CHEMISTRY 1111 LAB MANUAL >C<
1st Edition
ISBN: 9781307092097
Author: Chang
Publisher: MCG/CREATE
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Textbook Question
Chapter 2, Problem 2.36QP
Give the number of protons and electrons in each of the following common ions: K+, Mg2+, Fe3+, Br−, Mn2+, C4−, Cu2+.
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You have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you
manipulated and exploited the acid-base chemistry of one or more of the compounds in your
mixture to facilitate their separation into different phases. The key to understanding how liquid-
liquid extractions work is by knowing which layer a compound is in, and in what protonation state.
The following liquid-liquid extraction is different from the one you performed in Experiment
4, but it uses the same type of logic. Your task is to show how to separate apart Compound
A and Compound B.
. Complete the following flowchart of a liquid-liquid extraction. Handwritten work is
encouraged.
•
Draw by hand (neatly) only the appropriate organic compound(s) in the boxes.
.
Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4
and 5.
•
Box 7a requires the solvent (name is fine).
•
Box 7b requires one inorganic compound.
• You can neatly complete this assignment by hand and…
b) Elucidate compound D w) mt at 170 nd shows c-1 stretch at 550cm;'
The compound has the ff electronic transitions: 0%o* and no a*
1H NMR Spectrum
(CDCl3, 400 MHz)
3.5
3.0
2.5
2.0
1.5
1.0
0.5 ppm
13C{H} NMR Spectrum
(CDCl3, 100 MHz)
Solvent
80
70
60
50
40
30
20
10
0 ppm
ppm
¹H-13C me-HSQC Spectrum
ppm
(CDCl3, 400 MHz)
5
¹H-¹H COSY Spectrum
(CDCl3, 400 MHz)
0.5
10
3.5
3.0
2.5
2.0
1.5 1.0
10
15
20
20
25
30
30
-35
-1.0
1.5
-2.0
-2.5
3.0
-3.5
0.5
ppm
3.5
3.0
2.5
2.0
1.5
1.0
0.5
ppm
Show work with explanation. don't give Ai generated solution
Chapter 2 Solutions
CHEMISTRY 1111 LAB MANUAL >C<
Ch. 2.1 - The atoms of elements A (blue) and B (orange) form...Ch. 2.3 - How many protons, neutrons, and electrons are in...Ch. 2.3 - Review of Concepts
What is the atomic number of an...Ch. 2.4 - In viewing the periodic table, do chemical...Ch. 2.5 - Review of Concepts
what does S8 signify? How does...Ch. 2.6 - Write the empirical formula for caffeine...Ch. 2.6 - Prob. 4PECh. 2.6 - Prob. 1RCCh. 2.7 - Name the following compounds: (a) PbO and (b)...Ch. 2.7 - Prob. 6PE
Ch. 2.7 - Name the following molecular compounds: (a) NF3...Ch. 2.7 - Prob. 8PECh. 2.7 - Prob. 1RCCh. 2.7 - Prob. 9PECh. 2.7 - Prob. 2RCCh. 2.8 - Prob. 1RCCh. 2 - Prob. 2.1QPCh. 2 - Name the types of radiation known to be emitted by...Ch. 2 - Compare the properties of the following: ...Ch. 2 - What is meant by the term fundamental particle?Ch. 2 - Describe the contributions of the following...Ch. 2 - Describe the experimental basis for believing that...Ch. 2 - The diameter of a helium atom is about 1 102 pm....Ch. 2 - Prob. 2.8QPCh. 2 - Use the helium-4 isotope to define atomic number...Ch. 2 - Why do all atoms of an element have the same...Ch. 2 - What do we call atoms of the same elements with...Ch. 2 - Explain the meaning of each term in the symbol...Ch. 2 - What is the mass number of an iron atom that has...Ch. 2 - Calculate the number of neutrons in 239Pu.Ch. 2 - Prob. 2.15QPCh. 2 - Indicate the number of protons, neutrons, and...Ch. 2 - Write the appropriate symbol for each of the...Ch. 2 - Write the appropriate symbol for each of the...Ch. 2 - What is the periodic table, and what is its...Ch. 2 - State two differences between a metal and a...Ch. 2 - Write the names and symbols for four elements in...Ch. 2 - Define, with two examples, the following terms:...Ch. 2 - Prob. 2.23QPCh. 2 - Describe the changes in properties (from metals to...Ch. 2 - Consult a handbook of chemical and physical data...Ch. 2 - Group the following elements in pairs that you...Ch. 2 - Prob. 2.27QPCh. 2 - Prob. 2.28QPCh. 2 - Describe the two commonly used molecular models.Ch. 2 - Prob. 2.30QPCh. 2 - Prob. 2.31QPCh. 2 - Prob. 2.32QPCh. 2 - Identify the following as elements or compounds:...Ch. 2 - Prob. 2.34QPCh. 2 - Give the number of protons and electrons in each...Ch. 2 - Give the number of protons and electrons in each...Ch. 2 - What does a chemical formula represent? What is...Ch. 2 - Define molecular formula and empirical formula....Ch. 2 - Give an example of a case in which two molecules...Ch. 2 - Prob. 2.40QPCh. 2 - Prob. 2.41QPCh. 2 - Prob. 2.42QPCh. 2 - Prob. 2.43QPCh. 2 - Prob. 2.44QPCh. 2 - What are the empirical formulas of the following...Ch. 2 - What are the empirical formulas of the following...Ch. 2 - Write the molecular formula of glycine, an amino...Ch. 2 - Write the molecular formula of ethanol. The color...Ch. 2 - Prob. 2.49QPCh. 2 - Prob. 2.50QPCh. 2 - Prob. 2.51QPCh. 2 - Prob. 2.52QPCh. 2 - Prob. 2.53QPCh. 2 - Prob. 2.54QPCh. 2 - Prob. 2.55QPCh. 2 - Prob. 2.56QPCh. 2 - Name these compounds: (a) Na2CrO4, (b) K2HPO4, (c)...Ch. 2 - Prob. 2.58QPCh. 2 - Prob. 2.59QPCh. 2 - Prob. 2.60QPCh. 2 - Sulfur (S) and fluorine (F) form several different...Ch. 2 - Prob. 2.62QPCh. 2 - Pair the following species that contain the same...Ch. 2 - Write the correct symbols for the atoms that...Ch. 2 - Prob. 2.65QPCh. 2 - In which one of the following pairs do the two...Ch. 2 - Prob. 2.67QPCh. 2 - Prob. 2.68QPCh. 2 - Determine the molecular and empirical formulas of...Ch. 2 - What is wrong with or ambiguous about the phrase...Ch. 2 - Prob. 2.71QPCh. 2 - Which of the following are elements, which are...Ch. 2 - Prob. 2.73QPCh. 2 - Prob. 2.74QPCh. 2 - Each of the following pairs of elements will react...Ch. 2 - Match the descriptions [(a)(h)] with each of the...Ch. 2 - Explain why anions are always larger than the...Ch. 2 - Prob. 2.78QPCh. 2 - Caffeine, shown here, is a psychoactive stimulant...Ch. 2 - Prob. 2.80QPCh. 2 - Prob. 2.81QPCh. 2 - Prob. 2.82QPCh. 2 - Fill in the blanks in the following table.Ch. 2 - Prob. 2.84QPCh. 2 - Write the formula of the common ion derived from...Ch. 2 - Prob. 2.86QPCh. 2 - Prob. 2.87QPCh. 2 - Of the 118 elements known, only two are liquids at...Ch. 2 - Prob. 2.89QPCh. 2 - Prob. 2.90QPCh. 2 - Prob. 2.91QPCh. 2 - Prob. 2.92QPCh. 2 - Prob. 2.93QPCh. 2 - Prob. 2.94QPCh. 2 - List five elements each that are (a) named after...Ch. 2 - Prob. 2.96QPCh. 2 - Fluorine reacts with hydrogen (H) and deuterium...Ch. 2 - Prob. 2.98QPCh. 2 - Identify each of the following elements: (a) a...Ch. 2 - Prob. 2.100QPCh. 2 - Show the locations of (a) alkali metals, (b)...Ch. 2 - Fill the blanks in the following table.Ch. 2 - Prob. 2.103QPCh. 2 - In Section 2.1 it was pointed out that mass and...Ch. 2 - Draw all possible structural formulas of the...Ch. 2 - Prob. 2.106QPCh. 2 - Draw two different structural formulas based on...Ch. 2 - Prob. 2.108QPCh. 2 - Prob. 2.109QPCh. 2 - A monatomic ion has a charge of +2. The nucleus of...Ch. 2 - In the following 2 2 crossword, each letter must...Ch. 2 - Prob. 2.112QPCh. 2 - Prob. 2.113QPCh. 2 - Prob. 2.114QPCh. 2 - Prob. 2.115QPCh. 2 - Prob. 2.116IMECh. 2 - Prob. 2.117IMECh. 2 - Prob. 2.118IMECh. 2 - Prob. 2.119IMECh. 2 - Prob. 2.120IMECh. 2 - Prob. 2.121IMECh. 2 - One technique proposed for recycling plastic...
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