Inorganic Chemistry
Inorganic Chemistry
5th Edition
ISBN: 9781292134147
Author: Housecroft, Catherine E.
Publisher: Pearson,
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Chapter 2, Problem 14P

In the following table, match a species in list 1 with an isoelectronic partner in list 2.Some species may have more than one partner. Qualify how you have interpreted the term isoelectronic.

List 1 List 2
F 2 [ H 3 O ] +
NH 3 [ GaCl 4 ]
[ GaBr 4 ] - Cl 2
[ SH ] - [ NH 4 ] +
[ BH 4 ] - [ OH ] -
[ AsF 6 ] - [ O 2 ] 2-
[ PBr 4 ] + SeF 6
HF SiBr 4
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2. Provide a clear arrow-pushing mechanism for the following reactions. Do not skip proton transfers, do not combine steps, and make sure your arrows are clear enough to be interpreted without ambiguity. a. CH3 Ph OEt هد Ph CH3 Hint: the species on the left is an ynolate, which behaves a lot like an enolate.
b. CH3 H3C CH3 CH3 H3C an unexpected product, containing a single 9- membered ring the expected product, containing two fused rings H3C-I (H3C)2CuLi an enolate
b. H3C CH3 1. 2. H3O+ H3C MgBr H3C

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Inorganic Chemistry

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