CHEMISTRY-TEXT
8th Edition
ISBN: 9780134856230
Author: Robinson
Publisher: PEARSON
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Chapter 2, Problem 2.144SP
Interpretation Introduction
To determine:
The complete structural formula of isooctane.
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+0
Also calculate the amount of starting materials chlorobenzaldehyde and p-chloroacetophenone
required to prepare 400 mg of the given chalcone product 1, 3-bis(4-chlorophenyl)prop-2-en-1-one
molar mass ok 1,3-bis(4-Chlorophenyl) prop-2-en-1-one = 277.1591m01
number of moles= 0.400/277.15 = 0.00144 moles
2 x 0.00 144=0.00288 moves
arams of acetophenone = 0.00144 X 120.16 = 0.1739
0.1739x2=0.3469
grams of benzaldehyde = 0.00144X106.12=0.1539
0.1539x2 = 0.3069
Starting materials:
0.3469 Ox acetophenone,
0.3069 of benzaldehyde
3
1.
Answer the questions about the following reaction:
(a) Draw in the arrows that can be used make this reaction occur and draw in the product of substitution in this
reaction. Be sure to include any relevant stereochemistry in the product structure.
+
SK
F
Br
+
(b) In which solvent would this reaction proceed the fastest (Circle one)
Methanol
Acetone
(c) Imagine that you are working for a chemical company and it was your job to perform a similar reaction to the
one above, with the exception of the S atom in this reaction being replaced by an O atom. During the reaction, you
observe the formation of three separate molecules instead of the single molecule obtained above. What is the likeliest
other products that are formed? Draw them in the box provided.
3. For the reactions below, draw the arrows corresponding to the transformations and draw in the boxes the reactants
or products as indicated. Note: Part A should have arrows drawn going from the reactants to the middle structure
and the arrows on the middle structure that would yield the final structure. For part B, you will need to draw in
the reactant before being able to draw the arrows corresponding to product formation.
A.
B.
Rearrangement
ΘΗ
Chapter 2 Solutions
CHEMISTRY-TEXT
Ch. 2 - An element is a shiny, silver-colored solid at...Ch. 2 - Prob. 2.2ACh. 2 - PRACTICE 2.3Compounds A and B are colorless gases...Ch. 2 - APPLY 2.4If the chemical formula of compound A in...Ch. 2 - PRACTICE 2.5The gold foil that Rutherford used in...Ch. 2 - Prob. 2.6ACh. 2 - PRACTICE 2.7The isotope 3475Se is used medically...Ch. 2 - APPLY 2.8Element X is toxic to humans in high...Ch. 2 - PRACTICE 2.9Copper metal has two naturally occur-...Ch. 2 - Prob. 2.10A
Ch. 2 - Prob. 2.11PCh. 2 - APPLY 2.12If 2.26 1022 atoms Of element Y have a...Ch. 2 - Use the data from the mass spectrum of asample of...Ch. 2 - Use the data from the mass spectrum of a sample of...Ch. 2 - Which of the following drawings represents a pure...Ch. 2 - Red and blue spheres representatoms of different...Ch. 2 - Thymine, one of the four basesin deoxyribonucleic...Ch. 2 - Prob. 2.18ACh. 2 - Prob. 2.19PCh. 2 - Which of the following drawings most likely...Ch. 2 - Prob. 2.21PCh. 2 - Prob. 2.22ACh. 2 - Prob. 2.23PCh. 2 - Prob. 2.24ACh. 2 - Prob. 2.25PCh. 2 - Prob. 2.26ACh. 2 - Global climate is affected by variations in (a)...Ch. 2 - Prob. 2.28PCh. 2 - How many protons, neutrons, and electrons arein...Ch. 2 - Which sample of H2O has a higher ratio of 18O/16O...Ch. 2 - The last ice age occurred from 110,000 to11,700...Ch. 2 - For this problem, assume that water consistsonly...Ch. 2 - Prob. 2.33PCh. 2 - Prob. 2.34CPCh. 2 - Prob. 2.35CPCh. 2 - Prob. 2.36CPCh. 2 - Prob. 2.37CPCh. 2 - If yellow spheres represent sulfur atoms and red...Ch. 2 - Prob. 2.39CPCh. 2 - Prob. 2.40CPCh. 2 - Which of the following three drawings represents a...Ch. 2 - In the following drawings, red and blue spheres...Ch. 2 - Prob. 2.43CPCh. 2 - Prob. 2.44CPCh. 2 - Prob. 2.45CPCh. 2 - Prob. 2.46SPCh. 2 - Which element accounts for roughly 75% of the...Ch. 2 - Prob. 2.48SPCh. 2 - Prob. 2.49SPCh. 2 - Prob. 2.50SPCh. 2 - Prob. 2.51SPCh. 2 - Prob. 2.52SPCh. 2 - Prob. 2.53SPCh. 2 - Examine Figure 2.2, A portion of Mendeleev’s...Ch. 2 - Prob. 2.55SPCh. 2 - Prob. 2.56SPCh. 2 - Prob. 2.57SPCh. 2 - Prob. 2.58SPCh. 2 - Prob. 2.59SPCh. 2 - Prob. 2.60SPCh. 2 - Prob. 2.61SPCh. 2 - Prob. 2.62SPCh. 2 - Prob. 2.63SPCh. 2 - 2.60 List several general properties of the...Ch. 2 - Prob. 2.65SPCh. 2 - Prob. 2.66SPCh. 2 - Prob. 2.67SPCh. 2 - At room temperature, a certain element is found to...Ch. 2 - Prob. 2.69SPCh. 2 - At room temperature, a certain element is yellow...Ch. 2 - Prob. 2.71SPCh. 2 - Prob. 2.72SPCh. 2 - Prob. 2.73SPCh. 2 - Prob. 2.74SPCh. 2 - Prob. 2.75SPCh. 2 - How does Dalton’s atomic theory account for the...Ch. 2 - Prob. 2.77SPCh. 2 - A sample of mercury with a mass of 114.0 g was...Ch. 2 - Prob. 2.79SPCh. 2 - In methane, one part hydrogen combine with three...Ch. 2 - In borane, one part hydrogen combine with 3.6...Ch. 2 - Benzene, ethane, and ethylene are just three of a...Ch. 2 - Prob. 2.83SPCh. 2 - Prob. 2.84SPCh. 2 - 2.79 In addition to carbon monoxide (CO) and...Ch. 2 - Prob. 2.86SPCh. 2 - What affects the magnitude of the deflection of...Ch. 2 - Prob. 2.88SPCh. 2 - Prob. 2.89SPCh. 2 - Which of the following charges is NOT possible for...Ch. 2 - What discovery about atomic structure was made...Ch. 2 - Prior to Rutherford’s gold foil experiment, the...Ch. 2 - A period at the end of sentence written with a...Ch. 2 - A 1/4 inch thick lead sheet is used for protection...Ch. 2 - Prob. 2.95SPCh. 2 - What is the difference between an atom’s atomic...Ch. 2 - Prob. 2.97SPCh. 2 - Prob. 2.98SPCh. 2 - Prob. 2.99SPCh. 2 - Prob. 2.100SPCh. 2 - The radioactive isotope cesium-137 was produced in...Ch. 2 - Prob. 2.102SPCh. 2 - Prob. 2.103SPCh. 2 - How many protons, neutrons, and electrons are in...Ch. 2 - Prob. 2.105SPCh. 2 - Prob. 2.106SPCh. 2 - Prob. 2.107SPCh. 2 - Prob. 2.108SPCh. 2 - Prob. 2.109SPCh. 2 - Fluorine occurs naturally as a single isotope. How...Ch. 2 - Hydrogen has three isotopes (1H,2H,and3H) , and...Ch. 2 - The unified atomic mass unit (u) is defined as...Ch. 2 - Prob. 2.113SPCh. 2 - Prob. 2.114SPCh. 2 - Label the following statements as true or false....Ch. 2 - Copper has two naturally occurring isotopes,...Ch. 2 - Sulfur has four naturally occurring isotopes,...Ch. 2 - aturally occurring boron consists of two isotopes:...Ch. 2 - Prob. 2.119SPCh. 2 - Magnesium has three naturally occurring isotopes:...Ch. 2 - A sample of naturally occurring silicon consists...Ch. 2 - Copper metal has two naturally occurring isotopes:...Ch. 2 - Germanium has five naturally occurring...Ch. 2 - What is the mass in grams of each of the following...Ch. 2 - How many moles are in each of the following...Ch. 2 - If the atomic weight of an element is x, what is...Ch. 2 - If the atomic weight of an element is x, what is...Ch. 2 - Prob. 2.128SPCh. 2 - If 4.611021 atoms of element Z have a mass of 0.8...Ch. 2 - Refer to Figure 2.10 showing a schematic...Ch. 2 - Copper has two naturally occurring isotopes,...Ch. 2 - Use the data from the mass spectrum of a sample of...Ch. 2 - Use the data from the mass spectrum of a sample of...Ch. 2 - Prob. 2.134SPCh. 2 - Which of the following bonds are likely to be...Ch. 2 - The symbol CO stands for carbon monoxide, but the...Ch. 2 - Prob. 2.137SPCh. 2 - Prob. 2.138SPCh. 2 - Prob. 2.139SPCh. 2 - Prob. 2.140SPCh. 2 - Prob. 2.141SPCh. 2 - Prob. 2.142SPCh. 2 - Prob. 2.143SPCh. 2 - Prob. 2.144SPCh. 2 - Prob. 2.145SPCh. 2 - Give systematic names for the following binary...Ch. 2 - Give systematic names for the following binary...Ch. 2 - Prob. 2.148SPCh. 2 - Prob. 2.149SPCh. 2 - Prob. 2.150SPCh. 2 - Prob. 2.151SPCh. 2 - Give systematic names for the following compounds:...Ch. 2 - Name the following ions: (a) Ba2+ (b) Cs+ (c) V3+...Ch. 2 - Prob. 2.154SPCh. 2 - Prob. 2.155SPCh. 2 - Prob. 2.156SPCh. 2 - Prob. 2.157SPCh. 2 - Prob. 2.158SPCh. 2 - Prob. 2.159SPCh. 2 - Prob. 2.160SPCh. 2 - Prob. 2.161SPCh. 2 - Prob. 2.162SPCh. 2 - Prob. 2.163SPCh. 2 - Prob. 2.164SPCh. 2 - Prob. 2.165SPCh. 2 - Ammonia (NH3) and hydrazine (N2H4) are both...Ch. 2 - If 3.670 g of nitrogen combines with 0.5275 g of...Ch. 2 - Prior to 1961, the atomic mass unit (amu) was...Ch. 2 - What was the mass ¡n atomic mass units of a 40Ca...Ch. 2 - Prob. 2.170MPCh. 2 - The mass percent of an element in a compound is...Ch. 2 - In an alternate universe, the smallest negatively...
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