
Inorganic Chemistry
5th Edition
ISBN: 9781292134147
Author: Housecroft, Catherine E.
Publisher: Pearson,
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Textbook Question
Chapter 2, Problem 14P
In the following table, match a species in list 1 with an isoelectronic partner in list 2.Some species may have more than one partner. Qualify how you have interpreted the term isoelectronic.
List 1 | List 2 |
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HF |
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2. Provide a clear arrow-pushing mechanism for the following reactions. Do not skip proton
transfers, do not combine steps, and make sure your arrows are clear enough to be interpreted
without ambiguity.
a.
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Ph
OEt
هد
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Hint: the species on the left is an ynolate, which behaves a lot like an enolate.
b.
CH3
H3C
CH3
CH3
H3C
an unexpected product,
containing a single 9-
membered ring
the expected product,
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H3C-I
(H3C)2CuLi
an enolate
b.
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1.
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H3C
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Chapter 2 Solutions
Inorganic Chemistry
Ch. 2 - Draw Lewis structures to describe the bonding in...Ch. 2 - Use the Lewis structure model to deduce the type...Ch. 2 - Draw the resonance structures for the O3 molecule....Ch. 2 - 2.4 Draw Lewis structures for (a) , (b) ,(c) and...Ch. 2 - 2.5 Each of the following is a radical. For which...Ch. 2 - (a) Use VB theory to describe the bonding in the...Ch. 2 - 2.7 Use VB theory and Lewis structure model,...Ch. 2 - 2.8 Does VB theory indicate that the diatomic...Ch. 2 - 2.9 (a) Use MO theory to determine the bond order...Ch. 2 - Prob. 10P
Ch. 2 - Prob. 11PCh. 2 - Draw charge-separated resonance structures to give...Ch. 2 - Prob. 13PCh. 2 - In the following table, match a species in list 1...Ch. 2 - Using the data in table 2.2, determine which of...Ch. 2 - Prob. 16PCh. 2 - 2.17 Use the VSEPR model to predict the structures...Ch. 2 - 2.18 Use the VSEPR model to rationalize the...Ch. 2 - Determine the shapes of each of the following...Ch. 2 - 2.20 State whether you expect the following...Ch. 2 - 2.21 (a) Draw resonance structure for the CO,...Ch. 2 - Prob. 22PCh. 2 - Prob. 23PCh. 2 - Suggest reasons for the following observations....Ch. 2 - Prob. 25PCh. 2 - Prob. 26PCh. 2 - 2.27 (a) Write down the ions that are present in...Ch. 2 - 2.28 Assuming that VSEPR model can be applied...Ch. 2 - Critically compare the VB and MO treatments of the...Ch. 2 - The table below gives the average composition of...Ch. 2 - Carbon monoxide is a toxic pollutant which arises...Ch. 2 - 2.32 Volcanoes and deep sea hydrothermal vents are...
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