACh. 2 - PRACTICE 2.3Compounds A and B are colorless gases...Ch. 2 - APPLY 2.4If the chemical formula of compound A in...Ch. 2 - PRACTICE 2.5The gold foil that Rutherford used in...Ch. 2 - Prob. 2.6ACh. 2 - PRACTICE 2.7The isotope 3475Se is used medically...Ch. 2 - APPLY 2.8Element X is toxic to humans in high...Ch. 2 - PRACTICE 2.9Copper metal has two naturally occur-...Ch. 2 - Prob. 2.10A
Ch. 2 - Prob. 2.11PCh. 2 - APPLY 2.12If 2.26 1022 atoms Of element Y have a...Ch. 2 - Prob. 2.13PCh. 2 - Prob. 2.14ACh. 2 - Prob. 2.15PCh. 2 - Prob. 2.16ACh. 2 - Prob. 2.17PCh. 2 - Prob. 2.18ACh. 2 - Prob. 2.19PCh. 2 - Prob. 2.20ACh. 2 - Prob. 2.21PCh. 2 - Prob. 2.22ACh. 2 - Prob. 2.23PCh. 2 - Prob. 2.24ACh. 2 - Prob. 2.25PCh. 2 - Prob. 2.26PCh. 2 - Prob. 2.27PCh. 2 - Prob. 2.28PCh. 2 - Prob. 2.29PCh. 2 - Prob. 2.30PCh. 2 - Prob. 2.31CPCh. 2 - Prob. 2.32CPCh. 2 - Prob. 2.33CPCh. 2 - Prob. 2.34CPCh. 2 - Prob. 2.35CPCh. 2 - Prob. 2.36CPCh. 2 - Prob. 2.37CPCh. 2 - Prob. 2.38CPCh. 2 - Prob. 2.39CPCh. 2 - Prob. 2.40CPCh. 2 - Prob. 2.41CPCh. 2 - Prob. 2.42CPCh. 2 - Prob. 2.43CPCh. 2 - Prob. 2.44SPCh. 2 - Prob. 2.45SPCh. 2 - Prob. 2.46SPCh. 2 - Prob. 2.47SPCh. 2 - Prob. 2.48SPCh. 2 - Prob. 2.49SPCh. 2 - Prob. 2.50SPCh. 2 - Prob. 2.51SPCh. 2 - Prob. 2.52SPCh. 2 - Prob. 2.53SPCh. 2 - Prob. 2.54SPCh. 2 - Prob. 2.55SPCh. 2 - Where in the periodic table are the metallic...Ch. 2 - Prob. 2.57SPCh. 2 - Prob. 2.58SPCh. 2 - Prob. 2.59SPCh. 2 - 2.60 List several general properties of the...Ch. 2 - Prob. 2.61SPCh. 2 - Prob. 2.62SPCh. 2 - Prob. 2.63SPCh. 2 - At room temperature, a certain element is found to...Ch. 2 - Prob. 2.65SPCh. 2 - At room temperature, a certain element is yellow...Ch. 2 - Prob. 2.67SPCh. 2 - Prob. 2.68SPCh. 2 - Prob. 2.69SPCh. 2 - How does Dalton’s atomic theory account for the...Ch. 2 - Prob. 2.71SPCh. 2 - A sample of mercury with a mass of 114.0 g was...Ch. 2 - Prob. 2.73SPCh. 2 - In methane, one part hydrogen combine with three...Ch. 2 - In borane, one part hydrogen combine with 3.6...Ch. 2 - Benzene, ethane, and ethylene are just three of a...Ch. 2 - Prob. 2.77SPCh. 2 - Prob. 2.78SPCh. 2 - 2.79 In addition to carbon monoxide (CO) and...Ch. 2 - Prob. 2.80SPCh. 2 - Prob. 2.81SPCh. 2 - Prob. 2.82SPCh. 2 - What affects the magnitude of the deflection of...Ch. 2 - Prob. 2.84SPCh. 2 - Prob. 2.85SPCh. 2 - Which of the following charges is NOT possible for...Ch. 2 - What discovery about atomic structure was made...Ch. 2 - Prior to Rutherford’s gold foil experiment, the...Ch. 2 - A period at the end of sentence written with a...Ch. 2 - A 1/4 inch thick lead sheet is used for protection...Ch. 2 - Prob. 2.91SPCh. 2 - What is the difference between an atom’s atomic...Ch. 2 - Prob. 2.93SPCh. 2 - Prob. 2.94SPCh. 2 - Prob. 2.95SPCh. 2 - Prob. 2.96SPCh. 2 - The radioactive isotope cesium-137 was produced in...Ch. 2 - Prob. 2.98SPCh. 2 - Prob. 2.99SPCh. 2 - How many protons, neutrons, and electrons are in...Ch. 2 - Prob. 2.101SPCh. 2 - Prob. 2.102SPCh. 2 - Prob. 2.103SPCh. 2 - Prob. 2.104SPCh. 2 - Prob. 2.105SPCh. 2 - Prob. 2.106SPCh. 2 - Prob. 2.107SPCh. 2 - Prob. 2.108SPCh. 2 - Naturally occurring silver consists of two...Ch. 2 - Prob. 2.110SPCh. 2 - Prob. 2.111SPCh. 2 - Prob. 2.112SPCh. 2 - Prob. 2.113SPCh. 2 - Prob. 2.114SPCh. 2 - Prob. 2.115SPCh. 2 - Prob. 2.116SPCh. 2 - Prob. 2.117SPCh. 2 - Prob. 2.118SPCh. 2 - Prob. 2.119SPCh. 2 - Prob. 2.120SPCh. 2 - Which of the following bonds are likely to be...Ch. 2 - The symbol CO stands for carbon monoxide, but the...Ch. 2 - Prob. 2.123SPCh. 2 - Prob. 2.124SPCh. 2 - Prob. 2.125SPCh. 2 - Prob. 2.126SPCh. 2 - Prob. 2.127SPCh. 2 - Prob. 2.128SPCh. 2 - Prob. 2.129SPCh. 2 - Prob. 2.130SPCh. 2 - Prob. 2.131SPCh. 2 - Give systematic names for the following binary...Ch. 2 - Give systematic names for the following binary...Ch. 2 - Prob. 2.134SPCh. 2 - Prob. 2.135SPCh. 2 - Prob. 2.136SPCh. 2 - Prob. 2.137SPCh. 2 - Give systematic names for the following compounds:...Ch. 2 - Name the following ions: (a) Ba2+ (b) Cs+ (c) V3+...Ch. 2 - Prob. 2.140SPCh. 2 - Prob. 2.141SPCh. 2 - Prob. 2.142SPCh. 2 - Prob. 2.143SPCh. 2 - Prob. 2.144SPCh. 2 - Prob. 2.145SPCh. 2 - Prob. 2.146SPCh. 2 - Prob. 2.147SPCh. 2 - Prob. 2.148SPCh. 2 - Prob. 2.149SPCh. 2 - Prob. 2.150SPCh. 2 - Prob. 2.151SPCh. 2 - Germanium has five naturally occurring isotopes:...Ch. 2 - Prob. 2.153CPCh. 2 - Ammonia (NH3) and hydrazine (N2H4) are both...Ch. 2 - Prob. 2.155CPCh. 2 - Prob. 2.156CPCh. 2 - Prob. 2.157CPCh. 2 - Prob. 2.158CPCh. 2 - What was the mass in atomic mass units of a 40Ca...Ch. 2 - Prob. 2.160CPCh. 2 - Prob. 2.161CPCh. 2 - Prob. 2.162CPCh. 2 - Prob. 2.163CP
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