Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Textbook Question
Chapter 2, Problem 23Q
The contributions of J. J. Thomson and Ernest Rutherford led the way to today’s understanding of the structure of the atom. What were their contributions?
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3. Consider the compounds below and determine if they are aromatic, antiaromatic, or
non-aromatic. In case of aromatic or anti-aromatic, please indicate number of I
electrons in the respective systems. (Hint: 1. Not all lone pair electrons were explicitly
drawn and you should be able to tell that the bonding electrons and lone pair electrons
should reside in which hybridized atomic orbital 2. You should consider ring strain-
flexibility and steric repulsion that facilitates adoption of aromaticity or avoidance of anti-
aromaticity)
H H
N
N:
NH2
N
Aromaticity
(Circle)
Aromatic Aromatic Aromatic Aromatic Aromatic
Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic
nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic
aromatic TT
electrons
Me
H
Me
Aromaticity
(Circle)
Aromatic Aromatic Aromatic
Aromatic Aromatic
Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic
nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic
aromatic πT
electrons
H
HH…
A chemistry graduate student is studying the rate of this reaction:
2 HI (g) →H2(g) +12(g)
She fills a reaction vessel with HI and measures its concentration as the reaction proceeds:
time
(minutes)
[IH]
0
0.800M
1.0
0.301 M
2.0
0.185 M
3.0
0.134M
4.0
0.105 M
Use this data to answer the following questions.
Write the rate law for this reaction.
rate
= 0
Calculate the value of the rate constant k.
k =
Round your answer to 2 significant digits. Also be
sure your answer has the correct unit symbol.
None
Chapter 2 Solutions
Chemistry
Ch. 2 - Use Daltons atomic theory to account for each of...Ch. 2 - What evidence led to the conclusion that cathode...Ch. 2 - What discoveries were made by J. J. Thomson, Henri...Ch. 2 - Consider Ernest Rutherfords -particle bombardment...Ch. 2 - Do the proton and the neutron have exactly the...Ch. 2 - What is the distinction between atomic number and...Ch. 2 - Distinguish between the terms family and period in...Ch. 2 - The compounds AlCl3, CrCl3, and ICl3 have similar...Ch. 2 - Prob. 9RQCh. 2 - How would you name HBrO4, KIO3, NaBrO2, and HIO?...
Ch. 2 - Which of the following is true about an individual...Ch. 2 - How would you go about finding the number of chalk...Ch. 2 - These questions concern the work of J. J. Thomson....Ch. 2 - Prob. 4ALQCh. 2 - You have a chemical in a sealed glass container...Ch. 2 - The formula of water is If-O. Which of the...Ch. 2 - You may have noticed that when water boils, you...Ch. 2 - One of the best indications of a useful theory is...Ch. 2 - Prob. 9ALQCh. 2 - Label each of the following as an atomic element,...Ch. 2 - Why is the term sodium chloride molecule incorrect...Ch. 2 - Prob. 12ALQCh. 2 - Label each of the following as an atomic element,...Ch. 2 - Prob. 14ALQCh. 2 - Prob. 15ALQCh. 2 - Prob. 16ALQCh. 2 - Which of tire following explain how an ion is...Ch. 2 - What refinements had to be made in Daltons atomic...Ch. 2 - When hydrogen is burned in oxygen to form water,...Ch. 2 - The two most reactive families of elements are the...Ch. 2 - Explain the law of conservation of mass, the law...Ch. 2 - Section 2.3 describes the postulates of Daltons...Ch. 2 - The contributions of J. J. Thomson and Ernest...Ch. 2 - Prob. 24QCh. 2 - The number of protons in an atom determines the...Ch. 2 - If the volume of a proton were similar to the...Ch. 2 - Prob. 27QCh. 2 - List some characteristic properties that...Ch. 2 - Consider the elements of Group 4A (the carbon...Ch. 2 - Chlorine has two natural isotopes: 1737Cl and...Ch. 2 - Before an electrocardiogram (ECG) is recorded for...Ch. 2 - Distinguish between the following terms. a....Ch. 2 - Label the type of bonding for each of the...Ch. 2 - The vitamin niacin (nicotinic acid. C6H5NO2) can...Ch. 2 - Prob. 35QCh. 2 - Prob. 36QCh. 2 - When mixtures of gaseous H2 and gaseous Cl2 react,...Ch. 2 - Observations of the reaction between nitrogen gas...Ch. 2 - A sample of chloroform is found to contain 12.0 g...Ch. 2 - A sample of H2SO4 contains 2.02 g of hydrogen,...Ch. 2 - Consider 80.0-g samples of two different compounds...Ch. 2 - Several compounds containing sulfur and fluorine...Ch. 2 - The three most stable oxides of carbon ire carbon...Ch. 2 - Two elements. R and Q, combine to form two binary...Ch. 2 - In Section 1.1 of the text, the concept of a...Ch. 2 - In a combustion reaction, 46.0 g of ethanol reacts...Ch. 2 - Early tables of atomic weights (masses) were...Ch. 2 - Indium oxide contains 4.784 g of indium for every...Ch. 2 - Prob. 49ECh. 2 - If you wanted to make an accurate scale model of...Ch. 2 - In an experiment it was found that the total...Ch. 2 - A chemist in a galaxy tar, far away performed the...Ch. 2 - What are the symbols of the following nonmetals:...Ch. 2 - Prob. 55ECh. 2 - In the periodic table, how many elements are found...Ch. 2 - a. Classify the following elements as metals or...Ch. 2 - a. List the noble gas elements. Which of the noble...Ch. 2 - For each of the following sets of elements, label...Ch. 2 - Prob. 60ECh. 2 - Prob. 61ECh. 2 - Write the atomic symbol (ZAX) for each of the...Ch. 2 - Write the symbol of each atom using the ZAX...Ch. 2 - For carbon-14 and carbon-12, how many protons and...Ch. 2 - How many protons and neutrons are in the nucleus...Ch. 2 - Prob. 66ECh. 2 - For each of the following ions, indicate the...Ch. 2 - How many protons, neutrons, and electrons are in...Ch. 2 - Prob. 69ECh. 2 - What is the symbol of an ion with 16 protons, 18...Ch. 2 - Complete the following table: Symbol Number of...Ch. 2 - Complete the following table: Symbol Number of...Ch. 2 - Would you expect each of the following atoms to...Ch. 2 - Prob. 74ECh. 2 - Name the compounds in parts ad and write the...Ch. 2 - Name the compounds in parts a-d and write the...Ch. 2 - Prob. 77ECh. 2 - Prob. 78ECh. 2 - Prob. 79ECh. 2 - Prob. 80ECh. 2 - Prob. 81ECh. 2 - Prob. 82ECh. 2 - Prob. 83ECh. 2 - Prob. 84ECh. 2 - Prob. 85ECh. 2 - Prob. 86ECh. 2 - Prob. 87ECh. 2 - Write the formula for each of the following...Ch. 2 - Prob. 89ECh. 2 - Write the formula for each of the following...Ch. 2 - Prob. 91ECh. 2 - Each of the following compounds is incorrectly...Ch. 2 - Insulin is a complex protein molecule produced by...Ch. 2 - Carbohydrates, a class of compounds containing the...Ch. 2 - Prob. 95AECh. 2 - What are the symbols for the following nonmetal...Ch. 2 - Four Fe2+ ions are key components of hemoglobin,...Ch. 2 - Which of the following statements is(are) true?...Ch. 2 - The isotope of an unknown element, X, has a mass...Ch. 2 - Prob. 100AECh. 2 - Prob. 101AECh. 2 - Identify each of the following elements: a. a...Ch. 2 - Prob. 103AECh. 2 - Prob. 104AECh. 2 - Prob. 105AECh. 2 - Prob. 106AECh. 2 - Prob. 107AECh. 2 - Prob. 108AECh. 2 - Consider 100.0-g samples of two different...Ch. 2 - Give the systematic name for the following...Ch. 2 - Prob. 111CWPCh. 2 - Prob. 112CWPCh. 2 - Complete the following table. Atom/Ion Protons...Ch. 2 - Which of the following is{are) correct? a. 40Ca2...Ch. 2 - Prob. 115CWPCh. 2 - Prob. 116CWPCh. 2 - Prob. 117CWPCh. 2 - Prob. 118CWPCh. 2 - Reaction of 2.0 L of hydrogen gas with 1.0 L of...Ch. 2 - A combustion reaction involves the reaction of a...Ch. 2 - A chemistry instructor makes the following claim:...Ch. 2 - The early alchemists used to do an experiment in...Ch. 2 - Consider the chemical reaction as depicted below....Ch. 2 - Each of the following statements is true, but...Ch. 2 - You have two distinct gaseous compounds made from...Ch. 2 - A single molecule has a mass of 7.31 1023 g....Ch. 2 - You take three compounds, each consisting of two...Ch. 2 - Prob. 129IPCh. 2 - Prob. 130IPCh. 2 - Using the information in Table 2.1, answer the...
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